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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Defect chemistry and characterization Hg(1-x)Cd(x)Te

Iodine doped single crystal samples of mercury cadmium telluride were annealed at temperatures varying from 450 C to 600 C in Hg vapor and quenched to room temperature. Hall effect measurements at 77 K on the crystals cooled to room temperature indicate the samples to be n-type after anneals at high Hg pressures whereas they turn p-type after anneals at low Hg pressures; the electron concentration increases with increase in Hg pressure. The results are explained on the basis that the crystals are saturated with (Hg,Cd)I2, with a fraction of the iodine being present as donor occupying tellurium lattice sites and a fraction being present as acceptors resulting from the iodine on tellurium lattice sites pairing with the doubly ionized native acceptor defects. The solubility of the donor species increases with increase in Hg pressure, whereas that of the acceptor species increases with decrease in Hg pressure. Equilibrium constants for the incorporation of the iodine species as well as the pairing reaction were established.

Vydyanath, H. R.↗
NASA NTRS1981

The Limb Infrared Monitor of the Stratosphere /LIMS/ experiment - Temperature and nitrogen dioxide results

The Limb Infrared Monitor of the Stratosphere (LIMS) is a satellite-borne radiometer which scans across the earth's limb, measuring infrared radiation emitted by specific atmospheric gases in a number of broad channels. Instrumentation includes a folded telescope, which focuses the radiation from the limb onto an array of six mercury-cadmium-telluride detectors. A scan mirror within the telescope sweeps the fields of view across the horizon, with each up or down scan lasting 12 seconds. The measurements are inverted to yield distributions of temperature and nitrogen dioxide. The temperature is determined from two channels covering the intervals 595-739 per cm and 645-673 per cm of the 15 micron bands of CO2, with maximum signal to noise ratio of 500-1000. Nitrogen dioxide is determined from measurements in a channel from 1580-1613 per cm, with an S/N of approximately 100. Results show that the LIMS temperature and nitrogen dioxide data are characterized by high precision.

Gille, J. C.↗
NASA NTRS1981

Advanced methods for preparation and characterization of infrared detector materials

Differential thermal analysis data were obtained on mercury cadmium telluride alloys in order to establish the liquidus temperatures for the various alloy compositions. Preliminary theoretical analyses was performed to establish the ternary phase equilibrium parameters for the metal rich region of the phase diagram. Liquid-solid equilibrium parameters were determined for the pseudobinary alloy system. Phase equilibrium was calculated and Hg(l-x) Cd(x) Te alloys were directionally solidified from pseudobinary melts. Electrical resistivity and Hall coefficient measurements were obtained.

Lehoczky, S. L.↗
NASA NTRS1981

Moderate temperature detector development

P-side backside reflecting constant, photodiode characterization, and photodiode diffusion and G-R currents were investigated in an effort to develop an 8 m to 12 m infrared quantum detector using mercury cadmium telluride. Anodization, phosphorus implantation, and the graded band gap concept were approaches considered for backside formation. Variable thickness diodes were fabricated with a back surface anodic oxide to investigate the effect of this surface preparation on the diffusion limited zero bias impedance. A modeling technique was refined to thoroughly model diode characteristics. Values for the surface recombination velocity in the depletion region were obtained. These values were improved by implementing better surface damage removal techniques.

Marciniec, J. W.↗
NASA NTRS1981

Electric power needs in space

The power requirements for specific float zone experiments in space are presented. Power figures for the Space Shuttle and projected available power for advanced vehicles are given. The following power related trends are derived: (1) float zone processing of up to 5 cm diameter silicon and 16.0 cm diameter cadmium telluride can be conducted on a Shuttle pallet mission; (2) float zone processing of up to 8.5 cm diameter silicon for 70% total heating efficiency can be conducted on the initial MEC/space platform; (3) projected available host vehicle power for float zone sample heating; (4) induction heating is found to be the most promising heating method; (5) process control and ease of equipment integration into the host vehicle influence heating method selection.

Waltz, D. M.↗
NASA NTRS1981

1.0 to 2.5 micrometer short wavelength infrared /SWIR/ linear array technology for low background applications

A design concept is presented for a hybrid linear focal plane array operating in the 1.0 to 2.5 micron band under low background conditions such as encountered in spaceborne missions. The concept is based on direct gate coupling of the input from a photovoltaic mercury-cadmium telluride detector into a CCD multiplexer. Theoretical analysis indicates a specific detectivity at peak wavelength on the order of 10 to the 12th cm sq rt Hz/W when the system is operating at 200 K. Values of the voltage responsivity, specific detectivity and the relative voltage noise levels of the coupled system obtained in experimental studies with direct-gate-coupled 4.0-micron detectors support the theoretical analysis performed for the case of system detectivity limited by the CCD 1/f noise.

Stobie, J.↗
NASA NTRS1986

Measuring Thermal Diffusivity of Molten Semiconductors

Thermal diffusivity of molten and solid mercury cadmium telluride measured with aid of new apparatus. Knowledge gained from such measurements help efforts to grow high-quality single crystals of this semiconductor for use in infrared detectors: Without knowledge of thermal diffusivity, difficult to control growth rate of solid from molten material.

Crouch, R.↗
NASA NTRS1986

Determining the Temperature Profile in a Cylindrical Sample

Power-series solution extrapolates from axial temperature profile. Thermal profile in homogeneous axisymmetric body determined throughout body if axial temperature profile known at any radius. New theory developed as aid in research on growth of mercury cadmium telluride for infrared detectors. In particular, applicable to Bridgman-Stockbarger growth, in which round cylindrical ampoule of molten ternary semiconductor is solidified directionally, from one end to other.

Clayton, J. C.↗
NASA NTRS1984

Solidification and crystal growth of solid solution semiconducting alloys

Problems associated with the solidification and crytal growth of solid-solution semiconducting alloy crystals in a terrestrial environment are described. A detailed description is given of the results for the growth of mercury cadmium telluride (HgCdTe) alloy crystals by directional solidification, because of their considerable technological importance. A series of HgCdTe alloy crystals are grown from pseudobinary melts by a vertical Bridgman method using a wide range of growth rates and thermal conditions. Precision measurements are performed to establish compositional profiles for the crystals. The compositional variations are related to compositional variations in the melts that can result from two-dimensional diffusion or density gradient driven flow effects ahead of the growth interface. These effects are discussed in terms of the alloy phase equilibrium properties, the recent high temperature thermophysical data for the alloys and the highly unusual heat transfer characteristics of the alloy/ampule/furnace system that may readily lead to double diffusive convective flows in a gravitational environment.

Lehoczky, S. L.↗
NASA NTRS1983

An imaging spectrometer experiment for the Shuttle

An imaging spectrometer experiment concept for earth remote sensing, developed as part of NASA's Multispectral Linear Array program, will map a series of test sites at high spatial and spectral resolution from the vantage point of the Shuttle payload bay. The instrument covers the spectral range from 0.4 to 2.5 micrometers with a sampling interval of 10 nanometers in the visible and near infrared (to 1.0 micrometer) and 20 nanometers in the short wavelength infrared (1.0 to 2.5 micrometers). Resolution corresponding to a ground instantaneous field of view (pixel size) of 30 meters is provided over a swath width of 12 kilometers. On-board data editing is utilized to select a subset of the data stream for transmission to the ground. The instrument utilizes silicon and mercury cadmium telluride area array detectors. Pointing mirrors are included to permit specific test sites to be imaged from the Shuttle orbit.

Wellman, J. B.↗
NASA NTRS1984

Sealed silica pressure ampoules for crystal growth

The properties of vitreous silica and the mechanics of thick walled pressure vessels are reviewed with regard to the construction of sealed silica crucibles such as are used in the growth of mercury-cadmium telluride crystals. Data from destructive rupture tests are reported, failure modes discussed, and recommendations for design given. Ordinary commercial clear vitreous silica from flame fused quartz can withstand a surface stress of 20 MPa or more in this application.

Holland, L. R.↗
NASA NTRS1983

Airborne Imaging Spectrometer - An advanced concept instrument

The Airborne Imaging Spectrometer (AIS) is a multispectral infrared imaging instrument utilizing a 32- x 32-element mercury-cadmium-telluride detector array to achieve high spatial resolution. A novel optical design provides high spectral resolution, and, in conjunction with the 32-element spatial resolution, makes optimal use of the capabilities of the area array. The experiment requirements and the details of instrument design, implementation, and calibration are presented. The superior resolution, accuracy, and data acquisition rate of this sensor/instrument concept for reconnaissance and geophysical survey is detailed and plans for upgrading/improving the instrument and future applications of this design concept are discussed.

Labaw, C.↗
NASA NTRS1986

Hyperspectral Infrared Images of Terrain

Images at 128 wavelengths allow direct identification of many earth surface materials. Two reports describe advanced airborne spectrometer that creates images of terrain at many wavelengths. Airborne imaging spectrometer (AIS) produces two-dimensional images in 128 spectral bands in 1.2-to-2.4-micrometer wavelength region. Images created by 32-by-32 array of mercury cadmium telluride detector elements. Array views swath of Earth below moving aircraft. Used for agricultural, geological, and other surveys.

Vane, G.↗
NASA NTRS1986

Correcting for Nonlinearity in a Photodetector

Simple positive-feedback circuit varies bias voltage as necessary. Ideal detector biased with constant voltage, detector current proportional to photon flux plus constant offset. Detector connected between inverting input and ground, and feedback from operational amplifier through feedback resistor Rf make voltage at inverting input equal to noninverting input. Bias voltage held constant. Principle applied to linearizing mercury cadmium telluride infrared detectors in Fourier-transform spectrometers and other spectral and imaging instruments.

Schindler, R. A.↗
NASA NTRS1986

Low-Resistivity Zinc Selenide for Heterojunctions

Magnetron reactive sputtering enables doping of this semiconductor. Proposed method of reactive sputtering combined with doping shows potential for yielding low-resistivity zinc selenide films. Zinc selenide attractive material for forming heterojunctions with other semiconductor compounds as zinc phosphide, cadmium telluride, and gallium arsenide. Semiconductor junctions promising for future optoelectronic devices, including solar cells and electroluminescent displays. Resistivities of zinc selenide layers deposited by evaporation or chemical vapor deposition too high to form practical heterojunctions.

Stirn, R. J.↗
NASA NTRS1984

Results of testing short wavelength HgCdTe hybrid focal plane arrays for earth remote sensing applications

The NASA Imaging Spectrometer program has the objective to develop the next generation of earth remote sensing systems. One part of the program is concerned with the production of advanced short-wavelength mercury cadmium telluride (HgCdTe) hybrid focal plane arrays (FPAs). These arrays are needed for several instruments, including the Shuttle Imaging Spectrometer (SIS), which requires a mosaic of six 64 x 64-element arrays with a cutoff wavelength of 2.5 microns. A device description is provided and the test results are considered. The Airborne Imaging Spectrometer (AIS) is discussed, taking into account an instrument description, focal plane requirements, and AIS results.

Blessinger, M. A.↗
NASA NTRS1984

MLA instruments and SWIR focal-plane technology

It is pointed out that next-generation sensors for earth observation will utilize Multispectral Linear Array (MLA) technology wherein linear detector arrays will scan the earth in pushbroom fashion. MLA instruments will permit a dramatic increase in detector dwell time, which can be utilized to improve spatial, spectral, and radiometric resolution. In connection with the considered applications for MLA sensors, the employed detector arrays should cover the visible, near-infrared, and shortwave infrared (SWIR) spectral bands. The present paper is mainly concerned with the development of mercury-cadmium-telluride focal-plane arrays for the SWIR spectral regime (1-2.5 microns). Attention is given to the requirements, design details regarding the detector array, the employed multiplexer technique, the hybrid concept, packaging, and the program status.

Brown, F. G.↗
NASA NTRS1987

Growing Single Crystals of Compound Semiconductors

Defect reduced by preventing melt/furnace contact and suppressing convention. Large crystals of compound semiconductors with few defects grown by proposed new method. Such materials as gallium arsenide and cadmium telluride produced, with quality suitable for very-large-scale integrated circuits or for large focal-plane arrays of photodetectors. Method used on small scale in Earth gravity, but needs microgravity to provide crystals large enough for industrial use.

Naumann, Robert J.↗