Radiation Stability of MOF Engineered Particles

Abstract

Pacific Northwest National Laboratory (PNNL), in collaboration with Flibe Energy, demonstrated the fabrication of metal organic frameworks (MOFs) into engineered beads to manage off-gases released from advanced reactors, including molten salt reactors. Based on the commercial availability and easy to synthesis at scale, PNNL down-selected two MOF sorbents known as CuBTC and UiO-67. The sorbents were synthesized, characterized, and fabricated into mechanically robust engineered beads (composites) using wet granulation method using polymer as a binder. Further, MOF powders and and mechanically robust composites were exposed to gamma radiation using Co-60 source and characterized irradiated MOFs to demonstrate the structural stability. Among the two MOF sorbents identified, the CuBTC MOF was shown to be very promising for noble gas management at low temperature (193 K) compared to UiO-67 MOF. The high adsorption capacity of the synthesized composites was correlated to the high surface area and pore volume of the CuBTC MOF. Both MOFs retain structural integrity and long-range order even after exposure to 1000 kGy of radiation.