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DOE OSTI · 21580234

Two types of diffusions at the cathode/electrolyte interface in IT-SOFCs

Mori, Toshiyuki·Auchterlonie, Graeme John·Jin, Zou·Drennan, John
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Abstract

Analytical transmission electron microscopy, in particular with the combination of energy dispersive X-ray spectroscopy (EDX) and electron energy-loss spectroscopy (EELS), has been performed to investigate the microstructure and microchemistry of the interfacial region between the cathode (La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3}, LSCF) and the electrolyte (Gd-doped ceria, GDC). Two types of diffusions, mutual diffusion between cathode and electrolyte as well as the diffusion along grain boundaries, have been clarified. These diffusions suggest that the chemical stability of LSCF and GDC are not as good as previously reported. The results are more noteworthy if we take into consideration the fact that such interdiffusions occur even during the sintering process of cell preparation. - Graphical Abstract: Two types of diffusions, the mutual diffusion and the diffusion along grain boundaries, occurred at the cathode/electrolyte interface of intermediate temperature solid state fuel cells, during cell preparation. The mutual diffusion is denoted by black arrows and the diffusion along grain boundaries assigned by pink arrows. Highlights: > All the cations in cathode (LSCF) and electrolyte (GDC) can mutually diffuse into each other. > Diffusing elements will segregate at grain boundaries or triple junctions around the cathode/electrolyte interface. > Two types of diffusions, the mutual diffusion and diffusion along grain boundaries, have been clarified thereafter.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYCATHODESDIFFUSIONDIRECT ENERGY CONVERTERSDOPED MATERIALSELECTROCHEMICAL CELLSELECTRODESELECTROLYTESELECTRON MICROSCOPYELECTRON SPECTROSCOPYELECTRONSELEMENTARY PARTICLESENERGY-LOSS SPECTROSCOPYFERMIONSFUEL CELLSGRAIN BOUNDARIESHIGH-TEMPERATURE FUEL CELLSLEPTONSMATERIALSMICROSCOPYMICROSTRUCTURESOLID ELECTROLYTE FUEL CELLSSOLID OXIDE FUEL CELLSSOLIDSSPECTROSCOPYSTABILITYTRANSMISSION ELECTRON MICROSCOPYX-RAY SPECTROSCOPY

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Mori, Toshiyuki, Auchterlonie, Graeme John, Jin, Zou, Drennan, John. 2011-09-15. Two types of diffusions at the cathode/electrolyte interface in IT-SOFCs. https://www.osti.gov/biblio/21580234

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