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DOE OSTI · 2500822

Ligand-Induced Size-Dependent Circular Dichroism in Quantum Dots

Chabeda, Daniel·Gee, Stephen·Rabani, Eran
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Abstract

Recent experiments have probed the chiral properties of semiconductor nanocrystal (NC) quantum dots (QDs), but understanding the circular dichroism line shape, excitonic features, and chirality induction mechanism remains a challenge. We propose an atomistic pseudopotential method to model chiral ligand passivated QDs, computing circular dichroism (CD) spectra for CdSe QDs (2.6-3.8 nm). We find strong agreement between calculated and measured line shapes, predicting consistent bisignate line shapes with decreasing CD magnitude as size increases. Further, our analysis reveals the origin of bisignate line shapes, arising from nondegenerate excitons with opposing angular momenta. We also explore the impact of chiral ligand orientation on QD surfaces, observing changes in the optical activity magnitude and sign. This orientation sensitivity offers the means to distinguish ordered from disordered ligand configurations, facilitating the study of order-disorder transitions at ligand-QD interfaces.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYAbsorptionChiralityCircular dichroism spectroscopyLigandsQuantum dots

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Chabeda, Daniel, Gee, Stephen, Rabani, Eran. 2024-07-25. Ligand-Induced Size-Dependent Circular Dichroism in Quantum Dots. https://doi.org/10.1021/acs.jpclett.4c01682

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