Long-range interactions between chiral molecules

Salam, A.

doi:10.1063/1.4906634

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Long-range interactions between chiral molecules

Salam, A.

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Abstract

Results of molecular quantum electrodynamics calculations of discriminatory interactions between two chiral molecules undergoing resonance energy transfer, van der Waals dispersion, and optical binding are presented. A characteristic feature of the theory is that the radiation field is quantized with signals consequently propagating between centres at the speed of light. In order to correctly describe optically active chromophores, it is necessary to include magnetic as well as electric dipole coupling terms in the time-dependent perturbation theory computations. Recent work investigating the effect of an absorptive and dispersive chiral medium on the rate of migration of energy will also be discussed.

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74 ATOMIC AND MOLECULAR PHYSICS CHIRALITY COUPLING ELECTRIC DIPOLES ENERGY TRANSFER INTERACTION RANGE PERTURBATION THEORY QUANTIZATION QUANTUM ELECTRODYNAMICS TIME DEPENDENCE VAN DER WAALS FORCES VELOCITY VISIBLE RADIATION

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Salam, A.. 2015-01-22. Long-range interactions between chiral molecules. https://doi.org/10.1063/1.4906634

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