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DOE OSTI · 2588108

Multimodal Ligand Non-Innocence for Reduction Catalysis (Final Technical Report)

Heyduk, Alan [Univ. of California, Irvine, CA (United States)]
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Abstract

The goal of this project was to develop multimodal ligand non-innocence in late transition metal complexes of aminophenolate ligands and to apply this ligand-centered reactivity to small-molecule reduction reactions relevant to energy-conversion chemistry. Specific aims were, 1) Prepare new coordination complexes of aminophenolate ligands and characterize them using a battery of structural, spectroscopic, and computational methods. 2) Benchmark the thermodynamics and kinetics of e - , H + , H • , and H - transfer reactivity to establish the baseline reactivity of new metal complexes containing aminophenolate ligands. 3) Apply new aminophenolate complexes to catalytic reduction reactions.

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Heyduk, Alan [Univ. of California, Irvine, CA (United States)]. 2025-09-11. Multimodal Ligand Non-Innocence for Reduction Catalysis (Final Technical Report). https://doi.org/10.2172/2588108

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