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DOE OSTI · 3028358

Ion dynamics in hexagonal boron nitride ionogel electrolytes

de Araujo Lima e Souza, Giselle [Hunter College, CUNY, New York, NY (United States)] (ORCID:0000000192125334)·Acero, Moises [Hunter College, CUNY, New York, NY (United States)] (ORCID:0009000941376585)·Pelegano-Titmuss, Emilia [Hunter College, CUNY, New York, NY (United States)] (ORCID:0009000025383405)·Stallworth, Phillip [Hunter College, CUNY, New York, NY (United States)] (ORCID:0000000242100531)·Thomas, Cory M. [Northwestern University, Evanston, IL (United States)] (ORCID:0009000850132550)·Hersam, Mark C. [Northwestern University, Evanston, IL (United States)] (ORCID:0000000341201426)·Oliveira Sebastião, Pedro José [Universidade de Lisboa (Portugal)] (ORCID:0000000164503019)·Greenbaum, Steven [Hunter College, CUNY, New York, NY (United States)] (ORCID:0000000154975274)
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Abstract

Ionogel electrolytes incorporating exfoliated hexagonal boron nitride (hBN) nanoplatelets are promising materials for next-generation energy storage systems. However, detailed understanding of their ion transport properties at the molecular level remains limited. This study employs diffusion and relaxation nuclear magnetic resonance (NMR) techniques, including fast-field cycling (FFC) NMR, to investigate the dynamics of ionic species in hBN-ionogels. By spanning a broad frequency range from 30 kHz using FFC NMR to high-field NMR (500–800 MHz), we reveal distinct relaxation mechanisms governing ion dynamics in ionogels with and without lithium salts. Our results highlight the role of hBN in modulating molecular rotation and translational motion, significantly affecting 1 H and 19 F relaxation profiles. The presence of Li + alters the dynamic behavior in ionogels, enhancing anion mobility at the interface. Notably, 7 Li relaxation reveals strong interactions with the hBN surface that cannot be detected by diffusion NMR. Furthermore, these findings underscore the importance of spanning a broad frequency range in NMR studies of ionogels and provide critical insights into optimizing their design as novel electrolytes.

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ElectrolytesEnergy storageIonic liquidsIonogelMolecular dynamicsNanoplateletNuclear magnetic resonanceTransport properties

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de Araujo Lima e Souza, Giselle [Hunter College, CUNY, New York, NY (United States)] (ORCID:0000000192125334), Acero, Moises [Hunter College, CUNY, New York, NY (United States)] (ORCID:0009000941376585), Pelegano-Titmuss, Emilia [Hunter College, CUNY, New York, NY (United States)] (ORCID:0009000025383405), Stallworth, Phillip [Hunter College, CUNY, New York, NY (United States)] (ORCID:0000000242100531), Thomas, Cory M. [Northwestern University, Evanston, IL (United States)] (ORCID:0009000850132550), Hersam, Mark C. [Northwestern University, Evanston, IL (United States)] (ORCID:0000000341201426), Oliveira Sebastião, Pedro José [Universidade de Lisboa (Portugal)] (ORCID:0000000164503019), Greenbaum, Steven [Hunter College, CUNY, New York, NY (United States)] (ORCID:0000000154975274). 2025-06-06. Ion dynamics in hexagonal boron nitride ionogel electrolytes. https://doi.org/10.1063/5.0271227

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