State of the Art in Thermal Catalytic Upgrading of Biomass and Biomass-Derived Intermediates

Hall, Jacklyn N. [Argonne National Laboratory (ANL), Argonne, IL (United States)]; Miller, Jacob H. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Assary, Rajeev S. [Argonne National Laboratory (ANL), Argonne, IL (United States)]; Baddour, Frederick G. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Dagle, Robert [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Dagle, Vanessa [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Griffin, Michael B. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Habas, Susan E. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Iisa, Kristiina [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Krause, Theodore R. [Argonne National Laboratory (ANL), Argonne, IL (United States)]; Kumar, Adarsh [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Linger, Jeffrey G. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Mittal, Ashutosh [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Mukarakate, Calvin [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Parks, James E. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)]; Ruddy, Daniel A. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]; Schmidt, Andrew [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Sutton, Andrew D. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)]; Thorson, Michael R. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Unocic, Kinga A. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)]; Wang, Huamin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Winkelman, Austin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)]; Yang, Xiaokun [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)] (ORCID:0000000181539574); Schaidle, Joshua A. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]

doi:10.1146/annurev-chembioeng-082323-122317

DOE OSTI · 2570043

State of the Art in Thermal Catalytic Upgrading of Biomass and Biomass-Derived Intermediates

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Abstract

Biomass-derived energy sources represent a promising domestic route for fuel and chemical production, taking advantage of largely underutilized biological and waste resources. Heterogeneous catalysis plays a key role in these biomass conversion processes, as reflected by all American Society for Testing and Materials–approved pathways for producing sustainable aviation fuel proceeding through a catalytic step. This concise review seeks to establish the state of the art in thermal catalytic process development for various biomass-derived feedstocks and the current enabling capabilities that aid this development. Research needs are identified and described throughout the article, as further advancements in heterogeneous catalysis are required to improve the affordability and realize the full potential of biomass-derived products.

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09 BIOMASS FUELS 10 SYNTHETIC FUELS 25 ENERGY STORAGE 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION 36 MATERIALS SCIENCE 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY 42 ENGINEERING 54 ENVIRONMENTAL SCIENCES biochemicals biofuels biomass heterogeneous catalysis sustainable aviation fuel thermal catalysis

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Hall, Jacklyn N. [Argonne National Laboratory (ANL), Argonne, IL (United States)], Miller, Jacob H. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Assary, Rajeev S. [Argonne National Laboratory (ANL), Argonne, IL (United States)], Baddour, Frederick G. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Dagle, Robert [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)], Dagle, Vanessa [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)], Griffin, Michael B. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Habas, Susan E. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Iisa, Kristiina [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Krause, Theodore R. [Argonne National Laboratory (ANL), Argonne, IL (United States)], Kumar, Adarsh [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Linger, Jeffrey G. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Mittal, Ashutosh [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Mukarakate, Calvin [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Parks, James E. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)], Ruddy, Daniel A. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)], Schmidt, Andrew [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)], Sutton, Andrew D. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)], Thorson, Michael R. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)], Unocic, Kinga A. [Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)], Wang, Huamin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)], Winkelman, Austin [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)], Yang, Xiaokun [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)] (ORCID:0000000181539574), Schaidle, Joshua A. [National Renewable Energy Laboratory (NREL), Golden, CO (United States)]. 2025-06-01. State of the Art in Thermal Catalytic Upgrading of Biomass and Biomass-Derived Intermediates. https://doi.org/10.1146/annurev-chembioeng-082323-122317

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