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DOE OSTI · 3377055

Determining Drying Conditions to Mitigate Hanford Double Shell Storage Tank Underside Corrosion — Phase 1

Abstract

The Hanford Site in Washington State has legacy radiological waste that is being retrieved from single shell tanks (SSTs) and transferred to newer, double shell tanks (DSTs) for eventual closure of the SSTs. The waste is maintained in the DSTs until eventual immobilization can be performed at the Waste Treatment and Immobilization Plant (WTP), currently under construction. Until full immobilization is complete, extended service of the DSTs must be ensured by mitigating corrosion of the steel tank walls and buried steel pipelines. A Pit Air Supply System has been developed to mitigate corrosion of the leak detection pits connected to the concrete foundations of the DSTs. The objectives for the present study are: (i) to corrode steel specimens in an electrolytic simulant to form artificial pits with specific pit depths, and (ii) to determine the temperature and humidity levels that will mitigate further pit growth. Experimental work and results will be presented to evaluate conditions associated with the PASS system and predict corrosion rates when the PASS is operating.

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BibTeXRIS

Benjamin, Barkai [Savannah River National Laboratory (SRNL), Aiken, SC (United States)], Sykes, Kiana [Savannah River National Laboratory (SRNL), Aiken, SC (United States)], Shukla, Pavan K. [Savannah River National Laboratory (SRNL), Aiken, SC (United States)], Fatima, Tasnia [Savannah River National Laboratory (SRNL), Aiken, SC (United States)], Fuentes, Roderick E. [Savannah River National Laboratory (SRNL), Aiken, SC (United States)], Wiersma, Bruce J. [Savannah River National Laboratory (SRNL), Aiken, SC (United States)], Giardot, Crystal [Hanford Site (HNF), Richland, WA (United States)], Page, Jason [Hanford Site (HNF), Richland, WA (United States)], Campbell, Shawn [Hanford Site (HNF), Richland, WA (United States)]. 2026-07-09. Determining Drying Conditions to Mitigate Hanford Double Shell Storage Tank Underside Corrosion — Phase 1. https://www.osti.gov/biblio/3377055

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Determining the Efficiency of Nitrogen Blanketing to Mitigate Corrosion in Hanford’s Transfer Line System

The Hanford site stores large quantities of radioactive waste in underground, carbon-steel, double-shell tanks. The waste is transferred between the tanks using piping that consists of carbon-steel pipes and carbon-steel encasements. The transfer lines have shown extensive corrosion on both the interior of the casing and exterior of the carrier pipes. Nitrogen blanketing, used to displace the oxygen in the transfer lines, was hypothesized to reduce the corrosion of the transfer lines. Experimental studies were conducted to investigate the effect of oxygen concentration on the corrosion rate and the initiation of pitting on carbon steel. The results indicated that controlling the oxygen concentration to 0% effectively mitigates corrosion. However, at 5 vol% oxygen, a significant increase in the general corrosion rate and pitting corrosion is observed.

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