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Late Chondritic Additions and Planet and Planetesimal Growth: Evaluation of Physical and Chemical Mechanisms

Studies of terrestrial peridotite and martian and achondritic meteorites have led to the conclusion that addition of chondritic material to growing planets or planetesimals, after core formation, occurred on Earth, Mars, asteroid 4 Vesta, and the parent body of the angritic meteorites [1-4]. One study even proposed that this was a common process in the final stages of growth [5]. These conclusions are based almost entirely on the highly siderophile elements (HSE; Re, Au, Pt, Pd, Rh, Ru, Ir, Os). The HSE are a group of eight elements that have been used to argue for late accretion of chondritic material to the Earth after core formation was complete (e.g., [6]). This idea was originally proposed because the D(metal/silicate) values for the HSE are so high, yet their concentration in the mantle is too high to be consistent with such high Ds. The HSE also are present in chondritic relative abundances and hence require similar Ds if this is the result of core-mantle equilibration. Since the work of [6] there has been a realization that core formation at high PT conditions can explain the abundances of many siderophile elements in the mantle (e.g., [7]), but such detailed high PT partitioning data are lacking for many of the HSE to evaluate whether such ideas are viable for all four bodies. Consideration of other chemical parameters reveals larger problems that are difficult to overcome, but must be addressed in any scenario which calls on the addition of chondritic material to a reduced mantle. Yet these problems are rarely discussed or emphasized, making the late chondritic (or late veneer) addition hypothesis suspect.

Righter, Kevin↗

Core-Mantle Partitioning of Volatile Elements and the Origin of Volatile Elements in Earth and Moon

Depletions of siderophile elements in mantles have placed constraints on the conditions on core segregation and differentiation in bodies such as Earth, Earth's Moon, Mars, and asteroid 4 Vesta. Among the siderophile elements there are a sub-set that are also volatile (volatile siderophile elements or VSE; Ga, Ge, In, As, Sb, Sn, Bi, Zn, Cu, Cd), and thus can help to constrain the origin of volatile elements in these bodies, and in particular the Earth and Moon. One of the fundamental observations of the geochemistry of the Moon is the overall depletion of volatile elements relative to the Earth, but a satisfactory explanation has remained elusive. Hypotheses for Earth include addition during accretion and core formation and mobilized into the metallic core, multiple stage origin, or addition after the core formed. Any explanation for volatile elements in the Earth's mantle must also be linked to an explanation of these elements in the lunar mantle. New metal-silicate partitioning data will be applied to the origin of volatile elements in both the Earth and Moon, and will evaluate theories for exogenous versus endogenous origin of volatile elements.

Righter, K.↗

Petrology and Geochemistry of Unbrecciated Harzburgitic Diogenite MIL 07001: A Window Into Vestan Geological Evolution

There is a strong case that asteroid 4 Vesta is the parent of the howardite, eucrite and diogenite (HED) meteorites. Models developed for the geological evolution of Vesta can satisfy the compositions of basaltic eucrites that dominate in the upper crust. The bulk compositional characteristics of diogenites - cumulate harzburgites and orthopyroxenites from the lower crust - do not fit into global magma ocean models that can describe the compositions of basaltic and cumulate eucrites. Recent more detailed formation models do make provision for a more complicated origin for diogenites, but this model has yet to be completely vetted. Compositional studies of bulk samples has led to the hypothesis that many diogenites were formed late by interaction of their parent melts with a eucritic crust, but those observations may alternatively be explained by subsolidus equilibration of trace elements between orthopyroxene and plagioclase and Ca-phosphate in the rocks. Differences in radiogenic Mg-26 content between diogenites and eucrites favors early formation of the former, not later formation. Understanding the origin of diogenites is crucial for understanding the petrologic evolution of Vesta. We have been doing coordinated studies of a suite of diogenites including petrologic investigations, bulk rock major and trace element studies, and in situ trace element analyses of orthopyroxene. Here we will focus on an especially unusual, and potentially key, diogenite, MIL 07001.

Mittlefehldt, D. W.↗

Ion Propulsion: An Enabling Technology for the Dawn Mission

The Dawn mission, part of NASA's Discovery Program, has as its goal the scientific exploration of the two most massive main-belt asteroids, 4 Vesta, and the dwarf planet 1 Ceres. The Dawn spacecraft was launched from the Cape Canaveral Air Force Station on September 27, 2007 on a Delta-II 7925H-9.5 rocket that placed the 1218-kg spacecraft into an Earth-escape (heliocentic) trajectory with an escape velocity of 11 km/s. On-board the spacecraft is an ion propulsion system (IPS) developed at the Jet Propulsion Laboratory which will provide an additional delta-V of approximately 11 km/s for the heliocentric transfers to each body and for all orbit transfers including orbit capture/escape and transition to the various science orbits. Deterministic thrusting to Vesta began in December 2007 and concluded with orbit capture at Vesta in July 2011. The transfer to Vesta included a Mars gravity assist flyby in February 2009 that provided an additional delta-V of 2.6 km/s and was the only post-launch mission delta-V not provided by IPS. The IPS was used during the 14 months at Vesta for all science orbit transfers and then for Vesta escape. Deterministic thrusting for Ceres began in late August 2012 with a planned arrival date at Ceres in early 2015, whereupon IPS will be used for all science orbit transfers. As of January 2013 the IPS has been operated for approximately 28,000 hours, consumed approximately 280 kg of xenon, and provided a delta-V of approximately 7.5 km/s, the most post-launch delta-V of any spacecraft yet flown. IPS performance characteristics are very close to the expected performance based on analysis and testing performed pre-launch. Use of the IPS together with a medium-priced launch vehicle enabled this high delta-V mission to be performed within the Discovery Program cost cap. This paper provides an overview of the Dawn IPS and its mission operations through departure for Ceres.

Dawn mission overview↗

In-flight Operation of the Dawn Ion Propulsion System Through Year One of Cruise to Ceres

The Dawn mission, part of NASA's Discovery Program, has as its goal the scientific exploration of the two most massive main-belt asteroids, 4 Vesta, and the dwarf planet 1 Ceres. The Dawn spacecraft was launched from the Cape Canaveral Air Force Station on September 27, 2007 on a Delta-II 7925H-9.5 rocket that placed the 1218-kg spacecraft into an Earth-escape trajectory. On-board the spacecraft is an ion propulsion system (IPS) developed at the Jet Propulsion Laboratory which will provide an additional delta- V of approximately 11 km/s for the heliocentric transfers to each body and for all orbit transfers including orbit capture/escape and transition to the various science orbits. Deterministic thrusting to Vesta began in December 2007 and concluded with orbit capture at Vesta in July 2011. The transfer to Vesta included a Mars gravity assist flyby in February 2009 that provided an additional delta-V of 2.6 km/s and was the only postlaunch mission delta-V not provided by IPS. During the mission at Vesta the IPS was used for all orbit transfers which included six different near-polar science mapping orbits. Thrusting for departure from Vesta and the start of cruise to Ceres began on July 25, 2012 with escape from Vesta occurring on September 5, 2012. To date the IPS has been operated for approximately 31,000 hours, consumed approximately 300 kg of xenon, and provided a delta-V of approximately 8.3 km/s. IPS performance characteristics are very close to the expected performance based on analysis and testing performed prelaunch. Thrusting for cruise to Ceres will continue until the spring of 2015, with a planned arrival date at Ceres in April 2015. This paper provides an overview of Dawn's mission objectives and the results of Dawn IPS mission operations from Vesta departure through the first year of cruise to Ceres.

Hayabusa spacecraft↗

Petrology of Anomalous Mafic Achondrite Polymict Breccia Pasamonte

The most common asteroidal igneous meteorites are eucrite-type basalts and gabbros - rocks composed of ferroan pigeonite and augite, calcic plagioclase, silica, ilmenite, troilite, Ca-phosphate, chromite and Fe-metal [1]. These rocks are thought to have formed on a single asteroid, widely considered to be 4 Vesta, along with howardites and diogenites [1, 2]. High precision O-isotopic analyses have shown that some eucrites have small, well-resolved O-isotopic differences from the group mean [3-5]. These Oanomalous eucrites are thought to hail from asteroidal parents that are distinct from that of eucrites [5]. Three O-anomalous eucrites are PCA 82502, PCA 91007 (paired) and Pasamonte, all of which have the same O-isotopic composition [5, 6]. Our petrologic studies have shown that PCA 82502 and PCA 91007 have well-resolved anomalies in low-Ca pyroxene Fe/Mn compared to eucrites [6]. Divalent Mn and Fe are homologous species that do not greatly fractionate during igneous processes; mafic mineral Fe/Mn can be used to fingerprint parent object sources [7]. Previous petrological studies of Pasamonte [8-10] have not yielded sufficiently precise Fe/Mn ratios to allow distinction of anomalies of the scale of those found for the PCA basalts. We have begun petrological study of Pasamonte for comparison with our results on normal and anomalous eucrites [6], and to constrain its origin.

Mittlefehldt, D. W.↗

Petrology of Igneous Clasts in Regolithic Howardite EET 87503

The howardite, eucrite and diogenite (HED) clan of meteorites is widely considered to originate from asteroid 4 Vesta, as a result of a global magma ocean style of differentiation. A global magmatic stage would allow silicate material to be well mixed, destroying any initial heterogeneity that may have been present resulting in the uniformity of eucrite and diogenite delta(exp 17)O, for example. The Fe/Mn ratio of mafic phases in planetary basalts can be diagnostic of different source bodies as this ratio is little-affected by igneous processes, so long as the oxygen and sulphur fugacities are buffered. Here, pyroxene Fe/Mn ratios in mafic clasts in howardite EET 87503 have been determined to further evaluate whether the HED parent asteroid is uniform. Uniformity would suggest that the parent asteroid was subject to homogenization prior to the formation of HED lithologies, likely through an extensive melting phase. Whereas, distinct differences may point towards heterogeneity of the parent body.

Hodges, Z. V.↗

Determination of Celestial Body Principal Axes via Gravity Field Estimation

The determination of physical parameters of celestial bodies provides critical navigational and scientific information. Determining the mass, rotation state, and density distribution is an important task of the navigation team on an operational mission. One representation of the internal density distribution, spherical harmonics, may be leveraged to compute the orientation of the principal axis frame of the celestial body, which in turn informs the dynamics of the body’s motion. Using data from NASA’s Dawn mission to the massive asteroids (1) Ceres and (4) Vesta, a method is proposed that refines the knowledge of the principal axis frame by utilizing estimated spherical harmonic coefficients. Applying an iterative rotation scheme to the solved-for body-fixed frame leads to convergence on a frame that is very close to the actual dynamical principal axis frame.

Takahashi, Yu↗

Visualization and Analysis of Data from Small-Body Missions with NASA's Solar System Treks Portals

The portals of NASA's Solar System Trek Project (SSTP) provide web-based suites of interactive visualization and analysis tools enabling mission planners, planetary scientists, students, and the general public to explore planetary surfaces as seen through the eyes of many different instruments aboard a wide range of spacecraft. The portals present a vast collection of mapped data products from past and current missions for a growing number of planetary bodies. As web-based toolsets, the portals do not require users to purchase or install any software beyond current web browsers. They feature a common user interface and are available through a single integrated website at https://trek.nasa.gov. This presentation will highlight 4 portals focusing on small bodies. We will provide an overview of established portals for (1) Ceres and (4) Vesta, and present the early capabilities for new portals being introduced for (162173) Ryugu and (101955) Bennu.

Day, Brian↗

Cardiopulmonary Inflammatory Response to Meteorite Dust Exposures - Implications for Human Health on Earth and Beyond

This year marks the 50th anniversary of Apollo 11, the first time humans set foot on the Moon. The Apollo missions not only help answer questions related to our solar system, they also highlight many hazards associated with human space travel. One major concern is the effect of extraterrestrial dust on astronaut health. In an effort to expand upon previous work indicating lunar dust is respirable and reactive, the authors initiated an extensive study evaluating the role of a particulate’s innate geochemical features (e.g., bulk chemistry, internal composition, morphology, size, and reactivity) in generating adverse toxicological responses in vitro and in vivo. To allow for a broader planetary and geochemical assessment, seven samples were evaluated: six meteorites from either the Moon, Mars, or Asteroid 4 Vesta and a terrestrial basalt analogue. Even with the relatively small geochemical differences (all samples basaltic in nature), significant difference in cardiopulmonary inflammatory markers developed in both single exposure and multiple exposure studies. More specifically: 1) the single exposure studies reveal relationships between toxicity and a meteorite sample’s origin, its pre-ejected state (weathered versus un-weathered), and geochemical features (e.g. bulk iron content) and 2) multiple exposure studies reveal a correlation with particle derived reactive oxygen species (ROS) formation and neutrophil infiltration. Extended human exploration will further increase the probability of inadvertent and repeated exposures to extraterrestrial dusts. This comprehensive dataset allows for not only the toxicological evaluation of extraterrestrial materials but also clarifies important correlations between geochemistry and health. The utilization of an array of extraterrestrial samples from Moon, Mars, and asteroid 4Vesta will enable the development of a geochemical based toxicological hazard model that can be used for: 1) mission planning, 2) rapid risk assessment in cases of unexpected exposures, and 3) evaluation of the efficacy of various in situ techniques in gauging surface dust toxicity. Furthermore, by better understanding the importance of geochemical features on exposure related health outcomes in space, it is possible to better understand of the deleterious nature of dust exposure on Earth.

Harrington, A. D.↗

Identification of Anomalous Eucrites and Diogenites by Multivariable Discriminant Analysis

Howardite, eucrite and diogenite clan (HED) is the largest magmatic achondrite group and has been suggested to be derived from asteroid (4) Vesta (e.g., [1]). Previous geochemical studies have suggested HEDs were generated by asteroid melting followed by crystallization, metamorphism, and impact [1-6]. However, numerous eucrites and diogenites have anomalous compositional, isotopic or petrological characteristics compared to the norm. This diversity might indicate more complex magma processes on the parent asteroid, or they could be linked to different parental asteroids (e.g., [5]). The former case would imply that the parent asteroid is more heterogenous than currently thought, and that our petrologic models are too simple. The latter case would increase the number of asteroids known to have formed mafic crusts, and would allow for petrological comparisons across numerous bodies. We apply multivariable discrimination analysis (MDA) to a large database of HED pyroxene analyses. This technique allows all elemental information to be considered simultaneously to facilitate identification of groupings, trends, and outliers within the dataset.

Peng, Z. X.↗

Contributions of Antarctic Meteorites in Understanding the Inner Solar System: The Interplay of Samples and Paradigms

Antarctic meteorites number nearly 50,000 in world collections, and have provided significant contributions to our understanding of the Solar System. Collections include samples from the Moon, Mars, asteroid 4 Vesta, as well as dozens or even hundreds of other bodies from the asteroid belt or near Earth objects. This 50th anniversary of the Japanese Antarctic finds from Yamato Mountains offers a chance to reflect on the contributions to planetary science. Antarctic meteorites have provided fundamental constraints on Solar System science in three major roles: A) unique samples of bodies (Mars and Vesta), B) complementary samples of bodies (Moon, together with Apollo and Luna), and C) foundational samples that have expanded the variety of known and documented materials in our sample collections. These have all contributed to the ideas and paradigms that have influenced the understanding of our Solar System.

Righter, K.↗

Exogenic Basalt on Asteroid (101955) Bennu

When rubble-pile asteroid 2008 TC3 impacted Earth on October 7, 2008, the recovered rock fragments indicated that such asteroids can contain exogenic material. However, spacecraft missions to date have only observed exogenous contamination on large, monolithic asteroids that are impervious to collisional disruption. Here we report the presence of meter-scale exogenic boulders on the surface of near-Earth asteroid (101955) Bennu - the 0.5-km, rubble-pile target of the OSIRIS-REx mission which has been spectroscopically linked to the CM carbonaceous chondrite meteorites. Hyperspectral data indicate that the exogenic boulders have the same distinctive pyroxene composition as the howardite-eucrite-diogenite (HED) meteorites that come from (4) Vesta, a 525-km diameter asteroid that has undergone differentiation and extensive igneous processing. Delivery scenarios include the infall of Vesta fragments directly onto Bennu or indirectly onto Bennu’s parent body, where the latter’s disruption created Bennu from a mixture of endogenous and exogenic debris. Our findings demonstrate that rubble-pile asteroids can preserve evidence of inter-asteroid mixing that took place at macroscopic scales well after planetesimal formation ended. Accordingly, the presence of HED-like material on the surface of Bennu provides previously unrecognized constraints on the collisional and dynamical evolution of the inner main belt.

Asteroids↗

Development Towards Stable Chlorine Isotope Measurements of Astromaterials Using the Modified Middleton Source of an Accelerator Mass Spectrometer

The volatile element Cl can be lost during the formation and evolution of planetary bodies, leading to fractionation of its two stable isotopes 35Cl and 37Cl. Chlorine isotope variations (reported as δ37Cl in parts per thousand (‰) relative to Standard Mean Ocean Chloride, SMOC) are documented to exceed 80‰ between different lunar rock samples and have been variably interpreted as the fingerprint of degassing during accretion, magma ocean, or volcanic portions of lunar history. The large intersample and intrasample variations observed by both bulk isotope ratio mass spectrometry (IRMS) and in-situ secondary ion mass spectrometry (SIMS) methods are difficult to interpret in part because of a paucity of bulk Cl isotope measurements. This lack of high-precision bulk data is due to the relative rarity of IRMS laboratories capable of making these high precision measurements on small samples of precious planetary materials such as those returned by human or robotic exploration. Here we present a new method for performing high precision δ37Cl measurements using the modified Middleton ion source of an existing accelerator mass spectrometer. For samples with as little as 1 μg Cl–the equivalent of 2–4 mm3 of a typical lunar rock sample–the average cathode accuracy is ∼1‰. Cathode reproducibility is typically ∼1‰ (2σ) for samples with at least 10 μg of Cl, increasing to ∼3–6‰ for aliquots with ∼1–2 μg Cl, similar to published SIMS results and sufficient to study astromaterials from the Moon, Mars, or 4 Vesta, which have tens of ‰ observed variations.

Tyler S. Anderson↗

Petrologic and Chemical Characterization of a Suite of Antarctic Diogenites

The origin of diogenites, ultramafic cumulates related to eucrites, is an unresolved problem [1]. Most diogenites are orthopyroxenites, a few are harzburgites [2], and some are transitional to cumulate eucrites [1, 3]. Cumulate eucrites are gabbros formed by crystal fractionation from basaltic eucrites [4]. The consensus view is that basaltic eucrites are residual melts from global-magma-ocean crystallization on their parent asteroid [4] which is plausibly Vesta [5]. However, the petrologic and compositional characteristics of diogenites seem to preclude a magma ocean origin [1, 4]. We are doing a petrologic and chemical study of new or unusual diogenites with the ultimate goals of constraining their genesis, and the geologic evolution of Vesta.

Mittlefehldt, D. W.↗

Automation and Process Improvement Enables a Small Team to Operate a Low Thrust Mission in Orbit Around the Asteroid Vesta

NASA's Dawn mission to the asteroid Vesta and dwarf planet Ceres launched September 27, 2007 and arrived at Vesta in July of 2011. This mission uses ion propulsion to achieve the necessary delta-V to reach and maneuver at Vesta and Ceres. This paper will show how the evolution of ground system automation and process improvement allowed a relatively small engineering team to transition from cruise operations to asteroid operations while maintaining robust processes. The cruise to Vesta phase lasted almost 4 years and consisted of activities that were built with software tools, but each tool was open loop and required engineers to review the output to ensure consistency. Additionally, this same time period was characterized by the evolution from manually retrieved and reviewed data products to automatically generated data products and data value checking. Furthermore, the team originally took about three to four weeks to design and build about four weeks of spacecraft activities, with spacecraft contacts only once a week. Operations around the asteroid Vesta increased the tempo dramatically by transitioning from one contact a week to three or four contacts a week, to fourteen contacts a week (every 12 hours). This was accompanied by a similar increase in activity complexity as well as very fast turn around activity design and build cycles. The design process became more automated and the tools became closed loop, allowing the team to build more activities without sacrificing rigor. Additionally, these activities were dependent on the results of flight system performance, so more automation was added to analyze the flight data and provide results in a timely fashion to feed the design cycle. All of this automation and process improvement enabled up the engineers to focus on other aspects of spacecraft operations, including spacecraft health monitoring and anomaly resolution.

ground system automation↗

Diffusion of Redox-Sensitive Elements in Basalt at Different Oxygen Fugacities

The terrestrial planets and moons of our solar system have differentiated over a range of oxygen fugacity conditions. Basalts formed from magmas on the Earth cover a range of more oxidized states (from approximately IW (iron wustite) plus 2 to approximately FMQ (fayalite-magnetite-quartz) plus 3) than crustal rocks from Mars (IW to approximately IW plus 3), and basalts from the Moon are more reduced than both, ranging from IW to IW minus 2. The small body Vesta differentiated around IW minus 4. Characterization of redox sensitive elements' diffusivities will offer insight into behavior of these elements as a function of f (fugacity of) O2 for these planetary bodies. Here, we report a systematic study of the diffusion of redox-sensitive elements in basaltic melts with varying oxygen fugacities (fO2) for trace elements, V, Nb, W, Mo, La, Ce, Pr, Sm, Eu, Gd, Ta, and W. Since fO2 is an intensive variable that is different for the reservoirs of various planets and moons in our solar system, it is important to characterize how changes in redox states will affect diffusion. We conducted experiments in a piston cylinder device at 1300 degrees Centigrade and 1 gigapascal, at the University of Rochester and NASA Johnson Space Center. We buffered some experiments at Ru-RuO2 (FMQ plus 6.00), and conducted other experiments within either a graphite or Mo capsule, which corresponds to fO2s of either FMQ minus1.2, or FMQ minus 3.00, respectively. Characterizing the diffusivities of redox sensitive elements at different fO2s is important because some elements, like Eu, have varying valence states, such as Eu (sup 2 plus) and Eu (sup 3 plus). Differences in charge and ion radii may lead to differences in diffusivities within silicate melts. This could, lead to formation of a Eu anomaly by diffusion, the magnitude of which may be controlled by the fO2. Characterization of trace element diffusion is also important in understanding trace element fractionation. We found, during the course of our investigation, that not only did the diffusivities of the redox sensitive elements change with fO2, but that the diffusivities of all other analyzed elements also changed. This indicates that not only do changes in valence influence trace elements diffusivities but that the structure of melt may have changed with varying oxygen fugacity, probably due to changes in the speciation of the major element Fe.

Szumila, I.↗

Does Vesta Have Moons?

Previous searches for moons around Vesta have found nothing to an upper limit of 22.5 magnitude, that corresponds to 44 +/- 4 m diameter assuming the same albedo as Vesta. The Dawn mission's approach phase has dedicated satellite search observations consisting of two mosaic sequences bracketing the first observations of a complete rotation of Vesta scheduled for early July, 2011. In addition, we use the approach optical navigation image sequences for initial satellite searches. We will report any findings from these observations, and upper limits of magnitude and size.

McFadden, L. A.↗