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At least 181 records · Page 10

Mass spectrometric investigation of the vaporization of sodium and potassium chromates: Preliminary results

Knudsen cell mass spectrometry was used to study the vaporization of sodium and potassium chromates. For both salts, the vaporization proceeds predominately by the reactions M2CrO4(c)=2M(g)+5/4O2(g)+1/2 Cr203(s) and M2CrO4(c)=M2CrO4(g) where M = Na or K. The distribution of the ions M(+), O2(+) and M2CrO4(+) in the measured mass spectrum was found to depend on the material used for the Knudsen cell, even for materials such as platinum and gold. In the case of sodium chromate, the decomposition reaction appears to be less important than the molecular vaporization reaction. A preliminary value of 72 kcal/mole at 1141 K was measured for the heat of the molecular vaporization reaction for sodium chromate. In the case of potassium chromate, it has not been possible to conclude which mode of vaporization dominates. For potassium chromate a value of 101 kcal/mole at 1173 K was obtained for the heat of the molecular vaporization reaction.

Stearns, C. A.↗

The application of photovoltaic roof shingles to residential and commercial buildings

The recent development of a shingle-type solar-cell module makes it possible to incorporate easily photovoltaic power generation into the sloping roofs of residential or commercial buildings. These modules, which use a closely packed array of nineteen 53-mm-diameter circular solar cells, are capable of producing 101 watts/sq m of module area under standard operating conditions. This module performance is achievable by the use of solar cells with an average efficiency of 13.3 percent at 1 kW/sq m air-mass-1.5 insolation and at a cell temperature of 28 C. When these modules are mounted on a sloping south-facing roof which is insulated on the rear surface, the annual energy generated at the maximum power operating point will vary from 255.6 to 137.3 kWh/sq m of module area depending on the site location, with Albuquerque, NM, and Seattle, WA, representing the highest and lowest values of the thirteen sites considered.

Shepard, N. F., Jr.↗

Far-infrared observations of optical emission-line stars - Evidence for extensive cool dust clouds

Far-infrared observations (40-160 microns) of eight optical emission-line stars are presented. Six of these stars, LkH-alpha 198, T Tau, LkH-alpha 101, V380 Ori, R Mon, and MWC 1080, show substantially more far-infrared emission than would be expected on the basis of a blackbody extrapolation of their 10-20-micron fluxes. Additionally, in three cases, the far-infrared emission is shown to be spatially extended (greater than 40 arcsec). A simple model of the thermal emission from cool circumstellar dust (30-70 K) shows that these stars are surrounded by material left over from the star formation process; this result confirms the extreme youth of these stars. MWC 349 was detected at a level consistent with the expected free-free flux from its surrounding H II region, and RY Tau was not detected in the far-infrared; there is little circumstellar dust with temperatures of 20-100 K in these objects.

Harvey, P. M.↗

Performance, emissions, and physical characteristics of a rotating combustion aircraft engine, supplement A

Testing was conducted using the basic RC2-75 engine, to which several modifications were incorporated which were designed to reduce the hydrocarbon emissions and reduce the specific fuel consumption. The modifications included close-in surface gap spark plugs, increased compression ratio rotors, and provisions for utilizing either side or peripheral intake ports, or a combination of the two if required. The proposed EPA emissions requirements were met using the normal peripheral porting. The specific fuel economy demonstrated for the modified RC2-75 was 283 g/kW-hr at 75% power and 101 brake mean effective pressure (BMEP) and 272.5 g/kW-hr at 75% power and 111 BMEP. The latter would result from rating the engine for takeoff at 285 hp and 5500 rpm, instead of 6000 rpm.

Lamping, R. K.↗

Effect of impact damage and holes on the compressive strength of a graphite/epoxy laminate

An experimental investigation has been conducted to determine the effect of low-velocity impact damage and unloaded circular holes on the compressive strength of a 48-ply orthotropic graphite/epoxy flat laminate. Specimens were impacted by a 1.27-cm-diameter aluminum sphere with speeds from 52 to 101 m/x to simulate momenta typical of low-velocity impact hazards that can occur in commercial aircraft service. It is shown that low-velocity impact damage can significantly degrade the static compressive strength of the laminate. Specimens that fail at axial strains above 0.008 in the undamaged condition can fail at strains as low as 0.0031 when impacted at 100 m/s. Circular holes also reduce the static compressive strength of the laminate. The failure strain decreases as the hole diameter increases.

Starnes, J. H., Jr.↗

3500-hour durability testing of ceramic materials for automotive gas turbine engines

A two-year durability program was performed by AiResearch Phoenix to evaluate four commercially available ceramic materials under simulated automotive gas turbine combustor discharge conditions. These conditions included extended cyclic thermal exposures up to 2500 F and 3500 hr. The four materials selected for evaluation were Norton NCX-34 hot pressed silicon nitride, AiResearch RBN 101 reaction bonded silicon nitride, Carborundum pressureless sintered alpha-SiC and Pure Carbon Co. (British Nuclear Fuels, Ltd.) Refel reaction sintered silicon carbide. These materials were initially exposed to 350 hr/1750 cycles at 1200 and 1370 C. Subsequent exposures to 1050, 2100 and 3500 hr were performed on those materials maintaining 50% of baseline strength after the initial exposure. Additional evaluations of exposed bars included dimensional and weight changes, dye penetrant, specific damping capacity changes, SEM fractography, and X-ray diffraction.

Carruthers, W. D.↗

Role of the middle ear muscle apparatus in mechanisms of speech signal discrimination

A method of impedance reflexometry was used to examine 101 students with hearing impairment in order to clarify the interrelation between speech discrimination and the state of the middle ear muscles. Ability to discriminate speech signals depends to some extent on the functional state of intraaural muscles. Speech discrimination was greatly impaired in the absence of stapedial muscle acoustic reflex, in the presence of low thresholds of stimulation and in very small values of reflex amplitude increase. Discrimination was not impeded in positive AR, high values of relative thresholds and normal increase of reflex amplitude in response to speech signals with augmenting intensity.

Moroz, B. S.↗

Laser velocimetry technique applied to the Langley 0.3 meter transonic cryogenic tunnel

A low power laser velocimeter operating in the forward scatter mode was used to measure free stream mean velocities in the Langley 0.3 Meter Transonic Cryogenic Tunnel. Velocity ranging from 51 to 235 m/s was measured. Measurements were obtained for a variety of nominal tunnel conditions: Mach numbers from 0.20 to 0.77, total temperatures from 100 to 250 K, and pressures from 101 to 152 kPa. Particles were not injected to augment the existing Mie scattering materials. Liquid nitrogen droplets were the existing liqht scattering material. Tunnel vibrations and thermal effects had no detrimental effects on the optical system.

Gartrell, L. R.↗

Comparison of theoretical predictions of orbiter airloads with wind tunnel and flight test results for a Mach number of 0.52

The measurement and prediction of wing airloads for space shuttle orbiter 101 during approach and landing tests is discussed. Strain gage instrumentation, calibration, and flight data processing are covered along with wind tunnel and simulator results. The generation of theoretical predictions using the FLEXSTAB computer program is described, and the results are compared to experimental measurements.

Carter, A. L.↗

Galileo probe forebody thermal protection - Benchmark heating environment calculations

Solutions are presented for the aerothermal heating environment for the forebody heatshield of candidate Galileo probe. Entry into both the nominal and cool-heavy model atmospheres were considered. Solutions were obtained for the candidate heavy probe with a weight of 310 kg and a lighter probe with a weight of 290 kg. In the flowfield analysis, a finite difference procedure was employed to obtain benchmark predictions of pressure, radiative and convective heating rates, and the steady-state wall blowing rates. Calculated heating rates for entry into the cool-heavy model atmosphere were about 60 percent higher than those predicted for the entry into the nominal atmosphere. The total mass lost for entry into the cool-heavy model atmosphere was about 146 kg and the mass lost for entry into the nominal model atmosphere was about 101 kg.

Balakrishnan, A.↗

Irrigation market for solar thermal parabolic dish systems

The potential size of the onfarm-pumped irrigation market for solar thermal parabolic dish systems in seven high-insolation states is estimated. The study is restricted to the displacement of three specific fuels: gasoline, diesel and natural gas. The model was developed to estimate the optimal number of parabolic dish modules per farm based on the minimum cost mix of conventional and solar thermal energy required to meet irrigation needs. The study concludes that the potential market size for onfarm-pumped irrigation applications ranges from 101,000 modules when a 14 percent real discount rate is assumed to 220,000 modules when the real discount rate drops to 8 percent. Arizona, Kansas, Nebraska, New Mexico and Texas account for 98 percent of the total demand for this application, with the natural gas replacement market accounting for the largest segment (71 percent) of the total market.

Habib-Agahi, H.↗

Control of interface reactions in SIC/TI composites

The reaction between a 0.5 to 1.0 Al film and a thick Ti substrate to form TiAl3 occurs very rapidly on heating to 635 C and causes the Al to be confined to the surface region. After heating to 900 C Ti3Al is formed with little release of Al into alpha Ti. Further annealing at 900 C eventually causes the Ti3Al phase to decompose and a substantial amount of Al is released into alpha Ti. The interdiffusion coefficient for Al in alpha Ti at 900 C increases by less than one order of magnitude as Al is varied from 0 to 20 at %. These data were obtained from the (101) X-ray diffraction intensity band using polycrystalline samples. Improvements in the analysis of X-ray diffraction data for the determination of composition profiles are discussed.

Houska, C. R.↗

Buckling test of a 3-meter-diameter corrugated graphite-epoxy ring-stiffened cylinder

A three m diameter by three m long corrugated cylindrical shell with external stiffening rings was tested to failure by buckling. The corrugation geometry for the graphite epoxy composite cylinder wall was optimized to withstand a compressive load producing an ultimate load intensity of 157.6 kN/m without buckling. The test method used to produce the design load intensity was to mount the specimen as a cantilevered cylinder and apply a pure bending moment to the end. A load introduction problem with the specimen was solved by using the BOSOR 4 shell of revolution computer code to analyze the shell and attached loading fixtures. The cylinder test loading achieved was 101 percent of design ultimate, and the resulting mass per unit of shell wall area was 1.96 kg/sq m.

Davis, R. C.↗

Ellipsoidal corrections for geoid undulation computations using gravity anomalies in a cap

Ellipsoidal correction terms have been derived for geoid undulation computations when the Stokes equation using gravity anomalies in a cap is combined with potential coefficient information. The correction terms are long wavelength and depend on the cap size in which its gravity anomalies are given. Using the regular Stokes equation, the maximum correction for a cap size of 20 deg is -33 cm, which reduces to -27 cm when the Stokes function is modified by subtracting the value of the Stokes function at the cap radius. Ellipsoidal correction terms were also derived for the well-known Marsh/Chang geoids. When no gravity was used, the correction could reach 101 cm, while for a cap size of 20 deg the maximum correction was -45 cm. Global correction maps are given for a number of different cases. For work requiring accurate geoid computations these correction terms should be applied.

Rapp, R. H.↗

Solar power satellite microwave system concepts and performance considerations

The phase control system is the fundamental element in the forming, steering and control of the solar power satellite (SPS) microwave power beam. This system must in essence automatically adjust the phase at each of the transmitter's 101,552 power amplifiers to compensate for differences in transmission path lengths to the earth-based receiving antenna (rectenna). SPS phase control system requirements are discussed, taking into account system concepts, a reference system description, reference system performance, ground based phase control concepts, and ionosphere considerations. It is pointed out that the importance of determining the ionospheric effects cannot be overemphasized. The permissable power density limit through the ionosphere is a critical SPS sizing factor and the phase control system must be able to accommodate errors induced by a heated ionosphere.

Seyl, J. W.↗

Measurement of the profile of solar He I resonance lines

The analysis of data obtained by a rocket-borne helium-filled spectrometer employing a curve-of-growth technique in 1977 and 1980 is used in an investigation of the 584-A helium resonance line from the full solar disk. Between 6.5 and 13% of the Gaussian core area was found to be missing through self-reversal. Line widths from 1980 and 1977 were 101 + or - 10 mA and 128 + or - 20 mA full width at half maximum, respectively. No consistent relationship is found between the measured widths and solar activity.

Phillips, E.↗

VLA observations of mass loss from T Tauri stars

Six of 24 pre-main sequence stars surveyed with the VLA have been found to emit at 4.885 GHz. Radio maps of the six stars, V410 Tau, T Tau, DG Tau, LkH-alpha 101, L1551 IRS5, and Z CMa, show unresolved cores of less than 0.5 arcsec in most cases, along with 1-2 arcsec, faint, extended structures. Mass loss rates, derived under the assumption of uniform spherical winds, range from approximately 3 x 10 to the -7th to about 4 x 10 to the -5th solar masses/year. Because the flows are highly anisotropic, however, these estimates are to be taken only as likely upper limits.

Cohen, M.↗

Ab initio calculation of infrared intensities for hydrogen peroxide

Results of an ab initio SCF quantum mechanical study are used to derive estimates for the infrared intensities of the fundamental vibrations of hydrogen peroxide. Atomic polar tensors (APTs) were calculated on the basis of a 4-31G basis set, and used to derive absolute intensities for the vibrational transitions. Comparison of the APTs calculated for H2O2 with those previously obtained for H2O and CH3OH, and of the absolute intensities derived from the H2O2 APTs with those derived from APTs transferred from H2O and CH3OH, reveals the sets of values to differ by no more than a factor of two, supporting the validity of the theoretical calculation. Values of the infrared intensities obtained correspond to A1 = 14.5 km/mol, A2 = 0.91 km/mol, A3 = 0.058 km/mol, A4 = 123 km/mol, A5 = 46.2 km/mol, and A6 = 101 km/mol. Charge, charge flux and overlap contributions to the dipole moment derivatives are also computed.

Rogers, J. D.↗