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DOE OSTI · 2585375

Tethered oxygen turns methane into methanol

Abstract

Precise control of the oxidant — that is, preventing overoxidation — is the missing link in low-temperature methane upgrading. Now, the electro-splitting of carbonate on rutile IrO 2 is shown to cover the surface with on-top oxygen adatoms that act as tethered, single-step hydrogen abstractors. One subset can pull the hydrogen from methane to form a methoxy intermediate, while the neighbouring site can protonate this intermediate to form methanol. Together, this mechanism delivers a room-temperature conversion of methane to methanol with >90% selectivity.

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BibTeXRIS

Prajapati, Aditya [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)] (ORCID:0000000182845493). 2025-07-24. Tethered oxygen turns methane into methanol. https://doi.org/10.1038/s41929-025-01381-y

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