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Constraints on the Organic Composition of Meteoroids

One of the major results obtained from the spacecraft experiments at Comet Halley, and subsequent telescopic observations of comets, is the identification of a substantial organic fraction of cometary dust. There are also various meteor observations which indicate that there may also be a significant heavy organic component of small (mm-cm) meteoroids entering the terrestrial atmosphere. Here we describe the results of thermodynamic modelling of idealized meteoroids which was directed towards discovering which volatile species could survive for the (typically) millennia between release from a comet and entry into the atmosphere. We find that the most likely species to survive from plausible volatile constituents axe organic species with carbon numbers greater than -20 (i.e., tarry or kerogen-type chemicals). This result is in accord with recent observations of the heights of ablation of meteors observed using radar techniques, and provides supportive evidence for the idea that organic molecules are continually raining down upon our planet.

McKay, Chris P.↗

Solar System Observing with the Space Infrared Telescope Facility (SIRTF)

SIRTF is NASA's Space Infrared Telescope Facility. Currently planned for launch on 15 Apr 2003, it is the final element in NASA's Great Observatories Program. SIRTF has an 85 cm diameter f/12 lightweight beryllium telescope, cooled to lekss than 5.5K. It is diffraction-limited at 6.5 microns, and has wavelengthcoverage from 3-180 microns. Its estimated lifetime (limited by cryogen) is 2.5 years at minimum, with a goal of 5+ years. SIRTF has three instruments, IRAC, IRS, and MIPS. IRAC (InfraRed Array Camera) provides simultaneous images at wavelengths of 3.6, 4.5, 5.8, and 8.0 microns. IRS (InfraRed Spectrograph) has 4 modules providing low-resolution (R=60-120) spectra from 5.3 to 40 microns, high-resolution (R=600) spectra from 10 to 37 microns, and an autonomous target acquisition system (PeakUp) which includes small-field imaging at 15 microns. MIPS (Multiband Imaging Photometer for SIRTF)} does imaging photometry at 24, 70, and 160 m and low-resolution (R=15-25) spectroscopy (SED) between 55 and 96 microns. The SIRTF Guaranteed Time Observers (GTOs) are planning to observe Outer Solar System satellites and planets, extinct comets and low-albedo asteroids, Centaurs and Kuiper Belt Objects, cometary dust trails, and a few active short-period comets. The GTO programs are listed in detail in the SIRTF Reserved Observations Catalog (ROC). We would like to emphasize that there remain many interesting subjects for the General Observers (GO). Proposal success for the planetary observer community in the first SIRTF GO proposal cycle (GO-1) determines expectations for future GO calls and Solar System use of SIRTF, so we would like promote a strong set of planetary GO-1 proposals. Towards that end, we present this poster, and we will convene a Solar System GO workshop 3.5 months after launch.

Cleve, J. Van↗

Stardust Imaging of Comet Wild 2: First Look

On 2 January 2004 during its historic flight to return cometary dust samples to earth, the STARDUST spacecraft flew within the coma of comet Wild 2 and also took 72 images where the surface was resolved during the flyby. A combination of long and short exposures was used to observe the jets and the surface. Comet Surface: The images revealed a planetary body, one not having a significant atmosphere, quite different from any other such body seen from other spacecraft. Surface depressions, potentially a combination of craters and vents, were not bowl-shaped but typically had steep walls and flattened floors. One depression considered to be a vent, the source of a jet, had a depth to diameter ratio of approx.0.4, with near vertical walls. Jets: At least 10 to possibly 20 jets were active during the flyby. Some were traced back to the surface where they seem to originate from the near vertical walls of depressions (vents) that were facing the sun, having the highest solar insolation.

Newburn, R.↗

Scattering Properties of Aggregate Particles

We are engaged in modeling the scattering and emitting properties of irregular particles with the goal of understanding the composition and structure of cometary dust particles.

discrete dipole approximation non-spherical monome↗

Irradiation Effects in Fosterrite and the Nature of Interstellar Grains: A Coordinated Spectroscopy and Electron Microscopy Study

Crystalline and amorphous silicates condense in the outflows of low mass evolved stars and massive red supergiant stars and are injected into the interstellar medium (ISM) where they are rendered almost completely amorphous by a multitude of destructive processes (e.g. shock, grain-grain collisions, and irradiation). Irradiation effects in particular may have played an important role in the genesis and modification of primitive grains in cometary dust, but unraveling those effects requires controlled experiments under appropriate conditions and with an emphasis on materials relevant to the ISM. Here we report our infrared (IR) microspectroscopy and trans-mission electron microscope (TEM) measurements on forsterite that was amorphized through irradiation by high energy heavy ions.

Keller, Lindsay P.↗

Aerogel Track Morphology: Measurement, Three Dimensional Reconstruction and Particle Location using Confocal Laser Scanning Microscopy

The Stardust spacecraft returned the first undoubted samples of cometary dust, with many grains embedded in the silica aerogel collector . Although many tracks contain one or more large terminal particles of a wide range of mineral compositions , there is also abundant material along the track walls. To help interpret the full particle size, structure and mass, both experimental simulation of impact by shots and numerical modeling of the impact process have been attempted. However, all approaches require accurate and precise measurement of impact track size parameters such as length, width and volume of specific portions. To make such measurements is not easy, especially if extensive aerogel fracturing and discoloration has occurred. In this paper we describe the application and limitations of laser confocal imagery for determination of aerogel track parameters, and for the location of particle remains.

Kearsley, A. T.↗

Comets as Parent Bodies of CI1 Carbonaceous Meteorites and Possible Habitats of Ice-Microbiota

Recent studies of comets and cometary dust have confirmed the presence of biologically relevant organic molecules along with clay minerals and water ice. It is also now well established by deuterium/hydrogen ratios that the CI1 carbonaceous meteorites contain indigenous extraterrestrial water. The evidence of extensive aqueous alteration of the minerals in these meteorites led to the hypothesis that water-bearing asteroids or comets represent the parent bodies of the CI1 (and perhaps CM2) carbonaceous meteorites. These meteorites have also been shown to possess a diverse array of complex organics and chiral and morphological biomarkers. Stable isotope studies by numerous independent investigators have conclusively established that the complex organics found in these meteorites are both indigenous and extraterrestrial in nature. Although the origin of these organics is still unknown, some researchers have suggested that they originated by unknown abiotic mechanisms and may have played a role in the delivery of chiral biomolecules and the origin of life on Early Earth. In this paper we review these results and investigate the thermal history of comets. We show that permanent as well as transient domains of liquid water can be maintained on a comet under a plausible set of assumptions. With each perihelion passage of a comet volatiles are preferentially released, and during millions of such passages the comet could shed crustal debris that may survive transit through the Earth s atmosphere as a carbonaceous meteorite. We review the current state of knowledge of comets and carbonaceous meteorites. We also present the results of recent studies on the long-term viability of terrestrial ice-microbiota encased in ancient glacial ice and permafrost. We suggest that the conditions which have been observed to prevail on many comets do not preclude either survivability (or even the active metabolism and growth) of many types of eukaryotic and prokaryotic microbial extremophiles-including algae, cyanobacteria, bacteria and archaea. It is argued that the chemical and morphological biomarkers detected on comets and carbonaceous meteorites can be explained by ancient microbial activity without the need to invoke unknown abiotic production mechanisms.

Wickramasinghe, N. Chandra↗

Radiolysis of Amino Acids in Outer Solar-System Ice Analogs

Amino acids have been found in cometary dust particles and in the organic component of meteorites. These molecules, important for pre-biotic chemistry and for active biological systems, might be formed in cold planetary or interstellar environments and then delivered to H20-rich surfaces in the outer solar system. Many models for the availability of organic species on Earth and elsewhere depend on the ability of these molecules to survive in radiation-rich space environments. This poster presents results of O.8-MeV proton radiolysis of ice films at lS-140K. using infrared spectroscopy, the destruction rates of glycine, alanine, and phenylalanine have been determined for both pure films and those containing amino acids diluted in H2o. our results are discussed in terms of the survivability of these molecules in the icy surfaces present in the outer solar system and the possibility of their detection by instruments on board the New Horizons spacecraft

Gerakines, Perry A.↗

Organic Analysis in the Miller Range 090657 CR2 Chondrite: Part 3 C and N Isotopic Imaging

Primitive carbonaceous chondrites contain a wide variety of organic material, ranging from soluble discrete molecules to insoluble nanoglobules of macro-molecular carbon. The relationship between the soluble organic molecules, macromolecular organic material, and host minerals are poorly understood. Large H, C and N isotopic anomalies suggest some organic components formed in low-T interstellar or outer Solar System environments. The highest isotope anomalies occur in m-scale inclusions in the most primitive materials, such as cometary dust and the least altered carbonaceous chondrites. Often, the hosts of these isotopically anomalous 'hotspots' are discrete organic nanoglobules that probably formed in the outermost reaches of the protosolar disk or cold molecular cloud. Molecular and isotopic studies of meteoritic organic matter are aimed at identifying the chemical properties and formation processes of interstellar organic materials and the subsequent chemical evolutionary pathways in various Solar System environments. The combination of soluble and insoluble analyses with in situ and bulk studies provides powerful constraints on the origin and evolution of organic matter in the Solar System. Using macroscale extraction and analysis techniques as well as microscale in situ observations we have been studying both insoluble and soluble organic material in primitive astromaterial samples. Here, we present results of bulk C and N isotopic measurements and coordinated in situ C and N isotopic imaging and mineralogical and textural studies of carbonaceous materials in a Cr2 carbonaceous chondrite. In accompanying abstracts we discuss the morphology and distribution of carbonaceous components and soluble organic species of this meteorite.

Messenger, S.↗

3-D-Observation of Matrix of MIL 090657 Meteorite by Absorption-Phase Tomography

MIL 090657 meteorite (CR2.7) is one of the least altered primitive carbonaceous c hondrites [1]. This meteorite has amorphous silicates like GEMS (glass with embedded metal and sulfide), which are characteristically contained in cometary dust, in matrix [2,3] as with the Paris meteorite [4]. Three lithologies have been recognized; lithology-1 (L 1) dominated by submicron anhydrous silicates, lithology-2 (L2) by GEMS-like amorphous silicates and lithology-3 (L3) by phyllosilicates [2]. Organic materials are abundant in L 1 and L2 [2,3]. L 1 and L2 were further divided into sub-lithology respectively based on their textures and compositions [5]. These studies were performed by 2D SEM and TEM observations of sample surfaces and thin sections that are unable to reveal what constitute each lithology and how these lithologies are distributed and related to each other. This information will provide important insights into alteration and aggregation processes on asteroids and in the early solar nebula. In this study, MIL 090657 matrix was examined in 3D using two types of X-ray tomography; DET (dual-energy tomography) [6] and SIXM (scanning-imaging X-ray microscopy) [7]. Mineral phases can be discriminated based on absorption contrasts at two different X-ray energies in DET. In SIXM, materials composed of light elements such as water or organic materials can be identified based on phase and absorption contrasts. By combining these methods, we can discriminate not only organic materials from voids but also hydrous alteration products, such as hydrated silicates and carbonates, from anhydrous minerals [8]. In this study, we first observed cross sections of MIL 090657 matrix fragments C1 00 mm) in detail using FE-SEM/ EDS. Based on the results, three house-shaped samples (3 0 -50 mm) were extracted from L 1, L2 and their boundary (H1, H3 and H5, respectively) using FIB. 3D imaging of these samples were conducted at BL47XU of SPring-8, a synchrotron radiation facility, with -30-40 nm/ voxel and - 70-80 nm/ voxel at 7keV and 8keV in DET and -100 nm/ voxel at 8keV in SIXM. We found new lithologies that we named L4, L5 and L6 in H1 and H3 in addition to L 1 and L2. L4. L5 and L6 are mainly composed of probably phyllosilicates with different Fe contents. Sulfide and framboidal magnetite were recognized in L4. L5 includes magnetite and carbonate and L6 includes anhydrous silicates having cracks inside. L 1, L2, L4 and L5 are porous while few voids were observed in L6. L4 adjoins to L 1 with boundary, which is not very distinct. L2, L5 and L6 adjoin to each other, and the boundaries of L6 with L2 and L5 are clear. In H5, coarse mineral grains C5-1 0 mm) such as Fe-metal and enstatite are present in L 1 and L2. L 1-L2 boundary is not sharp in 3 D. In conclusion, we found a variety of lithologies by 3D observation for the first time, suggesting that t he MIL 0 90657 meteorite experienced complex alteration and aggregation histories. As L2 is dominated by amorphous silicates, which are extremely susceptible to aqueous alteration, t his is p resumed to be t he most primitive lithology. The contact between L2 and phyllosilicate-bearing lithologies (L5 and L6) with clear boundaries indicates that they were aggregated after aqueous alteration of L5 and L6. The indistinct boundary between L 1 and L2 is suggesting that these two lithologies might originally be the same aggregate composed of amorphous silicates and coarse mineral grains. L 1 might have experienced weak aqueous alteration followed by mild thermal alteration [2], while L2 did not undergo aqueous alteration.

Miyama, Sugimoto↗

Evidence of Collisional Histories of Asteroids, Comets and Meteorites: Comparisons with Shocked Minerals

Evidence of the collisional history of comets and asteroids has been emerging from analyses of cometary forsterite and enstatite returned from Comet Wild 2 by the Stardust mission (Keller et al.Geochim. Cosmochim. Acta 72, 2008; Tomeoka et al. MAPS 43, 2008; Jacobs et al. MAPS 44, 2009). Likewise, shock metamorphism is observed in many meteoritic forsterites and enstatites (McCausland et al. AGU, 2010), suggesting similar collisional histories for asteroids. Further exploration of the effects of collisions is slated for the upcoming Asteroid Impact Mission/Double Asteroid Redirection Test (AIM/DART) mission, expected for launch in 2020. DART will impact Didymoon, the companion of the larger 65803 Didymos (1996 G2) asteroid, and AIM will use its instrumentation to characterize the impact. A suite of relevant impact experiments have been carried out in the Experimental Impact Laboratory at the NASA Johnson Space Center at velocities ranging from approx. 2.0 - 2.8 km/s and temperatures from 25 C to -100 C. Targets include a suite of minerals typically found in cometary dust and in asteroids and meteorites: Mg-rich forsterite (olivine), enstatite (orthopyroxene), diopside (clinopyroxene), magnesite (Mg-rich carbonate), and serpentine (phyllosilicate). Transmission Electron Microscope (TEM) imaging indicates evidence of shock similar to that seen in forsterite and enstatite from Comet Wild 2. Fourier Transform Infrared (FTIR) Spectroscopy will also be used for comparisons with meteorite spectra. A quantitative analysis of the shock pressures required to induce planar dislocations and spectral effects with respect to wavelength will also be presented.

Lederer, Susan M.↗

Retrieval of Microphysical Characteristics of Particles in Atmospheres of Distant Comets from Ground-Based Polarimetry

We summarize unique aperture data on the degree of linear polarization observed for distant comets C/2010 S1, C/2010 R1, C/2011 KP36, C/2012 J1, C/2013 V4, and C/2014 A4 with heliocentric distances exceeding 3 AU. Observations have been carried out at the 6-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences (Nizhnij Arkhyz, Russia) during the period from 2011 to 2016. The measured negative polarization proves to be significantly larger in absolute value than what is typically observed for comets close to the Sun. We compare the new observational data with the results of numerical modeling performed with the T-matrix and superposition T-matrix methods. In our computer simulations, we assume the cometary coma to be an optically thin cloud containing particles in the form of spheroids, fractal aggregates composed of spherical monomers, and mixtures of spheroids and aggregate particles. We obtain a good semi-quantitative agreement between all polarimetric data for the observed distant comets and the results of numerical modeling for the following models of the cometary dust: (i) a mixture of submicrometer water-ice oblate spheroids with aggregates composed of submicrometer silicate monomers; and (ii) a mixture of submicrometer water-ice oblate spheroids and aggregates consisting of both silicate and organic monomers. The microphysical parameters of these models are presented and discussed.

Numerical modeling↗

SKYSURF: Constraints on Zodiacal Light and Extragalactic Background Light through Panchromatic HST All-sky Surface-brightness Measurements: II. First Limits on Diffuse Light at 1.25, 1.4, and 1.6 μm

We present the first results from the HST Archival Legacy project "SKYSURF." As described in Windhorst et al., SKYSURF utilizes the large HST archive to study the diffuse UV, optical, and near-IR backgrounds and foregrounds in detail. Here, we utilize SKYSURF's first sky-surface-brightness measurements to constrain the level of near-IR diffuse Extragalactic Background Light (EBL) in three near-IR filters (F125W, F140W, and F160W). This is done by comparing our preliminary sky measurements of >30,000 images to zodiacal light models, carefully selecting the darkest images to avoid contamination from stray light. Our sky-surface-brightness measurements have been verified to an accuracy of better than 1%, which when combined with systematic errors associated with HST, results in sky-brightness uncertainties of ∼ 2%–4% ≃ 0.005 MJy sr−1 in each image. When compared to the Kelsall et al. zodiacal model, an isotropic diffuse background of ∼30 nW m−2 sr−1 remains, whereas using the Wright zodiacal model results in no discernible diffuse background. Based primarily on uncertainties in the foreground model subtraction, we present limits on the amount of diffuse EBL of 29, 40, and 29 nW m−2 sr−1, for F125W, F140W, and F160W, respectively. While this light is generally isotropic, our modeling at this point does not distinguish between a cosmological origin or a solar system origin (such as a dim, diffuse, spherical cloud of cometary dust).

Timothy Carleton↗

Solar flare track densities in interplanetary dust particles The determination of an asteroidal versus cometary source of the zodiacal dust cloud

The possibility is explored whether an IDP (interplanetary dust particle) is cometary or asteroidal from measurements of the solar flare track density within its constituent mineral grains. Dust particles that are larger than 1 micron, when injected into the Solar System from comets and asteroids, will spiral into the sun due to the Poynting-Robertson effect. During the process of spiraling in, such dust particles accumulate solar flare tracks. The accumulated track density for a given dust grain is a function of the duration of its space exposure and its distance from the sun. Using a computer model, it was determined that the expected track density distributions from grains produced by comets are very different from those produced by asteroids. Individual asteroids produce populations of particles that arrive at 1 AU with scaled track density distributions containing 'spikes,' while comets supply particles with a flatter and wider distribution of track densities.

Sandford, Scott A.↗

Anticipated results from dust experiments on cometary missions

The major scientific objectives of a mission are: to determine the chemical nature and physical structure of comet nuclei, and to characterize the changes that occur as a function of time orbital position; to characterize the chemical and physical nature of the atmospheres and ionospheres of comets as well as the processes that occur in them, and to characterize the development of the atmospheres and ionospheres as functions of time and orbital position; and to determine the nature of comet tails and processes by which they are formed, and to characterize the interaction of comets with the solar wind. Since dust is a major constituent of a comet, the achievement of these goals requires the intensive study of the paticulate emission from a comet.

Kissel, J.↗

Stardust: The Adventure has Begun

The NASA Discovery STARDUST Mission was launched in February, 1999 to fly through the coma of P/Wild 2 in January, 2004 and return captured cometary and interplanetary dust particles to earth in January, 2006 for detailed analyses by the international science community. The STARDUST spacecraft is carrying a dust collector employing JPL Aerogel for collecting interstellar dust during interplanetary cruise and cometary dust during Wild 2 flyby. Additional instrumentation include the MPI fur Extraterrestrische Physik Cometary and Interplanetary Dust Analyzer, the University of Chicago Dust Flux Monitor and the JPL Imaging Camera. Doppler tracking of the spacecraft and high rate attitude orientation and body-fixed rate data from engineering subsystems will also provide science information. The presentation will describe the mission, scientific objectives and current state of the spacecraft in detail.

Duxbury, Thomas C.↗

Influence of the interplanetary magnetic field on cometary and primordial dust orbits - Applications of Lorentz Scattering

The equations describing the change in orbital elements of interplanetary dust due to Lorentz-force accelerations are presented in a simplified form. Such accelerations depend on the charge state of the dust; results of theoretical calculations for five possible dust materials are presented. Under present-day conditions, it is possible that semiconducting material such as graphite might carry a net voltage near zero, compared with a roughly 10-V charge expected for other grains. The scattering of dust by a randomly changing magnetic field can be viewed analogously to the dust diffusing in space; the equations presented thus can be used to interpret observations of the present distribution of dust in terms of its possible sources and sinks. The stronger magnetic fields of the early solar system would have led to more vigorous scattering of the dust; particles as large as 1 mm could have been significantly transported by Lorentz scattering during this time.

Consolmagno, G. J.↗