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DOE OSTI · 2475774

Dehydrogenated Polyethylene from Discarded Plastics as a Synthon for Functional Polyolefins

Hunt, Samuel B.·Delferro, Massimiliano
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Abstract

Many valuable specialty chemicals and drug candidates rely on synthesizing reactive intermediates to generate the final product(s). An approach that leverages C-H activation chemistry to achieve chemically active reactive handles for polymer diversification is desirable. Further, this report describes the synthesis and functionalization of dehydrogenated high-density polyethylene (HDPE) from discarded post-consumer plastic via acceptorless Ir-pincer-catalyzed non-oxidative dehydrogenation followed by acid-catalyzed hydroamination and hydroalkoxylation. The final products show significant material property changes with tunability and scalability through variation of the olefin content. This method highlights the potential value of dehydrogenated intermediates as platforms to enable carbon circularity and polyolefin end-of-life management strategies.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYFunctionalizationHydroaminationOlefinPolymerUpcycling

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Hunt, Samuel B., Delferro, Massimiliano. 2024-07-22. Dehydrogenated Polyethylene from Discarded Plastics as a Synthon for Functional Polyolefins. https://doi.org/10.1021/acsapm.4c01699

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