Renewable and Biodegradable Polyurethane Foams with Aliphatic Diisocyanates

Bruckbauer, Aaron; Scofield, Gordon B.; Allemann, Marco N.; Reindel, Jaysen; Zhao, Jiayu; Howell, Ayden N.; Frisch, Thomas; Johnson, Lindsey; Evans, Payton; Pomeroy, Robert S.; Simkovsky, Ryan; Bae, Jinhye; Mayfield, Stephen P.; Burkart, Michael D.

doi:10.1021/acs.macromol.3c02356

DOE OSTI · 2503940

Renewable and Biodegradable Polyurethane Foams with Aliphatic Diisocyanates

Bruckbauer, Aaron·Scofield, Gordon B.·Allemann, Marco N.·Reindel, Jaysen·Zhao, Jiayu·Howell, Ayden N.·Frisch, Thomas·Johnson, Lindsey·Evans, Payton·Pomeroy, Robert S.·Simkovsky, Ryan·Bae, Jinhye·Mayfield, Stephen P.·Burkart, Michael D.

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Abstract

The transition to renewable plastics will require the development of substitutes with existing industrial standards and manufacturing processes. Polyurethanes (PU), versatile plastics, are traditionally dominated by aromatic diisocyanates, which are challenging to derive from renewable sources. However, for higher biocontent, it is crucial to utilize aliphatic diisocyanates, which can be sourced from renewable plant or algae waste streams. Historically, PU foams relied on aromatic diisocyanates for essential hard segments, resulting in desired physical properties. Here, we report the generation of high-performance renewable and biodegradable PU foams utilizing aliphatic diisocyanates and aromatic polyols, translating hard segments into the polyester polyol component using biosourced furan dicarboxylic acid (FDCA) monomers. We demonstrate that an FDCA-based PU is suitable for foams with performance characteristics that meet commercial tolerances and can biodegrade under backyard compost conditions. Here, this demonstrates steps toward redesigning traditional petrochemical-based polymers to accommodate new biological monomers.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY 59 BASIC BIOLOGICAL SCIENCES Aromatic compounds Biodegradation Foams Organic polymers Polyols

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Bruckbauer, Aaron, Scofield, Gordon B., Allemann, Marco N., Reindel, Jaysen, Zhao, Jiayu, Howell, Ayden N., Frisch, Thomas, Johnson, Lindsey, Evans, Payton, Pomeroy, Robert S., Simkovsky, Ryan, Bae, Jinhye, Mayfield, Stephen P., Burkart, Michael D.. 2024-03-12. Renewable and Biodegradable Polyurethane Foams with Aliphatic Diisocyanates. https://doi.org/10.1021/acs.macromol.3c02356

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