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DOE OSTI · 2429871

Is Pt dissolution a concern from the counter electrode in electrochemical oxygen evolution reaction?

Lyu, Xiang·Yang, Jun·Serov, Alexey
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Abstract

The Pt metal and its oxides dissolution from the counter electrode (CE, in hydrogen evolution reaction (HER)) has been suspected to affect the non-noble metal catalysts toward oxygen evolution reaction (OER). However, little effort has been devoted to this concern, and this work aims to determine the effect. The influence of electrolytes (H 2 SO 4 and NaOH) and Pt CE (acid-treated and pristine) on the Pt dissolution and membrane separations (Nafion and PiperION) on preventing Pt species migration were evaluated. Here, the results indicate only 11.2 ppb Pt from the cathodic electrolyte with Nafion 211 and 5 M NaOH electrolyte is observed, and no Pt is found from all other samples with acid-treated Pt CE. Regarding pristine Pt CE, 0.4 and 4.4 ppb Pt are observed from 0.5 M H 2 SO 4 and 5 M NaOH electrolytes, respectively. The findings in this work include: (1) Nafion membrane can effectively prevent the migration of Pt species from the cathode to the anode side; (2) a simple acid treatment of Pt could minimize the Pt dissolution into the acid electrolyte while showing an opposite role in the alkaline electrolyte; (3) the Pt dissolution from all experiments is minor, indicating Pt is a suitable CE for OER.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYHydrogen evolution reactionOxygen evolution reactionPt dissolutionWater splitting

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Lyu, Xiang, Yang, Jun, Serov, Alexey. 2024-08-03. Is Pt dissolution a concern from the counter electrode in electrochemical oxygen evolution reaction?. https://doi.org/10.1016/j.electacta.2024.144824

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