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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Photoionization research on atomic beams. 2: The photoionization cross section of atomic oxygen

An experiment to determine the absolute value of the photo-ionization cross section of atomic oxygen is described. The atoms are produced in an electrical discharge in oxygen gas with 1% hydrogen added. In order to prevent recombination a crossed beam technique is employed. The ions formed are detected by a time-of-flight mass spectrometer. The concentration of oxygen atoms in the beam is 57%. The measured photoionization cross section of atomic oxygen is compared with theoretical data. The results show the participation of autoionization processes in ionization. The cross section at the autoionizing levels detected is considerably higher than the absorption due to the unperturbed continuum. Except for wavelengths where autoionization occurs, the measured ionization cross section is in fair agreement with theory. This holds up to 550 A whereas for shorter wavelengths the theoretical values are much higher.

Comes, F. J.↗
NASA NTRS1987

Comments on the interaction of materials with atomic oxygen

An explanation of the relative resistance of various materials to attack by atomic oxygen is presented. Data from both ground based and on-orbit experiments is interpreted. The results indicate the importance of bond strengths, size and structure of pendant groups, and fluorination to the resistance of certain polymers to atomic oxygen. A theory which provides a partial explanation of the degradation of materials in low Earth orbit due to surface recombination of oxygen atoms is also included. Finally, a section commenting on mechanisms of material degradation is provided.

Torre, Larry P.↗
NASA NTRS1995

Effects of atomic oxygen on polymeric materials flown on EOIM-3

Diverse polymeric materials, including several variations of Kapton, were flown on STS-46 as part of the Evaluation of Oxygen Interaction with Materials Experiment (EOIM-3). These materials were flown in the cargo bay and exposed to the space environment July 31 - August 8, 1992, including 40 hours of direct atomic oxygen impingement. The atomic oxygen exposure was approximately 2.2 x 10(exp 20) atoms/sq cm. Polymeric materials flown on EOIM-3 include coated and uncoated Kapton, Tefzel ETFE, Lexan, FEP and TFE Teflon, bulk Halar and PEEK, S383 silicone and Viton elastomeric seal material. Analyses performed included thickness measurements using Dektak and eddy current methods, mass loss, resistance, permeability, hardness, and FTIR. The effects of stress and the space environment on Kapton were also evaluated. Previous EOIM missions on STS-5 and STS-8 and the Long Duration Exposure Facility also contained polymeric material samples. Data from these previous flights are shown for comparison, as well as ground simulation of space environment effects using both thermal energy flow tubes and 5 eV neutral atomic oxygen beam facilities. Reaction efficiencies for the various atomic oxygen exposure conditions are discussed.

Kamenetzky, Rachel R.↗
DOE OSTI2025

Detection of atomic oxygen and its electronic coherence decays using time-resolved ultrafast coherent Raman scattering

We report the detection of atomic oxygen and quantitative measurements of its electronic Raman coherence decays in flames and low-temperature plasmas using time-resolved hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering (CARS). Atomic oxygen was detected using the Raman transitions between the spin–orbit coupled triplet ground states. Atomic oxygen was generated in an H 2 /O 2 /Ar diffusion flame and an O 2 /Ar pulsed plasma discharge. Single exponential decays were observed for the O( 3 P 2 )–O( 3 P 1 ) Raman transition at 158.3 cm −1 and the O( 3 P 2 )–O( 3 P 0 ) Raman transition at 227 cm −1 . From the decay measurements, the atomic O Raman linewidths were obtained from 25 to 150 Torr in non-equilibrium plasma and at 760 Torr in a flame. Enhanced signal-to-noise ratios (SNRs) of atomic oxygen and atomic to molecular oxygen signal contrasts were obtained by taking advantage of electronic triplet coherence beating. Enhancement of up to seven times in the atomic O SNR was observed. Furthermore, we also found that the dephasing rates of O 2 (v = 0–3, N = 37) were similar, which provides evidence for the assumption that vibrational excitation does not influence the dephasing of diatomic molecular rotational CARS transitions.

Atomic and molecular spectroscopy↗
DOE OSTI2021

Atomic oxygen density determination in the effluent of the COST reference source using in situ effective lifetime measurements in the presence of a liquid interface

Abstract Spatially resolved, absolute densities of atomic oxygen are measured for several helium-based admixtures in the effluent of the COST Reference Microplasma Jet using two-photon absorption laser induced fluorescence (TALIF). Admixtures investigated include a helium-only admixture, four helium/oxygen admixtures (0.1 % , 0.5 % , 0.6 % , and 1.0 % oxygen), and a helium/water admixture (2500 ppm water), chosen to coincide with previously published characterizations of plasma-treated liquid. The atomic oxygen TALIF signal is calibrated for density using the noble gas xenon, which possesses a very similar two-photon excitation and fluorescence scheme. Measurements are conducted for the jet operating in ambient air with both an open effluent and a liquid surface present, allowing for comparison with liquid phase measurements conducted under similar conditions. The presence of a water surface does not appear to alter the background chemistry in the effluent but reduces O densities close to the liquid interface when compared to a similar distance from the nozzle in an open effluent case. This may be the result of a reduction in flow velocity caused by the liquid obstructing the gas flow. Additionally, measurements near the liquid surface revealed a region of atomic oxygen well outside of where the core of the effluent impinges on the liquid. This is likely relevant for applications as it considerably expands the surface area subject to O absorption. Critically, in situ measurements of the effective lifetimes of the laser-excited 3p 3 P J state of atomic oxygen were recorded in the effluent by employing a picosecond (ps) laser and a nanosecond (ns) ICCD. By experimentally determining the contribution from collisional quenching via the in situ effective lifetime measurements, significant improvements in the accuracy of the atomic oxygen density calibration were made, with differences of approximately 30 % from existing methods of estimating quenching rates at atmospheric pressure. Finally, spatially resolved atomic oxygen densities allow for an investigation of O formation and extinction pathways in the effluent and a comparison between admixtures.

laser diagnostics↗
NASA NTRS1984

An atomic oxygen facility for studying polymer materials for spacecraft applications

A nozzle beam facility utilizing microwave discharge on a helium carrier gas seeded with oxygen to produce atomic oxygen fluxes of the order of 10 to the 15th power atoms/cu cm/sec is described. In addition, limited test results obtained from exposing a graphite/epoxy composite and Kapton (H) film are presented in terms of mass loss measurements and changes in surface morphology.

Tennyson, R. C.↗
NASA NTRS1990

Atomic oxygen effects on boron nitride and silicon nitride: A comparison of ground based and space flight data

The effects of atomic oxygen on boron nitride (BN) and silicon nitride (Si3N4) were evaluated in a low Earth orbit (LEO) flight experiment and in a ground based simulation facility. In both the inflight and ground based experiments, these materials were coated on thin (approx. 250A) silver films, and the electrical resistance of the silver was measured in situ to detect any penetration of atomic oxygen through the BN and Si3N4 materials. In the presence of atomic oxygen, silver oxidizes to form silver oxide, which has a much higher electrical resistance than pure silver. Permeation of atomic oxygen through BN, as indicated by an increase in the electrical resistance of the silver underneath, was observed in both the inflight and ground based experiments. In contrast, no permeation of atomic oxygen through Si3N4 was observed in either the inflight or ground based experiments. The ground based results show good qualitative correlation with the LEO flight results, indicating that ground based facilities such as the one at Los Alamos National Lab can reproduce space flight data from LEO.

Cross, J. B.↗
NASA NTRS1992

Atomic oxygen and ultraviolet radiation mission total exposures for LDEF experiments

Atomic oxygen and solar radiation exposures were determined analytically for rows, longerons, and end bays of the LDEF. Calculated atomic oxygen exposures are based on an analytical model that accounts for the effects of thermal molecular velocity, atmospheric temperature, number density, spacecraft velocity, incidence angle, and atmospheric rotation. Results also incorporate variations in solar activity, geomagnetic index, and orbital parameters occurring over the six year flight of the spacecraft. Solar radiation exposure calculations are based on the form factors reported in the Solar Illumination Data Package prepared by NASA Langley. The earth albedo value for these calculations was based on the Nimbus 7 earth radiation data set. Summary charts for both atomic oxygen and solar radiation exposure are presented to facilitate the use of the data generated by LDEF experimenters.

Bourassa, R. J.↗
NASA NTRS1996

A technique for synergistic atomic oxygen and vacuum ultraviolet radiation durability evaluation of materials for use in LEO

Material erosion data collected during flight experiments such as the Environmental Oxygen Interaction with Materials (EOIM)-3 and the Long Duration Exposure Facility (LDEF) have raised questions as to the sensitivity of material erosion to levels of atomic oxygen exposure and vacuum ultraviolet (VUV) radiation. The erosion sensitivity of some materials such as FEP Teflon used as a thermal control material on satellites in low Earth orbit (LEO), is particularly important but difficult to determine. This is in large part due to the inability to hold all but one exposure parameter constant during a flight experiment. This is also difficult to perform in a ground based facility, because often the variation of the level of atomic oxygen or VUV radiation also results in a change in the level of the other parameter. A facility has been developed which allows each parameter to be changed almost independently and offer broad area exposure. The resulting samples can be made large enough for mechanical testing. The facility uses an electron cyclotron resonance plasma source to provide the atomic oxygen. A series of glass plates is used to focus the atomic oxygen while filtering the VUV radiation from the plasma source. After filtering, atomic oxygen effective flux levels can still be measured which are as high as 7 x 10(exp 15) atoms/cm(exp 2)-sec which is adequate for accelerated testing. VUV radiation levels after filtering can be as low as 0.3 suns. Additional VUV suns can be added with the use of deuterium lamps which allow the VUV level to be changed while keeping the flux of atomic oxygen constant. This paper discusses the facility, and results from exposure of Kapton and FEP at pre-determined atomic oxygen flux and VUV sun levels.

Rutledge, Sharon K.↗
NASA NTRS2002

Issues and Consequences of Atomic Oxygen Undercutting of Protected Polymers in Low Earth Orbit

Hydrocarbon based polymers that are exposed to atomic oxygen in low Earth orbit are slowly oxidized which results in recession of their surface. Atomic oxygen protective coatings have been developed which are both durable to atomic oxygen and effective in protecting underlying polymers. However, scratches, pin window defects, polymer surface roughness and protective coating layer configuration can result in erosion and potential failure of protected thin polymer films even though the coatings are themselves atomic oxygen durable. This paper will present issues that cause protective coatings to become ineffective in some cases yet effective in others due to the details of their specific application. Observed in-space examples of failed and successfully protected materials using identical protective thin films will be discussed and analyzed. Proposed approaches to prevent the failures that have been observed will also be presented.

Banks, Bruce A.↗
NASA NTRS2009

Use of Atomic Oxygen for Increased Water Contact Angles of Various Polymers for Biomedical Applications

The purpose of this study was to determine the effect of atomic oxygen (AO) exposure on the hydrophilicity of nine different polymers for biomedical applications. Atomic oxygen treatment can alter the chemistry and morphology of polymer surfaces, which may increase the adhesion and spreading of cells on Petri dishes and enhance implant growth. Therefore, nine different polymers were exposed to atomic oxygen and water-contact angle, or hydrophilicity, was measured after exposure. To determine whether hydrophilicity remains static after initial atomic oxygen exposure, or changes with higher fluence exposures, the contact angles between the polymer and water droplet placed on the polymer s surface were measured versus AO fluence. The polymers were exposed to atomic oxygen in a 100-W, 13.56-MHz radio frequency (RF) plasma asher, and the treatment was found to significantly alter the hydrophilicity of non-fluorinated polymers. Pristine samples were compared with samples that had been exposed to AO at various fluence levels. Minimum and maximum fluences for the ashing trials were set based on the effective AO erosion of a Kapton witness coupon in the asher. The time intervals for ashing were determined by finding the logarithmic values of the minimum and maximum fluences. The difference of these two values was divided by the desired number of intervals (ideally 10). The initial desired fluence was then multiplied by this result (2.37), as was each subsequent desired fluence. The flux in the asher was determined to be approximately 3.0 x 10(exp 15) atoms/sq cm/sec, and each polymer was exposed to a maximum fluence of 5.16 x 10(exp 20) atoms/sq cm.

deGroh, Kim↗
NASA NTRS1989

MoS2 interactions with 1.5 eV atomic oxygen

Exposures of MoS2 to 1.5-eV atomic oxygen in an anhydrous environment reveal that the degree of oxidation is essentially independent of crystallite orientation, and that the surface-adsorbed reaction products are MoO3 and MoO2. A mixture of oxides and sulfide exists over a depth of about 90 A, and this layer has a low diffusion rate for oxygen. It is concluded that a protective oxide layer forms on MoS2 on exposure to the atomic-oxygen-rich environment of LEO.

Martin, J. A.↗
NASA NTRS2002

Atomic Oxygen Protection of Materials in Low Earth Orbit

Spacecraft polymeric materials as well as polymer-matrix carbon-fiber composites can be significantly eroded as a result of exposure to atomic oxygen in low Earth orbit (LEO). Several new materials now exist, as well as modifications to conventionally used materials, that provide much more resistance to atomic oxygen attack than conventional hydrocarbon polymers. Protective coatings have also been developed which are resistant to atomic oxygen attack and provide protection of underlying materials. However, in actual spacecraft applications, the configuration, choice of materials, surface characteristics and functional requirements of quasi-durable materials or protective coatings can have great impact on the resulting performance and durability. Atomic oxygen degradation phenomena occurring on past and existing spacecraft will be presented. Issues and considerations involved in providing atomic oxygen protection for materials used on spacecraft in low Earth orbit will be addressed. Analysis of in-space results to determine the causes of successes and failures of atomic oxygen protective coatings is presented.

Banks, Bruce A.↗
NASA NTRS1992

Monte Carlo modeling of atomic oxygen attack of polymers with protective coatings on LDEF

Characterization of the behavior of atomic oxygen interaction with materials on the Long Duration Exposure Facility (LDEF) will assist in understanding the mechanisms involved, and will lead to improved reliability in predicting in-space durability of materials based on ground laboratory testing. A computational simulation of atomic oxygen interaction with protected polymers was developed using Monte Carlo techniques. Through the use of assumed mechanistic behavior of atomic oxygen and results of both ground laboratory and LDEF data, a predictive Monte Carlo model was developed which simulates the oxidation processes that occur on polymers with applied protective coatings that have defects. The use of high atomic oxygen fluence-directed ram LDEF results has enabled mechanistic implications to be made by adjusting Monte Carlo modeling assumptions to match observed results based on scanning electron microscopy. Modeling assumptions, implications, and predictions are presented, along with comparison of observed ground laboratory and LDEF results.

Banks, Bruce A.↗
NASA NTRS2019

Atomic Oxygen Erosion Data from the MISSE 2-8 Missions

Polymers and other oxidizable materials on the exterior of spacecraft in the low Earth orbit (LEO) space environment can be eroded from reaction with atomic oxygen (AO). Therefore, in order to design durable spacecraft it is important to know the extent of erosion that will occur during a mission. This can be determined by knowing the LEO AO erosion yield, E(sub y) (volume loss per incident oxygen atom), of materials susceptible to AO reaction. In addition, recent flight experiments have shown that the AO E(sub y) can vary with the AO fluence and/or solar exposure. Therefore obtaining AO E(sub y) data for materials flown on various spaceflight missions is important. NASA Glenn Research Center has flown numerous experiments as part of the Materials International Space Station Experiment (MISSE) missions on the exterior of the International Space Station to characterize the LEO E(sub y) of polymers, composites, protective coatings, and other spacecraft materials. This report provides a summary of the erosion data for ram samples from six Glenn polymer experiments flown as part of MISSE 2, 4, 6, 7, and 8. A total of 71 types of materials with 111 E(sub y) values are provided. The E(sub y) values for uncoated polymers range from 3.81×10(exp –27) cu cm/atom for DC 93-500 silicone exposed to an AO fluence of 4.62×10(exp 21) atoms/sq cm on MISSE 8 to 9.14×10(exp –24) cu cm/atom for polyoxymethylene (POM) exposed to an AO fluence of 8.43×10(exp 21) atoms/sq cm on MISSE 2. One polymer, Triton oxygen resistant, low modulus (TOR(TM) LM), experienced mass gain when exposed to an AO fluence of 2.15×10(exp 21) atoms/sq cm on MISSE 4. In many cases the same material was flown on numerous missions so that trends for E(sub y) versus AO fluence and/or solar exposure can be determined, along with temperature effects.

Erosion↗
NASA NTRS1991

Pinhole cameras as sensors for atomic oxygen in orbit; application to attitude determination of the LDEF

Images produced by pinhole cameras using film sensitive to atomic oxygen provide information on the ratio of spacecraft orbital velocity to the most probable thermal speed of oxygen atoms, provided the spacecraft orientation is maintained stable relative to the orbital direction. Alternatively, as it is described, information on the spacecraft attitude relative to the orbital velocity can be obtained, provided that corrections are properly made for thermal spreading and a co-rotating atmosphere. The LDEF orientation, uncorrected for a co-rotating atmosphere, was determined to be yawed 8.0 minus/plus 0.4 deg from its nominal attitude, with an estimated minus/plus 0.35 deg oscillation in yaw. The integrated effect of inclined orbit and co-rotating atmosphere produces an apparent oscillation in the observed yaw direction, suggesting that the LDEF attitude measurement will indicate even better stability when corrected for a co-rotating atmosphere. The measured thermal spreading is consistent with major exposure occurring during high solar activity, which occurred late during the LDEF mission.

Peters, Palmer N.↗
NASA NTRS1992

Pinhole cameras as sensors for atomic oxygen in orbit: Application to attitude determination of the LDEF

Images produced by pinhole cameras using film sensitive to atomic oxygen provide information on the ratio of spacecraft orbital velocity to the most probable thermal speed of oxygen atoms, provided the spacecraft orientation is maintained stable relative to the orbital direction. Alternatively, information on the spacecraft attitude relative to the orbital velocity can be obtained, provided that corrections are properly made for thermal spreading and a corotating atmosphere. The Long Duration Exposure Facility (LDEF) orientation, uncorrected for a corotating atmosphere, was determined to be yawed 8.0 +/- 0.4 degrees from its nominal attitude, with an estimated +/- 0.35 degree oscillation in yaw. The integrated effect of inclined orbit and corotating atmosphere produces an apparent oscillation in the observed yaw direction, suggesting that the LDEF attitude measurement will indicate even better stability when corrected for a corotating atmosphere. The measured thermal spreading is consistent with major exposure occurring during high solar activity, which occurred late during the LDEF mission.

Peters, Palmer N.↗
NASA NTRS1991

Atomic oxygen erosion of polymer matrix composites

Results are presented on atomic oxygen erosion of circular tubes and flat plates fabricated from different epoxy matrix composites containing, boron and Kevlar fiber reinforcements. The UTIAS experiment was located at station D-12, at 90 deg to the LDEF leading edge which was yawed about approximately 8 to 10 deg relative to the velocity vector. This resulted in enhanced atomic oxygen exposure at D-12, providing a total fluence of about 4 x 10(exp 20) atoms/sq cm. Thickness loss measurements were obtained for both flat plates and cylindrical tubes. The effect of reflected atomic oxygen on erosion yield and surface morphology on back surfaces (not directly exposed to AO) are graphically demonstrated. Erosion yields are also compared with other space flight data for similar materials, and ground-based tests in the UTIAS AO simulator. The effect of angle of incidence on surface morphology, erosion profiles and thickness losses are presented and the results correlated with simulator tests as well.

Tennyson, R. C.↗