BENCH-SCALE DEVELOPMENT OF A TRANSFORMATIVE MEMBRANE PROCESS FOR PRE-COMBUSTION CO 2 CAPTURE

Kniep, Jay; Salim, Witopo; Merkel, Tim; Casillas, Carlos; Amo, Karl; He, Jenny; Huang, Ivy; Nguyen, Vincent; Batoon, Vincent

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DOE OSTI · 1878227

BENCH-SCALE DEVELOPMENT OF A TRANSFORMATIVE MEMBRANE PROCESS FOR PRE-COMBUSTION CO 2 CAPTURE

Kniep, Jay·Salim, Witopo·Merkel, Tim·Casillas, Carlos·Amo, Karl·He, Jenny·Huang, Ivy·Nguyen, Vincent·Batoon, Vincent

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Abstract

This final technical report describes work conducted by Membrane Technology and Research, Inc. (MTR) for the Department of Energy, National Energy Technology Laboratory (DOE NETL) on development of the second generation (Gen-2) Proteus™ membrane modules and a pre-combustion membrane process for carbon dioxide (CO 2 ) capture from an Integrated Gasification Combined Cycle (IGCC) plant for power generation (award number DE-FE0031632). The work was conducted from October 1, 2018 through March 30, 2022. The overall goal of this project was to bring a Gen-2 version of the H2-selective Proteus membrane to bench-scale module (component) testing with real syngas. MTR was assisted in this project by Susteon, a technology development company with extensive experience in gasification processes, and the University of North Dakota Energy & Environmental Research Center (EERC), who provided the host site for the slipstream field testing. This report details the work conducted to optimize the Gen-2 Proteus membrane and develop modules capable of operation at 200°C; demonstrate membrane module performance processing coal-derived syngas during a field test at EERC; and optimize integration of a dual-membrane process into an IGCC with carbon capture. Work for this project included membrane optimization and scale-up, module component screening and fabrication of high-temperature lab- and bench-scale modules, design and fabrication of a bench-scale field test membrane skid, operation of the field test skid processing coal-derived syngas at EERC, and a detailed techno-economic analysis (TEA) of the MTR dual-membrane process for IGCC power plant pre-combustion CO 2 capture. This project validated recent membrane technology advancements, mitigates risk in future scale-up activities, and moved the membrane pre-combustion capture technology from TRL-4 to TRL-5. Key results for each major task are discussed in the report.

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10 SYNTHETIC FUELS 20 FOSSIL-FUELED POWER PLANTS 42 ENGINEERING 54 ENVIRONMENTAL SCIENCES carbon dioxide-selective membrane dual-membrane process hydrogen-selective membrane integrated gasification combined-cycle (IGCC)power plant Pre-combustion CO2 capture

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Kniep, Jay, Salim, Witopo, Merkel, Tim, Casillas, Carlos, Amo, Karl, He, Jenny, Huang, Ivy, Nguyen, Vincent, Batoon, Vincent. 2022-07-27. BENCH-SCALE DEVELOPMENT OF A TRANSFORMATIVE MEMBRANE PROCESS FOR PRE-COMBUSTION CO 2 CAPTURE. https://www.osti.gov/biblio/1878227

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