Stereoregular cyclic poly(3-hydroxybutyrate) enabled by catalyst-controlled tacticity and topology

Parker, Celine R. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000189155380); Zhang, Zhen [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA]; Quinn, Ethan C. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:000000029609806X); Reilly, Liam T. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000314697606); Chen, Eugene Y. -X. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000175123484)

doi:10.1039/d4py01304b

DOE OSTI · 2531262

Stereoregular cyclic poly(3-hydroxybutyrate) enabled by catalyst-controlled tacticity and topology

Parker, Celine R. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000189155380)·Zhang, Zhen [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA]·Quinn, Ethan C. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:000000029609806X)·Reilly, Liam T. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000314697606)·Chen, Eugene Y. -X. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000175123484)

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Abstract

Metal-based catalysts with large ionic radii and longer and more ionic metal–polymer bonds can control both stereoselectivity of polymerization and chain cyclization leading to stereoregular cyclic P3HB.

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Parker, Celine R. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000189155380), Zhang, Zhen [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA], Quinn, Ethan C. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:000000029609806X), Reilly, Liam T. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000314697606), Chen, Eugene Y. -X. [Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, USA] (ORCID:0000000175123484). 2025-04-08. Stereoregular cyclic poly(3-hydroxybutyrate) enabled by catalyst-controlled tacticity and topology. https://doi.org/10.1039/d4py01304b

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