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DOE OSTI · 2569361

Multiple Operando Fields Can Identify a Predictive Mass Transport Theory in Electrolytes

Mistry, Aashutosh [Argonne National Laboratory (ANL), Argonne, IL (United States)] (ORCID:0000000243594975)·Steinrück, Hans-Georg [Forschungszentrum Juelich (Germany); RWTH Aachen Univ. (Germany)] (ORCID:0000000163730877)·Toney, Michael F. [Univ. of Colorado, Boulder, CO (United States)] (ORCID:0000000275131166)·Balsara, Nitash P. [University of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)] (ORCID:0000000201065565)·Srinivasan, Venkat [Argonne National Laboratory (ANL), Argonne, IL (United States)] (ORCID:0000000212485952)
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Abstract

An electrolyte transport theory connects its transport properties, evolution of spatiotemporal fields (e.g., concentration), and corresponding macroscopic current and voltage responses. Given this interconnection, the transport properties are typically inferred by analyzing the macroscopic response through the lens of a chosen electrolyte transport theory. Unfortunately, the same macroscopic measurements can be analyzed by using different theories to arrive at seemingly dissimilar properties that are inconsistent with each other. Here, we offer a resolution to this dilemma by analyzing multiple spatiotemporal (i.e., operando) fields for a given electrolyte. We show that predictive transport theory can analyze operando fields to estimate underlying transport properties and subsequently predict another operando field. A theory passing this test identifies meaningful transport properties such that the electrolyte behavior can be accurately predicted over a wide range of excitations, and is critical to property-based electrolyte screening and electrolyte discovery efforts.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYElectrical transportElectrolytesInterfacesSolventsTransport properties

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Mistry, Aashutosh [Argonne National Laboratory (ANL), Argonne, IL (United States)] (ORCID:0000000243594975), Steinrück, Hans-Georg [Forschungszentrum Juelich (Germany); RWTH Aachen Univ. (Germany)] (ORCID:0000000163730877), Toney, Michael F. [Univ. of Colorado, Boulder, CO (United States)] (ORCID:0000000275131166), Balsara, Nitash P. [University of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)] (ORCID:0000000201065565), Srinivasan, Venkat [Argonne National Laboratory (ANL), Argonne, IL (United States)] (ORCID:0000000212485952). 2025-01-31. Multiple Operando Fields Can Identify a Predictive Mass Transport Theory in Electrolytes. https://doi.org/10.1021/acs.jpcc.4c06851

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