Polymer Brushes under High Load

Balko, Suzanne M.; Kreer, Torsten; Costanzo, Philip J.; Patten, Tim E.; Johner, Albert; Kuhl, Tonya L.; Marques, Carlos M.

doi:10.1371/journal.pone.0058392

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Polymer Brushes under High Load

Balko, Suzanne M.·Kreer, Torsten·Costanzo, Philip J.·Patten, Tim E.·Johner, Albert·Kuhl, Tonya L.·Marques, Carlos M.

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Abstract

Polymer coatings are frequently used to provide repulsive forces between surfaces in solution. After 25 years of design and study, a quantitative model to explain and predict repulsion under strong compression is still lacking. Here, we combine experiments, simulations, and theory to study polymer coatings under high loads and demonstrate a validated model for the repulsive forces, proposing that this universal behavior can be predicted from the polymer solution properties.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY compression computer modeling molecular dynamics monomers polymers polystyrene synthetic polymers toluene

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Balko, Suzanne M., Kreer, Torsten, Costanzo, Philip J., Patten, Tim E., Johner, Albert, Kuhl, Tonya L., Marques, Carlos M.. 2013-03-13. Polymer Brushes under High Load. https://doi.org/10.1371/journal.pone.0058392

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