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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Development of fracture mechanics data for two hydrazine APU turbine wheel materials

The effects of high temperature, high pressure ammonia were measured on the fracture mechanics and fatigue properties of Astroloy and Rene' 41 turbine wheel materials. Also, the influence of protective coatings on these properties was investigated. Specimens of forged bar stock were subjected to LCF and HCF tests at 950 K (1250 F) and 3.4 MN/sq m (500 psig) pressure, in ammonia containing about 1.5 percent H2O. Aluminized samples (Chromizing Company's Al-870) and gold plated test bars were compared with uncoated specimens. Comparison tests were also run in air at 950 K (1250 F), but at ambient pressures. K sub IE and K sub TH were determined on surface flawed specimens in both the air and ammonia in both uncoated and gold plated conditions. Gold plated specimens exhibited better properties than uncoated samples, and aluminized test bars generally had lower properties. The fatigue properties of specimens tested in ammonia were higher than those tested in air, yet the K sub TH values of ammonia tested samples were lower than those tested in air. However, insufficient specimens were tested to develop significant design data.

Curbishley, G.↗
NASA NTRS1975

Hot corrosion evaluation of aluminide coated superalloys in support of an ASTM Round Robin program

Commercial aluminized coatings on substrates were hot corroded at 900 C in a 0.3 Mach burner rig with 5 ppm synthetic sea salt and at two cycling frequencies. Extensive post-exposure examinations were conducted on the corroded specimens such as metallography, X-ray diffraction, scanning electron microscopy, microprobe raster scans, and spectrographic analyses. Thermodynamic calculations were made of the equilibrium burner flame composition and the calculations were compared to the experimental findings. It was found that localized spalling of the coatings preceded coating failure. It is suggested that the spalling of the coatings is due to the formation of localized stresses caused by the depletion of chromium and aluminum in the coating or the enrichment of the coating with sulfur. For the materials and test conditions investigated, it was found that coating life is dependent only upon the initial coating thickness and not on the type of aluminized coating, the substrate, or the cycle frequency.

Santoro, G.↗
NASA NTRS1975

Thermodynamics and kinetics of reactions in protective coating systems

A study of the aluminization of Ni from packs containing various percentages of unalloyed Al confirmed that the surface aluminum content of specimens aluminized tends to decrease with time and consequently a simple parabolic law for the weight-gain vs. time relationship is not obeyed. The diffusivity-composition relationship in NiAl was examined, and a set of curves is presented. A numerical method for the calculation of coating dissolution rates was developed and applied to NiAl-Ni3Al type of coatings.

Gupta, B.↗
NASA NTRS1976

Coatings for directional eutectics

Significant advances have been made in the development of an environmentally stable coating for a very high strength, directionally solidified eutectic alloy designated NiTaC-13. Three duplex (two-layer) coatings survived 3,000 hours on a cyclic oxidation test (1,100 C to 90 C). These coatings were fabricated by first depositing a layer of NiCrAl(Y) by vacuum evaporation from an electron beam heated source, followed by depositing an aluminizing overlayer. The alloy after exposure with these coatings was denuded of carbide fibers at the substrate/coating interface. It was demonstrated that TaC fiber denudation can be greatly retarded by applying a carbon-bearing coating. The coating was applied by thermal spraying followed by aluminization. Specimens coated with NiCrAlCY+Al survived over 2,000 hours in the cyclic oxidation test with essentially no TaC denudation. Coating ductility was studied for coated and heat-treated bars, and stress rupture life at 871 C and 1,100 C was determined for coated and cycled bars.

Rairden, J. R.↗
NASA NTRS1976

Cryogenic Hydrogen/helium Storage and Supply System, Phase 1

An existing cryogenic tank was refurbished, microspheres were installed in the tank annulus, and the thermal performance of the unit was tested. The performance data was compared with NRC-2 multilayer insulation and low emittance aluminized surfaces installed in tanks of the same basic design. The cryogenic tank modified during the program was originally designed for the Manned Orbiting Laboratory (MOL) Program, and subsequently modified by vacuum-depositing aluminum on all annulus surfaces and leaving out the NRC-2 multilayer insulation. It is concluded that the application of aluminized-microsphere insulation is not yet very predictable for tank design purposes, especially at LH2 temperature and in the presence of a vapor-cooled shield.

Norman, R. H.↗
NASA NTRS1978

Clast assemblages of possible deep-seated /77517/ and immiscible-melt /77538/ origins in Apollo 17 breccias

Breccia samples 77517 and 77538 are composed of abundant mineral and lithic clasts set in porous, poorly sintered matrices. Clast assemblages in the two rocks are of contrasting composition and origin. Breccia 77517 has Mg-rich olivine and pyroxene and calcic plagioclase clasts, indicating limited, almost exclusively ANT-suite parentage. A significant feature is the presence of an assemblage (aluminous enstatite, forsterite, anorthite, aluminous spinel) corresponding to spinel cataclasite, a rock type of deep-seated (about 60 km) crustal origin. Breccia 77538 contains Fe-rich pyroxene and rather sodic plagioclase clasts, indicative of predominantly KREEP and/or mare derivation. An important feature is the occurrence of high-K and high-Fe lithic clasts whose compositions resemble those of immiscible-melts produced during late-stage magmatic crystallization, and which probably originated via silicate liquid immiscibility in a KREEP or mare basalt magma. Both rocks contain numerous fine-grained breccia clasts which represent material that has been modified by impact processes at or very near the moon's surface.

Warner, R. D.↗
NASA NTRS1981

Evacuation-induced pressure differentials in multilayer insulation systems

The pressure differentials induced across three types of multilayer insulation systems during evacuation have been measured and compared with values predicted using an idealized parallel plate geometric model. The systems tested were double-aluminized Mylar with a Tissuglas or silk net spacer and crinkled single-aluminized Mylar. Test samples were circular. The influence of purge gas type, layer density, sample diameter, and temperature was systematically investigated. The experimental approach was to measure the absolute pressure history and corresponding pressure differential induced across the insulation during evacuation. The measured pressure differentials were nondimensionalized and compared with those predicted by the parallel plate model as a function of Knudsen number. It was concluded that the parallel plate model is adequate for making engineering analyses. The influence of all parameters, except layer density, is well represented by the model. Representation of the influence of layer density is less satisfactory, but can be improved by modification of the flat plate model to allow for the more obvious practical nonidealities, such as crinkling, or the presence of a net spacer.

Glassford, A. P. M.↗
NASA NTRS1982

Further efforts to limit lunar internal temperatures from electrical conductivity determinations

A representative set of 18 electrical conductivity profiles consistent with lunar transfer function data in the 0.00001 to 0.001 Hz range is generated by means of a Monte Carlo procedure. Laboratory electrical conductivity vs temperature data extrapolated to lower and higher temperatures are used to convert the 18 profiles into temperature profiles for a series of radially homogeneous olivine-pyroxene mixtures ranging from 100% olivine to 100% aluminous orthopyroxene. The former yields selenotherms approaching the Ringwood-Essene solidus at depths near 500 km, while additions of the latter in concentrations greater than 15-30 vol% leads to cooler selenotherms which approach the solidus only at depths greater than about 1000 km. On the basis of independent geophysical constraints, the profile envelopes for compositions containing more than 15-30 vol% aluminous orthopyroxene are considered to be the most probable.

Hood, L. L.↗
NASA NTRS1982

Thermal performance of aircraft polyurethane seat cushions

Measurements were conducted on 7.6 x 7.6 cm samples of polyurethane seat cushion material in a modified National Bureau of Standards smoke density chamber to simulate real life conditions for an onboard aircraft fire or post-crash fire. In this study, a non-flaming heat radiation condition was simulated. Two aluminized polymeric fabrics (Norfab 11HT-26-A and Preox 1100-4) and one neoprene type material in two thicknesses (Vonar 2 and 3) were tested as heat blocking layers to protect the urethane foam from rapid heat degradation. Thermogravimetric analysis and differential scanning calorimetry were performed to characterize thermally the materials tested. It was found that Vonar 2 or 3 provided approximately equal thermal protection to F.R. urethane as the aluminized fabrics, but at a significant weight penalty. The efficiency of the foams to absorb heat per unit mass loss when protected with the heat blocking layer decreases in the heating range of 2.5-5.0 W/sq cm, but remains unchanged or slightly increases in the range of 5.0-7.5 W/sq cm. The results show that at all heat flux ranges tested the usage of a heat blocking layer in aircraft seats significantly improves their thermal performance.

Kourtides, D. A.↗
NASA NTRS1984

Apollo 16 site geology and impact melts - Implications for the geologic history of the lunar highlands

The geology of the Apollo 16 site is reconsidered on the basis of data from photogeology, geochemical remote sensing, and lunar samples. The site possesses an upper surface of anorthositic gabbro and related rocks. Mafic components were deposited as basin ejecta. The events involved in its geological evolution were the Nectaris impact and the Imbrium impact. The role of large, local craters in the history of the region was to serve as topographic depressions to accumulate basin ejecta. The most abundant melt composition at Apollo 16 is an aluminous variety of LKFM basalt supplied by the Nectaris impact as ejected basin impact melt. The mafic LKFM melt may have been supplied by the Imbrium impact. More aluminous melt groups are probably derived from local, small craters. The remainder of the deposits in the region are composed of anorthositic clastic debris derived from the Nectaris basin, the local crustal substrate, and Imbrium and other basins.

Spudis, P. D.↗
NASA NTRS1988

Enthalpies of formation of CaAl4O7 and CaAl12O19 (hibonite) by high temperature, alkali borate solution calorimetry

Enthalpies of formation were determined for two calcium aluminate phases, CaAl4O7 and CaAl12O19, using high-temperature alkali borate solution calorimetry. The aluminates were synthesized by multiple-cycle heating and grinding stoichiometric mixtures of CaCO3 and Al2O3, and the products were characteized by X-ray diffraction and SEM microbeam analysis. The data on impurities (CaAl4O7 was found to be about 89.00 percent pure by weight and the CaAl12O19 samples about 91.48 percent pure) were used to correct the heat of solution values of the synthetic products. The enthalpies of formation, at 1063 K, from oxides, were found to be equal to -(25.6 + or - 4.7) kJ/g.f.w. for CaAl4O7 and -(33.0 + or - 9.7) kJ/g.f.w. for CaAl12O19; the respective standard enthalpies of formation from elements, at 298 K, were estimated to be -4007 + or - 5.2 kJ/g.f.w. and -10,722 + or - 12 kJ/g.f.w.

Geiger, C. A.↗
NASA NTRS1989

Germanium abundances in lunar basalts - Evidence of mantle metasomatism?

To fill in gaps in the present Ge database, mare basalts were analyzed for Ge and other elements by RNAA and INAA. Mare basalts from Apollo 11, 12, 15, and 17 landing sites are rather uniform in Ge abundance, but Apollo 14 aluminous mare basalts and KREEP are enriched in Ge by factors of up to 300 compared to typical mare basalts. These Ge enrichments are not associated with other siderophile element enrichments and thus are not due to differences in the amount of metal segregated during core formation. Based on crystal-chemical and interelement variations, it does not appear that the observed Ge enrichments are due to silicate liquid immiscibility. KREEP basalt source regions may have been metasomatized, and Apollo 14 aluminous mare basalt magmas may have become enriched in Ge by interacting with these metasomatized areas. The presence of volatile- and Ge-rich regions in the moon suggest that the moon was never totally molten.

Dickinson, T.↗
NASA NTRS1986

Composite ingot casting

A method and system for continuously or semicontinuously casting a composite metal article, such as a structurally composite ingot or the like, wherein one of the principal structural components of the ingot comprises an aluminum-lithium alloy. During such casting by a D.C. (direct chill) conventional tubular mold or electromagnetic process, the aluminum-lithium structural component of a structurally composite ingot is encircled or peripherally encased by a· further outer metal cladding component that can be cast simultaneously with the aluminum-lithium component such as another outer aluminous alloy from which lithium is absent as a constituent or impurity, although it may be present and tolerated as a trace element. In this arrangement the aluminum-lithium structural component is prevented during casting from coming into direct contact with the chilling coolant, normally water, with which lithium can react violently. Only the outer aluminous alloy envelope is subjected to the direct contact of a liquid coolant whereby as it solidifies, this outer envelope or . peripheral sheath acts as an impervious secondary mold for and protects the inner aluminum--lithium alloy structural component which is then directly controllably chilled and solidified.

George J Binczewski↗
NASA NTRS1991

Impact melts in the MAC88105 lunar meteorite - Inferences for the lunar magma ocean hypothesis and the diversity of basaltic impact melts

The MAC88105 lunar meteorite, as represented by thin section 78, contains three major types of impact melt breccias. The most abundant type is clast-laden, fine-grained, and rich in Al2O3 (28 wt pct); these clasts constitute most of the meteorite. Their abundance and aluminous nature indicate that the MAC88105 source area was very aluminous. This is consistent with formation of the primordial lunar crust from a global magma ocean. The second type of impact melt is represented by only one clast in 78. It has a basaltic bulk composition similar to many other lunar impact melts, but is significantly richer in P2O5 than most and has a much lower MgO/(MgO + FeO). The third impact-melt type resembles a prominent melt group at Apollo 16, but has lower MgO/(MgO + FeO). These data show that basaltic impact melts are compositionally diverse. Dating samples of the Al-rich impact melts and the new types of basaltic impact melts from this meteorite can test the idea that the Moon suffered a terminal cataclysm 3.9 Ga ago.

Taylor, G. J.↗
NASA NTRS1993

A 10 GHz Y-Ba-Cu-O/GaAs hybrid oscillator proximity coupled to a circular microstrip patch antenna

A 10 GHz hybrid YBCO/GaAs microwave oscillator proximity coupled to a circular microstrip antenna has been designed, fabricated, and characterized. The oscillator was a reflection mode type using a GaAs MESFET as the active element. The feedline, transmission lines, RF chokes, and bias lines were all fabricated from YBCO superconducting thin films on a 1 cm x 1 cm lanthanum aluminate substrate. The output feedline of the oscillator was wire bonded to a superconducting feedline on a second 1 cm x 1 cm lanthanum aluminate substrate, which was in turn proximity coupled to a circular microstrip patch antenna. Antenna patterns from this active patch antenna and the performance of the oscillator measured at 77 K are reported. The oscillator had a maximum output power of 11.5 dBm at 77 K, which corresponded to an efficiency of 10 percent. In addition, the efficiency of the microstrip patch antenna together with its high temperature superconducting feedline was measured from 85 K to 30 K and was found to be 71 percent at 77 K, increasing to a maximum of 87.4 percent at 30 K.

Rohrer, Norman J.↗
NASA NTRS1993

A 10 GHz Y-Ba-Cu-O/GaAs hybrid oscillator proximity coupled to a circular microstrip patch antenna

A 10 GHz hybrid Y-Ba-Cu-O / GaAs microwave oscillator proximity coupled to a circular microstrip antenna was designed, fabricated and characterized. The oscillator was a reflection mode type using a GaAs MESFET as the active element. The feedline, transmission lines, RF chokes, and bias lines were all fabricated from YBa2Cu3O(7-x) superconducting thin films on a 1 cm x 1 cm lanthanum aluminate substrate. The output feedline of the oscillator was wire bonded to a superconducting feedline on a second 1 cm x 1 cm lanthanum aluminate substrate, which was in turn proximity coupled to a circular microstrip patch antenna. Antenna patterns from this active patch antenna and the performance of the oscillator measured at 77 K are reported. The oscillator had a maximum output power of 11.5 dBm at 77 K, which corresponded to an efficiency of 10 percent. In addition, the efficiency of the microstrip patch antenna together with its high temperature superconducting feedline was measured from 85 K to 30 K and was found to be 71 percent at 77 4 increasing to a maximum of 87.4 percent at 30 K.

Rohrer, Norman J.↗
NASA NTRS1993

Lunar mare volcanism: Mixing of distinct, mantle source regions with KREEP-like component

Mare basalts comprise less than 1% of the lunar crust, but they constitute our primary source of information on the moon's upper mantle. Compositional variations between mare basalt suites reflect variations in the mineralogical and geochemical composition of the lunar mantle which formed during early lunar differentiation (4.5-4.4 AE). Three broad suites of mare basalt are recognized: very low-Ti (VLT) basalts with TiO2 less than 1 wt%, low-Ti basalts with TiO2 = 2-4 wt%, and high-Ti basalts with TiO2 = 10-14 wt%. Important subgroups include the Apollo 12 ilmenite basalts (TiO2 = 5-6 wt%), aluminous low-Ti mare basalts (TiO2 = 2-4 wt%, Al2O3 = 10-14 wt%), and the newly discovered Very High potassium (VHK) aluminous low-Ti basalts, with K2O = 0.4-1.5 wt%. The mare basalt source region has geochemical characteristics complementary to the highlands crust and is generally thought to consist of mafic cumulates from the magma ocean which formed the felsic crust by feldspar flotation. The progressive enrichment of mare basalts in Fe/Mg, alkalis, and incompatible trace elements in the sequence VLT basalt yields low-Ti basalt yields high-Ti basalt is explained by the remelting of mafic cumulates formed at progressively shallower depths in the evolving magma ocean. This model is also consistent with the observed decrease in compatible element concentrations and the progressive increase in negative Eu anomalies.

Shervais, John W.↗
NASA NTRS1994

The realuminizing of the 7-meter-diameter solar simulator collimating mirror

This paper describes the modification of a three-electron-beam (EB) gun system for vacuum depositing a highly reflective aluminum coating on a 7.01-m (23-ft) -diam nickel-plated aluminum collimating mirror. The mirror is part of the JPL 7.62-m space simulator that was recently modernized with a new high vacuum pumping system, solar lamp power supplies, solar optic lens system, and refurbished collimating mirror. The 7.01-m 12,700-kg (14-ton) spherical collimating mirror was removed from this facility for replating with 381 micron (0.015 in.) of electroless nickel and polished to a specular finish for realuminizing. The space chamber served as the vacuum coating vessel for the realuminizing coating process. The mirror is the primary reflector for the solar simulation system and the aluminized reflective surface is its most critical performance element. The uniformity of thickness and high reflectivity of the coating in visible and near-ultraviolet (UV) light governs the accuracy of the beam for solar testing. The uniformity of the thin-film thickness also controls the durability of the mirror over time. The mirror was polished to a 64-percent reflectivity with a uniformity of 1.5 percent. The performance goal for the aluminizing was 89 percent with +/- 0.5-percent variation over the mirror.

Noller, E. W.↗