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DOE OSTI · 2549476

AWSD reactive flow model for PBX 9404

Craven, Galen T. (ORCID:0000000151172345)·Price, Matthew A. (ORCID:0000000348918841)·Andrews, Stephen A. (ORCID:0000000349973906)·Velizhanin, Kirill A. (ORCID:0000000306451112)·Aslam, Tariq D. (ORCID:0000000242630401)·Leiding, Jeffery A. (ORCID:0000000325125291)·Ticknor, Christopher (ORCID:0000000199724524)
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Abstract

An Arrhenius–Wescott–Stewart–Davis (AWSD) reactive flow model for high explosive PBX 9404 is developed. We specifically calibrate an AWSD model for PBX 9404 by fitting equations of state for reactants and detonation products to the results of thermochemical calculations and to experimental data from multiple sources. The calibrated equations of state are then coupled with an Arrhenius rate law based on shock temperature that describes the reaction progress during PBX 9404 detonation. The parameter values in the rate law are calibrated to experimental gas-gun data and diameter effect results. The results of the calibrated AWSD model are in strong agreement with available experimental data for PBX 9404. A similar level of agreement between predicted and experimental results is observed when the calibrated model is validated on data that were not used in the model parameterization procedure. Our results illustrate that the AWSD model is capable of accurately describing the many important properties and observables in the reactive burn of PBX 9404. Because of the historical significance of PBX 9404 in high explosives research and its current use in aging studies, this work provides an important model of a legacy material, which can be used to make comparisons to new high explosive formulations.

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Craven, Galen T. (ORCID:0000000151172345), Price, Matthew A. (ORCID:0000000348918841), Andrews, Stephen A. (ORCID:0000000349973906), Velizhanin, Kirill A. (ORCID:0000000306451112), Aslam, Tariq D. (ORCID:0000000242630401), Leiding, Jeffery A. (ORCID:0000000325125291), Ticknor, Christopher (ORCID:0000000199724524). 2025-04-07. AWSD reactive flow model for PBX 9404. https://doi.org/10.1063/5.0250699

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