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DOE OSTI · 2544236

Bridge connectivity effects on photoinduced ground-state electron spin polarization

Shultz, David A. [North Carolina State University, Raleigh, NC (United States); NC State University] (ORCID:0000000181216812)·Marri, Anil Reddy [North Carolina State University, Raleigh, NC (United States)]·Nogueira, Andre M. [North Carolina State University, Raleigh, NC (United States)] (ORCID:0000000191463243)·Mishra, Vivek K. [North Carolina State University, Raleigh, NC (United States)] (ORCID:0000000221216121)·Kirk, Martin L. [University of New Mexico, Albuquerque, NM (United States)] (ORCID:0000000214793318)·van der Est, Art [Brock University, St. Catharines, ON (Canada)] (ORCID:0000000262149260)
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Abstract

Transient electron paramagnetic resonance (TREPR) spectroscopy has been used to probe photoinduced electron spin polarization in the recovered ground states of four radical-elaborated (CAT)Pt(bpy) donor-acceptor complexes (CAT = catechol; bpy = 4,4'-di-tert-butyl-2,2'-bipyridine). These complexes are comprised of one or two S = 1/2 nitronyl nitroxide radicals attached through different phenylethynyl bridges to the 3- or 3,6 positions of the CAT donor. In this paper, we demonstrate the effects of substitution patterns on the magnitude of the TREPR signal, thereby guiding future design principles for generating and understanding the origin of photoinduced electron spin polarization in these and related chromophores.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYAbsorption spectroscopyCharge recombinationElectron paramagnetic resonance spectroscopyEquilibrium thermodynamicsExchange interactionsInitializationLocalized statesQuantum information scienceSpin polarizationSpintronicsZero field splitting

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Shultz, David A. [North Carolina State University, Raleigh, NC (United States); NC State University] (ORCID:0000000181216812), Marri, Anil Reddy [North Carolina State University, Raleigh, NC (United States)], Nogueira, Andre M. [North Carolina State University, Raleigh, NC (United States)] (ORCID:0000000191463243), Mishra, Vivek K. [North Carolina State University, Raleigh, NC (United States)] (ORCID:0000000221216121), Kirk, Martin L. [University of New Mexico, Albuquerque, NM (United States)] (ORCID:0000000214793318), van der Est, Art [Brock University, St. Catharines, ON (Canada)] (ORCID:0000000262149260). 2025-02-25. Bridge connectivity effects on photoinduced ground-state electron spin polarization. https://doi.org/10.1063/5.0246344

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