Electrochemical Kinetics of Stable Isotopes (Final Report)

Kavner, Abby

doi:10.2172/1989821

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DOE OSTI · 1989821

Electrochemical Kinetics of Stable Isotopes (Final Report)

Kavner, Abby

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Abstract

Stable isotopes are sensitive indicators to the mass transport and chemical reactions that occur during potentiostat-controlled electroplating of metals from aqueous (and some non-aqueous) metal-salt solutions. The goal of this research program is to measure the stable isotope fractionation during electrochemical processes, how the isotope-dependent rates are sensitive to chemistry, temperature, and electrochemical kinetics, and to use these measurements to develop a theoretical framework for a kinetic isotope effect that is able to predict kinetic isotope fractionation factors.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY 58 GEOSCIENCES Electrochemistry Isotopes

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Kavner, Abby. 2023-07-18. Electrochemical Kinetics of Stable Isotopes (Final Report). https://doi.org/10.2172/1989821

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