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DOE OSTI · 22402584

Diffusionless phase transition with two order parameters in spin-crossover solids

Gudyma, Iurii·Ivashko, Victor·Linares, Jorge
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Abstract

The quantitative analysis of the interface boundary motion between high-spin and low-spin phases is presented. The nonlinear effect of the switching front rate on the temperature is shown. A compressible model of spin-crossover solid is studied in the framework of the Ising-like model with two-order parameters under statistical approach, where the effect of elastic strain on interaction integral is considered. These considerations led to examination of the relation between the order parameters during temperature changes. Starting from the phenomenological Hamiltonian, entropy has been derived using the mean field approach. Finally, the phase diagram, which characterizes the system, is numerically analyzed.

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71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICSENTROPYHAMILTONIANSINTERFACESMEAN-FIELD THEORYNONLINEAR PROBLEMSORDER PARAMETERSPHASE DIAGRAMSPHASE TRANSFORMATIONSSOLIDSSTRAINS

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Gudyma, Iurii, Ivashko, Victor, Linares, Jorge. 2014-11-07. Diffusionless phase transition with two order parameters in spin-crossover solids. https://doi.org/10.1063/1.4901243

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