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DOE OSTI · 3675834

Cyclobutane-linked nanothreads through thermal and photochemically mediated polymerization of cyclohexadiene

Murphy, Morgan·Xu, Bohan·Rank, Katie·Wu, Sikai·Huss, Steven·Badding, John·Lopez, Steven (ORCID:0000000284183638)·Crespi, Vincent·Elacqua, Elizabeth (ORCID:0000000212399560)
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Abstract

We present the pressure-induced polymerization of 1,4-cyclohexadiene, wherein thermal methods may access multiple reaction pathways. In contrast, light enables solely cyclobutane-based nanothreads to arise from a single viable reaction pathway.

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Murphy, Morgan, Xu, Bohan, Rank, Katie, Wu, Sikai, Huss, Steven, Badding, John, Lopez, Steven (ORCID:0000000284183638), Crespi, Vincent, Elacqua, Elizabeth (ORCID:0000000212399560). 2025-01-01. Cyclobutane-linked nanothreads through thermal and photochemically mediated polymerization of cyclohexadiene. https://doi.org/10.1039/d5py00470e

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DOE OSTI2024

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