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DOE OSTI · 2479657

Realization of an Elusive U(III) Imido Complex

Reinhart, Erik D. [Pacific Northwest National Laboratory Richland, Washington 99345 United States of America] (ORCID:0000000328789376)·Studvick, Chad M. [Department of Chemistry The University of Akron Akron, Ohio 44325-3601 United States of America] (ORCID:000000024249776X)·Billow, Brennan S. [Los Alamos National Laboratory Los Alamos, New Mexico 87545 United States of America] (ORCID:0000000275609369)·Odom, Aaron L. [Department of Chemistry Michigan States University 578 S. Shaw Lane East Lansing, Michigan 48824 United States of America] (ORCID:0000000185304561)·Popov, Ivan A. [Department of Chemistry Washington State University Pullman, Washington 99164 United States of America] (ORCID:0000000301989159)·Boncella, James M. [Pacific Northwest National Laboratory Richland, Washington 99345 United States of America, Department of Chemistry Washington State University Pullman, Washington 99164 United States of America] (ORCID:000000018393392X)
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Abstract

Abstract Reduction of Cp*( Tripp TerN)UI with KC 8 generates (KCp*( Tripp TerN)UI) 2 , the first example of a trivalent uranium imido, a previously elusive species, which are commonly unstable. Experimental and computational results indicate that the K + coordination is responsible for this isolable U(III) monoimido complex.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRYArene complexesElectronic structureImidosLow-valent uraniumReduction

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Reinhart, Erik D. [Pacific Northwest National Laboratory Richland, Washington 99345 United States of America] (ORCID:0000000328789376), Studvick, Chad M. [Department of Chemistry The University of Akron Akron, Ohio 44325-3601 United States of America] (ORCID:000000024249776X), Billow, Brennan S. [Los Alamos National Laboratory Los Alamos, New Mexico 87545 United States of America] (ORCID:0000000275609369), Odom, Aaron L. [Department of Chemistry Michigan States University 578 S. Shaw Lane East Lansing, Michigan 48824 United States of America] (ORCID:0000000185304561), Popov, Ivan A. [Department of Chemistry Washington State University Pullman, Washington 99164 United States of America] (ORCID:0000000301989159), Boncella, James M. [Pacific Northwest National Laboratory Richland, Washington 99345 United States of America, Department of Chemistry Washington State University Pullman, Washington 99164 United States of America] (ORCID:000000018393392X). 2024-12-02. Realization of an Elusive U(III) Imido Complex. https://doi.org/10.1002/chem.202403859

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