Insights for controlling plutonium behavior in hydrochloric acid solutions

Wang, Yufei [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:000000025780112X); Rice, Natalie T. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; Knapp, Julia G. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000233244875); Adelman, Sara L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000179893451); Aldrich, Kelly E. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; Arko, Brian T. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; Besmer, Manuel L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000347680149); Gilhula, J. Connor [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000163002570); Godt, Christopher J. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; Klouda, Jan [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; Kozimor, Stosh A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000173870507); Long, Brian N. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; MacInnes, Molly M. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; Marshall-Roth, Travis [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000262456404); Nagelski, Alexandra L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]; Piedmonte, Ida D. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]

doi:10.1039/d5qi00409h

DOE OSTI · 2555940

Insights for controlling plutonium behavior in hydrochloric acid solutions

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Abstract

Cyclic voltammetry, UV-vis, and X-ray absorption spectroscopy were used to demonstrate that aqueous plutonium coordination chemistry and electron transfer reactivity can be controlled by judicious manipulation of hydrochloric acid concentrations.

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Wang, Yufei [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:000000025780112X), Rice, Natalie T. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], Knapp, Julia G. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000233244875), Adelman, Sara L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000179893451), Aldrich, Kelly E. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], Arko, Brian T. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], Besmer, Manuel L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000347680149), Gilhula, J. Connor [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000163002570), Godt, Christopher J. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], Klouda, Jan [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], Kozimor, Stosh A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000173870507), Long, Brian N. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], MacInnes, Molly M. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], Marshall-Roth, Travis [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA] (ORCID:0000000262456404), Nagelski, Alexandra L. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA], Piedmonte, Ida D. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA]. 2025-01-01. Insights for controlling plutonium behavior in hydrochloric acid solutions. https://doi.org/10.1039/d5qi00409h

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