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DOE OSTI · 3006318

X-ray thermal diffuse scattering as a texture-robust temperature diagnostic for dynamically compressed solids

Heighway, P. G. [Univ. of Oxford (United Kingdom); et al.] (ORCID:0000000162210650)·Peake, D. J. [Department of Physics, Clarendon Laboratory, University of Oxford 1 , Parks Road, Oxford OX1 3PU,] (ORCID:0000000259926954)·Stevens, T. [Department of Physics, Clarendon Laboratory, University of Oxford 1 , Parks Road, Oxford OX1 3PU,] (ORCID:0009000683553509)·Wark, J. S. [Department of Physics, Clarendon Laboratory, University of Oxford 1 , Parks Road, Oxford OX1 3PU,] (ORCID:0000000330553223)·Albertazzi, B. [Ecole Polytechnique, Palaiseau, Laboratoire pour l’utilisation des lasers intenses (LULI), CNRS UMR 7605 2 , Route de Saclay, 91128 Palaiseau Cedex,]·Ali, S. J. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000318233788)·Antonelli, L. [School of Physics, Engineering and Technology, University of York 4 , Heslington, York YO10 5DD,] (ORCID:000000030694948X)·Armstrong, M. R. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000323751491)·Baehtz, C. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:000000031480511X)·Ball, O. B. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000252150153)·Banerjee, S. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:000000019407477X)·Belonoshko, A. B. [Frontiers Science Center for Critical Earth Material Cycling, School of Earth Sciences and Engineering, Nanjing University 8 , Nanjing 210023,]·Bolme, C. A. [Los Alamos National Laboratory 9 , Los Alamos, New Mexico 87545,] (ORCID:000000021880271X)·Bouffetier, V. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000160791260)·Briggs, R. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000345885802)·Buakor, K. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000302572822)·Butcher, T. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000309095982)·Di Dio Cafiso, S. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,]·Cerantola, V. [Dipartimento di Scienze dell’Ambiente e della Terra, Università degli Studi di Milano Bicocca 11 , Piazza della Scienza 1e4, I-20126 Milano,] (ORCID:0000000228082963)·Chantel, J. [Univ. Lille, CNRS, INRAE, Centrale Lille, UMR 8207—UMET—Unité Matériaux et Transformations 12 , F-59000 Lille,] (ORCID:0000000283329033)·Di Cicco, A. [School of Science and Technology—Physics Division, Università di Camerino 13 , 62032 Camerino,]·Coleman, A. L. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000256924400)·Collier, J. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000120030472)·Collins, G. [Laboratory for Laser Energetics (LLE), University of Rochester 14 , 250 East River Road, Rochester, New York 14623-1299,] (ORCID:0000000154366866)·Comley, A. J. [Atomic Weapons Establishment (AWE), Materials Science and Research Division (MSRD) 15 , Aldermaston, Berkshire RG7 4PR,] (ORCID:000900022580653X)·Coppari, F. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000315923898)·Cowan, T. E. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:000000025845000X)·Cristoforetti, G. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica, CNR—INO) 16 , Largo Enrico Fermi, 6, 50125 Firenze FI,] (ORCID:0000000194209080)·Cynn, H. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000346585764)·Descamps, A. [School of Mathematics and Physics, Queen’s University Belfast 17 , University Road, Belfast BT7 1NN,] (ORCID:0000000317086376)·Dorchies, F. [Université de Bordeaux, CNRS, CEA, CELIA, UMR 5107 18 , F-33400 Talence,] (ORCID:0000000259229585)·Duff, M. J. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,]·Dwivedi, A. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0009000874970444)·Edwards, C. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,]·Eggert, J. H. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000157307108)·Errandonea, D. [Departamento de Fisica Aplicada—ICMUV, Universidad de Valencia—UV 19 , C/Dr. Moliner 50 Burjassot, E-46100 Valencia,] (ORCID:0000000301894221)·Fiquet, G. [Sorbonne Université, Muséum National d’Histoire Naturelle, UMR CNRS 7590, Insitut de Minéralogie, de Physique, des Matériaux, et de Cosmochinie, IMPMC 20 , Paris 75005,] (ORCID:0000000189613281)·Galtier, E. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:000000020396285X)·Laso Garcia, A. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0000000276710901)·Ginestet, H. [Univ. Lille, CNRS, INRAE, Centrale Lille, UMR 8207—UMET—Unité Matériaux et Transformations 12 , F-59000 Lille,] (ORCID:0000000269314062)·Gizzi, L. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica (CNR—INO) 22 , Via G. Moruzzi, 1-56124 Pisa,] (ORCID:0000000165726492)·Gleason, A. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:0000000277365118)·Goede, S. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,]·Gonzalez, J. M. [Department of Physics, University of South Florida 23 , Tampa, Florida 33620,] (ORCID:0000000170389726)·Gorman, M. G. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000195676166)·Harmand, M. [Sorbonne Université, Muséum National d’Histoire Naturelle, UMR CNRS 7590, Insitut de Minéralogie, de Physique, des Matériaux, et de Cosmochinie, IMPMC 20 , Paris 75005,; PIMM, Arts et Metiers Institute of Technology, CNRS, Cnam, HESAM University 24 , 151 boulevard de l’Hopital, 75013 Paris,] (ORCID:0000000307135824)·Hartley, N. J. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:0000000262682436)·Hernandez-Gomez, C. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000595461989)·Higginbotham, A. [School of Physics, Engineering and Technology, University of York 4 , Heslington, York YO10 5DD,] (ORCID:0000000152119933)·Höppner, H. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0009000019295097)·Humphries, O. S. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000167480422)·Husband, R. J. [Deutsches Elektronen-Synchrotron DESY 25 , Notkestr. 85, 22607 Hamburg,] (ORCID:000000027666401X)·Hutchinson, T. M. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000318823702)·Hwang, H. [Deutsches Elektronen-Synchrotron DESY 25 , Notkestr. 85, 22607 Hamburg,] (ORCID:0000000284983811)·Keen, D. A. [ISIS Facility, STFC Rutherford Appleton Laboratory 26 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0000000303762767)·Kim, J. [Department of Physics, Hanyang University 27 , 17 Haengdang dong, Seongdong gu, Seoul 133-791,] (ORCID:0000000317873775)·Koester, P. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica, CNR—INO) 16 , Largo Enrico Fermi, 6, 50125 Firenze FI,] (ORCID:0000000216174633)·Konopkova, Z. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000189056307)·Kraus, D. [Universität Rostock, Institut für Physik 28 , D-18051 Rostock,] (ORCID:0000000263504180)·Krygier, A. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000161781195)·Labate, L. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica, CNR—INO) 16 , Largo Enrico Fermi, 6, 50125 Firenze FI,] (ORCID:0000000208044548)·Lazicki, A. E. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,]·Lee, Y. [Department of Earth System Sciences, Yonsei University 29 , 50 Yonsei-ro Seodaemun-gu, Seoul 03722,] (ORCID:0000000220430804)·Liermann, H.-P. [Deutsches Elektronen-Synchrotron DESY 25 , Notkestr. 85, 22607 Hamburg,] (ORCID:0000000150391183)·Mason, P. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0000000182409819)·Masruri, M. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0000000225216241)·Massani, B. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000258171780)·McBride, E. E. [School of Mathematics and Physics, Queen’s University Belfast 17 , University Road, Belfast BT7 1NN,] (ORCID:0000000288216126)·McGuire, C. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,]·McHardy, J. D. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000226308092)·McGonegle, D. [Atomic Weapons Establishment (AWE), Materials Science and Research Division (MSRD) 15 , Aldermaston, Berkshire RG7 4PR,] (ORCID:0000000153291081)·McWilliams, R. S. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000237308661)·Merkel, S. [Univ. Lille, CNRS, INRAE, Centrale Lille, UMR 8207—UMET—Unité Matériaux et Transformations 12 , F-59000 Lille,] (ORCID:000000032767581X)·Morard, G. [Univ. Grenoble Alpes, Univ. Savoie Mont Blanc, CNRS, IRD, Univ. Gustave Eiffel, ISTerre 30 , 38000 Grenoble,] (ORCID:0000000242250767)·Nagler, B. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:0009000257367842)·Nakatsutsumi, M. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000308684745)·Nguyen-Cong, K. [Department of Physics, University of South Florida 23 , Tampa, Florida 33620,] (ORCID:0000000342996208)·Norton, A.-M. [School of Physics, Engineering and Technology, University of York 4 , Heslington, York YO10 5DD,] (ORCID:0000000177120615)·Oleynik, I. I. [Department of Physics, University of South Florida 23 , Tampa, Florida 33620,] (ORCID:0000000253486484)·Otzen, C. [Institut für Geo- und Umweltnaturwissenschaften, Albert-Ludwigs-Universität Freiburg 31 , Hermann-Herder-Straße 5, 79104 Freiburg,] (ORCID:0000000208092355)·Ozaki, N. [Graduate School of Engineering Science, Osaka University 32 , 1-3 Machikaneyama Toyonaka, Osaka 560-8531,] (ORCID:0000000273209871)·Pandolfi, S. [Sorbonne Université, Muséum National d’Histoire Naturelle, UMR CNRS 7590, Insitut de Minéralogie, de Physique, des Matériaux, et de Cosmochinie, IMPMC 20 , Paris 75005,] (ORCID:0000000308559434)·Pelka, A. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0009000133085376)·Pereira, K. A. [Department of Chemistry, University of Massachusetts Amherst 33 , 690 N. Pleasant St., Physical Sciences Building, Amherst, Massachusetts 01003-9303,] (ORCID:0000000222522999)·Phillips, J. P. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0000000324720144)·Prescher, C. [Institut für Geo- und Umweltnaturwissenschaften, Albert-Ludwigs-Universität Freiburg 31 , Hermann-Herder-Straße 5, 79104 Freiburg,] (ORCID:0000000295561032)·Preston, T. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000312282263)·Randolph, L. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:000000019587404X)·Ranjan, D. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0000000286414794)·Ravasio, A. [Ecole Polytechnique, Palaiseau, Laboratoire pour l’utilisation des lasers intenses (LULI), CNRS UMR 7605 2 , Route de Saclay, 91128 Palaiseau Cedex,] (ORCID:0000000220776493)·Rips, J. [Universität Rostock, Institut für Physik 28 , D-18051 Rostock,] (ORCID:0009000247645618)·Santamaria-Perez, D. [Departamento de Fisica Aplicada—ICMUV, Universidad de Valencia—UV 19 , C/Dr. Moliner 50 Burjassot, E-46100 Valencia,] (ORCID:0000000211195056)·Savage, D. J. [Los Alamos National Laboratory 9 , Los Alamos, New Mexico 87545,] (ORCID:0000000199732030)·Schoelmerich, M. [Paul Scherrer Institut 34 , Forschungsstrasse 111, 5232 Villigen,] (ORCID:0000000247901565)·Schwinkendorf, J.-P. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0009000287037641)·Singh, S. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000202869549)·Smith, J. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000993340509)·Smith, R. F. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000256755731)·Sollier, A. [CEA, DAM, DIF 35 , 91297 Arpajon,; Université Paris-Saclay, CEA, Laboratoire Matière en Conditions Extrêmes 36 , 91680 Bruyères-le-Châtel,] (ORCID:000000015067954X)·Spear, J. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000149335325)

Abstract

We present a model of x-ray thermal diffuse scattering (TDS) from a cubic polycrystal with an arbitrary crystallographic texture, based on the classic approach of Warren [B. E. Warren, Acta Crystallogr. 6, 803 (1953)]. We compare the predictions of our model with femtosecond x-ray diffraction patterns gathered from ambient and dynamically compressed rolled copper foils obtained at the High Energy Density instrument of the European X-Ray Free-Electron Laser facility and find that the texture-aware TDS model yields more accurate results than does the conventional powder model owed to Warren. Nevertheless, we further show: with sufficient angular detector coverage, the TDS signal is largely unchanged by sample orientation and in all cases strongly resembles the signal from a perfectly random powder; shot-to-shot fluctuations in the TDS signal resulting from grain-sampling statistics are at the percent level, in stark contrast to the fluctuations in the Bragg-peak intensities (which are over an order of magnitude greater); and TDS is largely unchanged even following texture evolution caused by compression-induced plastic deformation. We conclude that TDS is robust against texture variation, making it a flexible temperature diagnostic applicable just as well to off-the-shelf commercial foils as to ideal powders.

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BibTeXRIS

Heighway, P. G. [Univ. of Oxford (United Kingdom); et al.] (ORCID:0000000162210650), Peake, D. J. [Department of Physics, Clarendon Laboratory, University of Oxford 1 , Parks Road, Oxford OX1 3PU,] (ORCID:0000000259926954), Stevens, T. [Department of Physics, Clarendon Laboratory, University of Oxford 1 , Parks Road, Oxford OX1 3PU,] (ORCID:0009000683553509), Wark, J. S. [Department of Physics, Clarendon Laboratory, University of Oxford 1 , Parks Road, Oxford OX1 3PU,] (ORCID:0000000330553223), Albertazzi, B. [Ecole Polytechnique, Palaiseau, Laboratoire pour l’utilisation des lasers intenses (LULI), CNRS UMR 7605 2 , Route de Saclay, 91128 Palaiseau Cedex,], Ali, S. J. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000318233788), Antonelli, L. [School of Physics, Engineering and Technology, University of York 4 , Heslington, York YO10 5DD,] (ORCID:000000030694948X), Armstrong, M. R. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000323751491), Baehtz, C. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:000000031480511X), Ball, O. B. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000252150153), Banerjee, S. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:000000019407477X), Belonoshko, A. B. [Frontiers Science Center for Critical Earth Material Cycling, School of Earth Sciences and Engineering, Nanjing University 8 , Nanjing 210023,], Bolme, C. A. [Los Alamos National Laboratory 9 , Los Alamos, New Mexico 87545,] (ORCID:000000021880271X), Bouffetier, V. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000160791260), Briggs, R. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000345885802), Buakor, K. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000302572822), Butcher, T. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000309095982), Di Dio Cafiso, S. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,], Cerantola, V. [Dipartimento di Scienze dell’Ambiente e della Terra, Università degli Studi di Milano Bicocca 11 , Piazza della Scienza 1e4, I-20126 Milano,] (ORCID:0000000228082963), Chantel, J. [Univ. Lille, CNRS, INRAE, Centrale Lille, UMR 8207—UMET—Unité Matériaux et Transformations 12 , F-59000 Lille,] (ORCID:0000000283329033), Di Cicco, A. [School of Science and Technology—Physics Division, Università di Camerino 13 , 62032 Camerino,], Coleman, A. L. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000256924400), Collier, J. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000120030472), Collins, G. [Laboratory for Laser Energetics (LLE), University of Rochester 14 , 250 East River Road, Rochester, New York 14623-1299,] (ORCID:0000000154366866), Comley, A. J. [Atomic Weapons Establishment (AWE), Materials Science and Research Division (MSRD) 15 , Aldermaston, Berkshire RG7 4PR,] (ORCID:000900022580653X), Coppari, F. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000315923898), Cowan, T. E. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:000000025845000X), Cristoforetti, G. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica, CNR—INO) 16 , Largo Enrico Fermi, 6, 50125 Firenze FI,] (ORCID:0000000194209080), Cynn, H. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000346585764), Descamps, A. [School of Mathematics and Physics, Queen’s University Belfast 17 , University Road, Belfast BT7 1NN,] (ORCID:0000000317086376), Dorchies, F. [Université de Bordeaux, CNRS, CEA, CELIA, UMR 5107 18 , F-33400 Talence,] (ORCID:0000000259229585), Duff, M. J. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,], Dwivedi, A. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0009000874970444), Edwards, C. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,], Eggert, J. H. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000157307108), Errandonea, D. [Departamento de Fisica Aplicada—ICMUV, Universidad de Valencia—UV 19 , C/Dr. Moliner 50 Burjassot, E-46100 Valencia,] (ORCID:0000000301894221), Fiquet, G. [Sorbonne Université, Muséum National d’Histoire Naturelle, UMR CNRS 7590, Insitut de Minéralogie, de Physique, des Matériaux, et de Cosmochinie, IMPMC 20 , Paris 75005,] (ORCID:0000000189613281), Galtier, E. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:000000020396285X), Laso Garcia, A. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0000000276710901), Ginestet, H. [Univ. Lille, CNRS, INRAE, Centrale Lille, UMR 8207—UMET—Unité Matériaux et Transformations 12 , F-59000 Lille,] (ORCID:0000000269314062), Gizzi, L. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica (CNR—INO) 22 , Via G. Moruzzi, 1-56124 Pisa,] (ORCID:0000000165726492), Gleason, A. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:0000000277365118), Goede, S. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,], Gonzalez, J. M. [Department of Physics, University of South Florida 23 , Tampa, Florida 33620,] (ORCID:0000000170389726), Gorman, M. G. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000195676166), Harmand, M. [Sorbonne Université, Muséum National d’Histoire Naturelle, UMR CNRS 7590, Insitut de Minéralogie, de Physique, des Matériaux, et de Cosmochinie, IMPMC 20 , Paris 75005,; PIMM, Arts et Metiers Institute of Technology, CNRS, Cnam, HESAM University 24 , 151 boulevard de l’Hopital, 75013 Paris,] (ORCID:0000000307135824), Hartley, N. J. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:0000000262682436), Hernandez-Gomez, C. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000595461989), Higginbotham, A. [School of Physics, Engineering and Technology, University of York 4 , Heslington, York YO10 5DD,] (ORCID:0000000152119933), Höppner, H. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0009000019295097), Humphries, O. S. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000167480422), Husband, R. J. [Deutsches Elektronen-Synchrotron DESY 25 , Notkestr. 85, 22607 Hamburg,] (ORCID:000000027666401X), Hutchinson, T. M. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000318823702), Hwang, H. [Deutsches Elektronen-Synchrotron DESY 25 , Notkestr. 85, 22607 Hamburg,] (ORCID:0000000284983811), Keen, D. A. [ISIS Facility, STFC Rutherford Appleton Laboratory 26 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0000000303762767), Kim, J. [Department of Physics, Hanyang University 27 , 17 Haengdang dong, Seongdong gu, Seoul 133-791,] (ORCID:0000000317873775), Koester, P. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica, CNR—INO) 16 , Largo Enrico Fermi, 6, 50125 Firenze FI,] (ORCID:0000000216174633), Konopkova, Z. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000189056307), Kraus, D. [Universität Rostock, Institut für Physik 28 , D-18051 Rostock,] (ORCID:0000000263504180), Krygier, A. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000161781195), Labate, L. [CNR—Consiglio Nazionale delle Ricerche, Istituto Nazionale di Ottica, CNR—INO) 16 , Largo Enrico Fermi, 6, 50125 Firenze FI,] (ORCID:0000000208044548), Lazicki, A. E. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,], Lee, Y. [Department of Earth System Sciences, Yonsei University 29 , 50 Yonsei-ro Seodaemun-gu, Seoul 03722,] (ORCID:0000000220430804), Liermann, H.-P. [Deutsches Elektronen-Synchrotron DESY 25 , Notkestr. 85, 22607 Hamburg,] (ORCID:0000000150391183), Mason, P. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0000000182409819), Masruri, M. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0000000225216241), Massani, B. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000258171780), McBride, E. E. [School of Mathematics and Physics, Queen’s University Belfast 17 , University Road, Belfast BT7 1NN,] (ORCID:0000000288216126), McGuire, C. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,], McHardy, J. D. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000226308092), McGonegle, D. [Atomic Weapons Establishment (AWE), Materials Science and Research Division (MSRD) 15 , Aldermaston, Berkshire RG7 4PR,] (ORCID:0000000153291081), McWilliams, R. S. [SUPA, School of Physics and Astronomy, and Centre for Science at Extreme Conditions, The University of Edinburgh 6 , Edinburgh EH9 3FD,] (ORCID:0000000237308661), Merkel, S. [Univ. Lille, CNRS, INRAE, Centrale Lille, UMR 8207—UMET—Unité Matériaux et Transformations 12 , F-59000 Lille,] (ORCID:000000032767581X), Morard, G. [Univ. Grenoble Alpes, Univ. Savoie Mont Blanc, CNRS, IRD, Univ. Gustave Eiffel, ISTerre 30 , 38000 Grenoble,] (ORCID:0000000242250767), Nagler, B. [SLAC National Accelerator Laboratory 21 , 2575 Sand Hill Road, Menlo Park, California 94025,] (ORCID:0009000257367842), Nakatsutsumi, M. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000308684745), Nguyen-Cong, K. [Department of Physics, University of South Florida 23 , Tampa, Florida 33620,] (ORCID:0000000342996208), Norton, A.-M. [School of Physics, Engineering and Technology, University of York 4 , Heslington, York YO10 5DD,] (ORCID:0000000177120615), Oleynik, I. I. [Department of Physics, University of South Florida 23 , Tampa, Florida 33620,] (ORCID:0000000253486484), Otzen, C. [Institut für Geo- und Umweltnaturwissenschaften, Albert-Ludwigs-Universität Freiburg 31 , Hermann-Herder-Straße 5, 79104 Freiburg,] (ORCID:0000000208092355), Ozaki, N. [Graduate School of Engineering Science, Osaka University 32 , 1-3 Machikaneyama Toyonaka, Osaka 560-8531,] (ORCID:0000000273209871), Pandolfi, S. [Sorbonne Université, Muséum National d’Histoire Naturelle, UMR CNRS 7590, Insitut de Minéralogie, de Physique, des Matériaux, et de Cosmochinie, IMPMC 20 , Paris 75005,] (ORCID:0000000308559434), Pelka, A. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0009000133085376), Pereira, K. A. [Department of Chemistry, University of Massachusetts Amherst 33 , 690 N. Pleasant St., Physical Sciences Building, Amherst, Massachusetts 01003-9303,] (ORCID:0000000222522999), Phillips, J. P. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0000000324720144), Prescher, C. [Institut für Geo- und Umweltnaturwissenschaften, Albert-Ludwigs-Universität Freiburg 31 , Hermann-Herder-Straße 5, 79104 Freiburg,] (ORCID:0000000295561032), Preston, T. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:0000000312282263), Randolph, L. [European XFEL 10 , Holzkoppel 4, 22869 Schenefeld,] (ORCID:000000019587404X), Ranjan, D. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0000000286414794), Ravasio, A. [Ecole Polytechnique, Palaiseau, Laboratoire pour l’utilisation des lasers intenses (LULI), CNRS UMR 7605 2 , Route de Saclay, 91128 Palaiseau Cedex,] (ORCID:0000000220776493), Rips, J. [Universität Rostock, Institut für Physik 28 , D-18051 Rostock,] (ORCID:0009000247645618), Santamaria-Perez, D. [Departamento de Fisica Aplicada—ICMUV, Universidad de Valencia—UV 19 , C/Dr. Moliner 50 Burjassot, E-46100 Valencia,] (ORCID:0000000211195056), Savage, D. J. [Los Alamos National Laboratory 9 , Los Alamos, New Mexico 87545,] (ORCID:0000000199732030), Schoelmerich, M. [Paul Scherrer Institut 34 , Forschungsstrasse 111, 5232 Villigen,] (ORCID:0000000247901565), Schwinkendorf, J.-P. [Helmholtz-Zentrum Dresden-Rossendorf (HZDR) 5 , Bautzner Landstraße 400, 01328 Dresden,] (ORCID:0009000287037641), Singh, S. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000202869549), Smith, J. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000993340509), Smith, R. F. [Lawrence Livermore National Laboratory 3 , Livermore, California 94550,] (ORCID:0000000256755731), Sollier, A. [CEA, DAM, DIF 35 , 91297 Arpajon,; Université Paris-Saclay, CEA, Laboratoire Matière en Conditions Extrêmes 36 , 91680 Bruyères-le-Châtel,] (ORCID:000000015067954X), Spear, J. [Central Laser Facility (CLF), STFC Rutherford Appleton Laboratory 7 , Harwell Campus, Didcot OX11 0QX,] (ORCID:0009000149335325). 2025-10-21. X-ray thermal diffuse scattering as a texture-robust temperature diagnostic for dynamically compressed solids. https://doi.org/10.1063/5.0295250

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Noncollinear polar magnet Fe 2 (SeO 3 ) 3 (H 2 O) 3 with inequivalent Fe 3+ sites

The emergence of novel magnetic states becomes more likely when the inversion symmetry of the crystal field, relative to the center between two spins, is broken. We propose that placing magnetic spins in inequivalent sites in a polar lattice can promote a realization of nontrivial magnetic states and associated magnetic properties. To test our hypothesis, we study Fe 2 (SeO 3 )(H 2 O) 3 as a model system that displays two distinct Fe(1) and Fe(2) magnetic sites in a polar structure (R3c space group). At low fields μ 0 H≤ 0.06 T, the material undergoes an antiferromagnetic ordering with T N1 = 77 K and a second transition at T N2 ≈ 4 K. At μ 0 H≥ 0.06 T and 74 K ≤T≤ 76 K, a positive entropy change of ∼0.12 mJ mol −1 K −1 can be associated with a metamagnetic transition to possibly nontrivial spin states. At zero field, Fe(1) is nearly fully ordered at T≈ 25 K, while Fe(2) features magnetic frustration down to T = 4 K. The magnetic ground state, a result corroborated by single-crystal neutron diffraction and 57 Fe Mössbauer spectroscopy, is a noncollinear antiparallel arrangement of ferrimagnetic Fe(1)–Fe(2) dimers along the c-axis. The results demonstrate that placing distinct magnetic sites in a polar crystal lattice can enable a new pathway to modifying spin, orbital, and lattice degrees of freedom for unconventional magnetism.

Crystal lattices