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NASA NTRS2001

Spectral Measurements of Meteorite Powders: Implications for 433 Eros

One of the goals of the NEAR-Shoemaker mission to 433 Eros was to determine if it has a meteoritic analog. The primary means of making such a link are the X-ray/gamma-ray spectrometers, which measure elemental compositions of the surface, and the multi-spectral imager (MSI) and near-infrared spectrometer (NIS), which measure spectral reflectance. For determining meteoritic analogs using the X-ray/gamma-ray spectrometer data, the primary data used for comparison is the set of bulk chemical analyses of meteorites done by Jarosewich. These bulk chemical analyses were done on samples now found in the Smithsonian's Analyzed Meteorite Powder collection (USNM 7073). For determining meteoritic analogs using MSI/NIS spectral data, the primary data used for comparison is the set of meteoritic spectra compiled by Gaffey. To expand the set of meteoritic spectra available to the scientific community, we have initiated a spectral study of over 70 samples (primarily ordinary chondrites) found in the Smithsonian's Analyzed Meteorite Powder collection and an electron microprobe study of their corresponding thin sections. This set of spectral and compositional data should allow for better constraints on the distribution of meteorites in plots of band area ratios versus Band I centers and the usefulness of equations for deriving mineralogic compositions from band parameters. These spectral data can also be combined with previous spectral studies of other meteorite types such as the primitive achondrites, eucrites, and angrites to determine how useful the derived band parameters are for differentiating between different meteorite classes. These spectral data can also be used for testing the Modified Gaussian Model (MGM) for determining modal abundances and mafic mineral chemistries from reflectance spectra.

Burbine, T. H.↗
NASA NTRS2013

MESSENGER at Mercury: Early Orbital Operations

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft, launched in August 2004 under NASA's Discovery Program, was inserted into orbit about the planet Mercury in March 2011. MESSENGER's three flybys of Mercury in 2008-2009 marked the first spacecraft visits to the innermost planet since the Mariner 10 flybys in 1974-1975. The unprecedented orbital operations are yielding new insights into the nature and evolution of Mercury. The scientific questions that frame the MESSENGER mission led to the mission measurement objectives to be achieved by the seven payload instruments and the radio science experiment. Interweaving the full set of required orbital observations in a manner that maximizes the opportunity to satisfy all mission objectives and yet meet stringent spacecraft pointing and thermal constraints was a complex optimization problem that was solved with a software tool that simulates science observations and tracks progress toward meeting each objective. The final orbital observation plan, the outcome of that optimization process, meets all mission objectives. MESSENGER's Mercury Dual Imaging System is acquiring a global monochromatic image mosaic at better than 90% coverage and at least 250 m average resolution, a global color image mosaic at better than 90% coverage and at least 1 km average resolution, and global stereo imaging at better than 80% coverage and at least 250 m average resolution. Higher-resolution images are also being acquired of targeted areas. The elemental remote sensing instruments, including the Gamma-Ray and Neutron Spectrometer and the X-Ray Spectrometer, are being operated nearly continuously and will establish the average surface abundances of most major elements. The Visible and Infrared Spectrograph channel of MESSENGER's Mercury Atmospheric and Surface Composition Spectrometer is acquiring a global map of spectral reflectance from 300 to 1450 nm wavelength at a range of incidence and emission angles. Targeted areas have been selected for spectral coverage into the ultraviolet with the Ultraviolet and Visible Spectrometer (UVVS). MESSENGER's Mercury Laser Altimeter is acquiring topographic profiles when the slant range to Mercury's surface is less than 1800 km, encompassing latitudes from 20 deg. S to the north pole. Topography over the remainder of the southern hemisphere will be derived from stereo imaging, radio occultations, and limb profiles. MESSENGER's radio science experiment is determining Mercury's gravity field from Doppler signals acquired during frequent downlinks. MESSENGER's Magnetometer is measuring the vector magnetic field both within Mercury's magnetosphere and in Mercury's solar wind environment at an instrument sampling rate of up to 20 samples/s. The UVVS is determining the three-dimensional, time-dependent distribution of Mercury's exospheric neutral and ionic species via their emission lines. During each spacecraft orbit, the Energetic Particle Spectrometer measures energetic electrons and ions, and the Fast Imaging Plasma Spectrometer measures the energies and mass per charge of thermal plasma components, both within Mercury's magnetosphere and in Mercury's solar-wind environment. The primary mission observation sequence will continue for one Earth year, until March 2012. An extended mission, currently under discussion with NASA, would add a second year of orbital observations targeting a set of focused follow-on questions that build on observations to date and take advantage of the more active Sun expected during 2012-2013. MESSENGER's total primary mission cost, projected at $446 M in real-year dollars, is comparable to that of Mariner 10 after adjustment for inflation.

mercury↗
NASA NTRS2012

MESSENGER at Mercury: Early Orbital Operations

The MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft, launched in August 2004 under NASA's Discovery Program, was inserted into orbit about the planet Mercury in March 2011. MESSENGER's three flybys of Mercury in 2008-2009 marked the first spacecraft visits to the innermost planet since the Mariner 10 flybys in 1974-1975. The unprecedented orbital operations are yielding new insights into the nature and evolution of Mercury. The scientific questions that frame the MESSENGER mission led to the mission measurement objectives to be achieved by the seven payload instruments and the radio science experiment. Interweaving the full set of required orbital observations in a manner that maximizes the opportunity to satisfy all mission objectives and yet meet stringent spacecraft pointing and thermal constraints was a complex optimization problem that was solved with a software tool that simulates science observations and tracks progress toward meeting each objective. The final orbital observation plan, the outcome of that optimization process, meets all mission objectives. MESSENGER's Mercury Dual Imaging System is acquiring a global monochromatic image mosaic at better than 90%coverage and at least 250 m average resolution, a global color image mosaic at better than 90%coverage and at least 1 km average resolution, and global stereo imaging at better than 80%coverage and at least 250 m average resolution. Higher-resolution images are also being acquired of targeted areas. The elemental remote sensing instruments, including the Gamma-Ray and Neutron Spectrometer and the X-Ray Spectrometer, are being operated nearly continuously and will establish the average surface abundances of most major elements. The Visible and Infrared Spectrograph channel of MESSENGER's Mercury Atmospheric and Surface Composition Spectrometer is acquiring a global map of spectral reflectance from 300 to 1450 nm wavelength at a range of incidence and emission angles. Targeted areas have been selected for spectral coverage into the ultraviolet with the Ultraviolet and Visible Spectrometer (UVVS). MESSENGER's Mercury Laser Altimeter is acquiring topographic profiles when the slant range to Mercury's surface is less than 1800 km, encompassing latitudes from 201S to the north pole. Topography over the remainder of the southern hemisphere will be derived from stereo imaging, radio occultations, and limb profiles. MESSENGER's radio science experiment is determining Mercury's gravity field from Doppler signals acquired during frequent downlinks. MESSENGER's Magnetometer is measuring the vector magnetic field both within Mercury's magnetosphere and in Mercury's solar wind environment at an instrument sampling rate of up to 20 samples/s. The UVVS is determining the three-dimensional, time-dependent distribution of Mercury's exospheric neutral and ionic species via their emission lines. During each spacecraft orbit, the Energetic Particle Spectrometer measures energetic electrons and ions, and the Fast Imaging Plasma Spectrometer measures the energies and mass per charge of thermal plasma components, both within Mercury's magnetosphere and in Mercury's solar-wind environment. The primary mission observation sequence will continue for one Earth year, until March 2012. An extended mission, currently under discussion with NASA, would add a second year of orbital observations targeting a set of focused follow-on questions that build on observations to date and take advantage of the more active Sun expected during 2012-2013. MESSENGER's total primary mission cost, projected at $446 M in real-year dollars, is comparable to that of Mariner 10 after adjustment for inflation.

Planetary Science↗
NASA NTRS2007

ACE-FTS Observation of a Young Biomass Burning Plume: First Reported Measurements of C2H4, C3H6O, H2CO and PAN by Infrared Occultation from Space

In the course of our study of the upper tropospheric composition with the infrared 35 Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE FTS), we 36 found an occultation sequence that on 8 October 2005, sampled a remarkable plume near the 37 east coast of Tanzania. Model simulations of the CO distribution in the Southern hemisphere 38 are performed for this period and they demonstrate that the emissions for this event originated 39 from a nearby forest fire, after which the plume was transported from the source region to the 40 upper troposphere. Taking advantage of the very high signal-to-noise ratio of the ACE FTS 41 spectra over a wide wavenumber range (750-4400 cm(exp -1), we present in-depth analyses of the 42 chemical composition of this plume in the middle and upper troposphere, focusing on the 43 measurements of weakly absorbing pollutants. For this specific biomass burning event, we 44 report simultaneous observations of an unprecedented number of organic species. 45 Measurements of C2H4 (ethene), C3H4 (propyne), H2CO (formaldehyde), C3H6O (acetone) 46 and CH3COO2NO2 (perxoxyacetylnitrate, abbreviated as PAN) are the first reported 47 detections using infrared occultation spectroscopy from satellites. Based on the lifetime of the 48 emitted species, we discuss the photochemical age of the plume and also report, whenever 49 possible, the enhancement ratios relative to CO.

Coheur, Pierre-Francois↗
NASA NTRS2008

Probing the Distribution of Ozone on Mars

We present the application of infrared heterodyne line shapes of ozone on Mars to those produced by radiative transfer modeling of ozone profiles predicted by photochemistry-coupled general circulation models (GCM), and to contemporaneous column abundances measured by Mars Express SPICAM. Ozone is an important tracer of photochemistry in Mars' atmosphere, serving as an observable with which to test predictions of photochemical models. Infrared heterodyne measurements of ozone absorption features on Mars have been obtained at various Martian seasons from 1988 until present at the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawai'i [I]. The NASAiGoddard Space Flight Center spectrometers used were the Infrared Heterodyne Spectrometer (IRHS) [2, 3] and, since 2003, the Heterodyne Instrument for Planetary Wind and Composition (HIPWAC) [4]. A description the infrared heterodyne technique applied to ground-base observations of Martian ozone can be found in [I]. The most recent measurements on February 21-24 2008 UT at Ls=35deg were made by HIPWAC on or near the Mars Express orbital path with the goal of acquiring spectra that can be directly compared to nadir observations by SPICAM.

Fast, K. E.↗
NASA NTRS1992

Lunar UV-visible-IR mapping interferometric spectrometer

Ultraviolet-visible-infrared mapping digital array scanned interferometers for lunar compositional surveys was developed. The research has defined a no-moving-parts, low-weight and low-power, high-throughput, and electronically adaptable digital array scanned interferometer that achieves measurement objectives encompassing and improving upon all the requirements defined by the LEXSWIG for lunar mineralogical investigation. In addition, LUMIS provides a new, important, ultraviolet spectral mapping, high-spatial-resolution line scan camera, and multispectral camera capabilities. An instrument configuration optimized for spectral mapping and imaging of the lunar surface and provide spectral results in support of the instrument design are described.

Smith, W. Hayden↗
NASA NTRS2021

The Science Case for Spacecraft Exploration of the Uranian Satellites: Candidate Ocean Worlds in an Ice Giant System

The 27 satellites of Uranus are enigmatic, with dark surfaces coated by material that could be rich in organics. Voyager 2 imaged the southern hemispheres of Uranus’s five largest “classical” moons—Miranda, Ariel, Umbriel, Titania, and Oberon, as well as the largest ring moon, Puck—but their northern hemispheres were largely unobservable at the time of the flyby and were not imaged. Additionally, no spatially resolved data sets exist for the other 21 known moons, and their surface properties are essentially unknown. Because Voyager 2 was not equipped with a near-infrared mapping spectrometer, our knowledge of the Uranian moons’ surface compositions, and the processes that modify them, is limited to disk-integrated data sets collected by ground- and space-based telescopes. Nevertheless, images collected by the Imaging Science System on Voyager 2 and reflectance spectra collected by telescope facilities indicate that the five classical moons are candidate ocean worlds that might currently have, or had, liquid subsurface layers beneath their icy surfaces. To determine whether these moons are ocean worlds, and to investigate Uranus’s ring moons and irregular satellites, close-up observations and measurements made by instruments on board a Uranus orbiter are needed.

Richard J. Cartwright↗
NASA NTRS2009

Development and Airborne Operation of a Compact Water Isotope Ratio Infrared Spectrometer

A sensitive laser spectrometer, named IRIS (water isotope ratio infrared spectrometer), was developed for the in situ detection of the isotopic composition of water vapour in the upper troposphere and the lower stratosphere. Isotope ratio measurements can be used to quantify troposphere stratosphere exchange, and to study the water chemistry in the stratosphere. IRIS is based on the technique of optical feedback cavity-enhanced absorption spectroscopy. It uses a room temperature near-infrared laser, and does not require cryogenic cooling of laser or detectors. The instrument weighs 51 kg including its support structure. Airborne operation was demonstrated during three flights aboard the European M55-Geophysica stratospheric research aircraft, as part of the AMMA/SCOUT-03 (African Monsoon Multidisciplinary Analysis/Stratospheric Climate links with emphasis on the Upper Troposphere and lower stratosphere) campaign in Burkina Faso in August 2006. The data are discussed with reference to a Rayleigh distillation model. As expected, there is no indication of non-mass-dependent fractionation (also known as mass-independent fractionation) in the troposphere. Furthermore, improvements to the thermal management system and a move to a (cryogen-free) longer-wavelength laser source are discussed, which together should result in approximately two orders of magnitude improvement of the sensitivity

Iannone, Rosario Q.↗
NASA NTRS1972

The composition of the Martian atmosphere - Minor constituents.

The Mariner 6 and 7 infrared spectrometers provided data which, in principle, determine upper limits on the possible atmospheric abundance of every gaseous substance that was undetected but which has recognized absorptions in the accessible spectral region, 1.9 to 14.4 microns. Through supporting laboratory determinations of curves of growth under pressure-broadening conditions appropriate to Mars, upper limits can be specified (expressed first in cm-atm, STP, for a vertical column and then in parts per million) for NO2, NH3, C3O2, SO2, OCS, NO, O3, CH4, N2O, HCL, HBr, and H2S. In addition, considerations of band contours, moments of inertia, and experimental absorption coefficients make it possible to place useful upper limits on 27 additional substances that were not detected and for which curves of growth have not been measured.

Horn, D.↗
NASA NTRS1993

Acousto-optic infrared spectral imager for Pluto fast flyby

Acousto-optic tunable filters (AOTF's) enable the design of compact, two-dimensional imaging spectrometers with high spectral and spatial resolution and with no moving parts. Tellurium dioxide AOTF's operate from about 400 nm to nearly 5 microns, and a single device will tune continuously over one octave by changing the RF acoustic frequency applied to the device. An infrared (1.2-2.5 micron) Acousto-Optic Imaging Spectrometer (AImS) was designed that closely conforms to the surface composition mapping objectives of the Pluto Fast Flyby. It features a 75-cm focal length telescope, infrared AOTF, and 256 x 256 NICMOS-3 focal plane array for acquiring narrowband images with a spectral resolving power (lambda/delta(lambda)) exceeding 250. We summarize the instrument design features and its expected performance at the Pluto-Charon encounter.

Glenar, D. A.↗
NASA NTRS2003

Spectral Properties of Hydrated Salts at Low Temperature: Implications for Europa Mission Spectrometer Design

Knowledge of the surface composition of Europa is critical for modeling of surface and interior processes and especially for evaluation of astrobiological potential. While much information has been derived from the Galileo Near-Infrared Mapping Spectrometer (NIMS) investigation, some breakthroughs have created more questions than answers. Any future Europa mission will attempt to capitalize on lessons learned from NIMS and try to answer these questions. At present, the surface composition appears to be a mixture of water ice, hydrated salts, sulfur compounds, radiolysis products (such as hydrogen peroxide and possibly simple organics like formaldehyde) and some as yet unidentified component. The small spatial scale of heterogeneity in Europa's surface geology poses additional challenges for orbiting spectrometers due to spectral mixing effects.

Dalton, J. Brad↗
NASA NTRS1975

Composition of the Martian dust as derived by infrared spectroscopy from Mariner 9

The Martian dust spectra obtained by the infrared interferometer spectrometer (Iris) experiment on Mariner 9 have been compared with modeling computations for various minerals and rocks. The model used was based upon a recently developed theory of absorption and scattering by particulate materials. The results indicate that the composition of Martian dust is biased toward silicate structures which involve a high degree of silicate oxygen sharing. A feldspar-rich dust of approximately 1-micron particle size appears to be the best candidate, although sheet-structure silicates cannot be ruled out.

Aronson, J. R.↗
NASA NTRS1995

NIMS Science Objectives and Observational Plans for Ganymede during the Galileo Tour

The Galileo spacecraft will use a Near Infrared Mapping Spectrometer (NIMS) to study Jupiter s moon, Ganymede. Although the main goal is to study the chemical components in the various surface compositional units, terrain types, craters, polar effects, hemisphere differences, and the atmosphere also will be examined.

components compositional units terrain types crate↗
NASA NTRS2020

Weak Spectral Features on (101995) Bennu from the OSIRIS-REx Visible and InfraRed Spectrometer

Context. The NASA Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission has obtained thousands of spectra of asteroid (101955) Bennu with the OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS). Aims. We present a spectral search for minor absorption bands and determine compositional variations on the surface of Bennu. Methods. Reflectance spectra with low and high spatial resolutions were analyzed for evidence of weak absorption bands. Spectra were also divided by a global average spectrum to isolate unique spectral features, and variations in the strongest band depths were mapped on a surface shape model. The global visible to near-IR spectrum of Bennu shows evidence of several weak absorption bands with depths of a few percent. Results. Several observed bands are consistent with phyllosilicates, and their distribution correlates with the stronger 2.74-μm hydration band. A 0.55-μm band is consistent with iron and is deepest in the spectrally reddest areas on Bennu. The presence of hydrated phyllosilicates and iron oxides indicates substantial aqueous alteration in Bennu’s past. Conclusions. Bennu’s spectra are not identical to a limited set of carbonaceous chondrite spectra, possibly due to compositional properties and spatial scale differences; however, returned samples should contain a mixture of common chondrite materials.

OSIRIS-REx↗
NASA NTRS1994

Spectral analysis of ALH 84001, a meteorite from Mars

ALH 84001 has recently been reclassified as a meteorite from Mars (SNC) and contains more than 90% orthopyroxene with minor chromite and accessory phases of augite, maskelynite, and carbonate. This meteorite represents a new class of igneous material from Mars. We have measured reflectance spectra of ALH 84001 as a chip as a powder, dry sieved to less than 125 microns to compare with previous spectral analyses of SNCs and remote observations of Mars. Spectra of the chip and powder in the visible-to-near-infrared region are shown. These spectra are composites of data measured with the RELAB bidirectional spectrometer from 0.3 to 2.55 microns and a Nicolet FTIR for longer wavelengths. As expected, the spectra of the chip have negative slopes and are significantly darker than the spectrum of the particulate sample, which has a positive slope. The strong absorptions near 1 micron and 2 microns are characteristic of low-Ca pyroxene and have band rninima of 0.925 microns and 1.930 microns. The strong absorption near 3 microns is characteristic of water. There is a distinct flattening in the spectrum between 1.0 and 1.5 microns indicating the presence of an additional absorption. This is interpreted to be the result of Fe(2+) in the M1 site of low-Ca pyroxene. Mid-infrared spectra showing the Christiansen feature and the reststrahlen bands are shown for spectra of the powder and of three different locations on the chip. These spectra exhibit several features in this range, some of which are associated with a specific region on the chip. Each of the spectra includes a doublet reststrahlen peak near 1100/cm, and peaks near 880 and 500/cm, which are typical for low-Ca pyroxenes. Weaker features at 940-1000/cm, 600-750/cm, and 530-560/cm are present in spectra from some locations on the chip, but not others, implying compositional and textural variation.

Bishop, J.↗
NASA NTRS2001

The Composition of 433 Eros: A Mineralogical-Chemical Synthesis

We report on an effort with the Near-Infrared Spectrometer/Multi-Spectral Imager (NIS/MSI) and X-ray/Gamma-ray Spectrometer (XGRS) teams to synthesize our data sets to constrain the relationship between Eros and meteorites; the mineralogy, abundances and compositions of Eros; and the processes that formed Eros. Additional information is contained in the original extended abstract.

McCoy, T. J.↗
NASA NTRS1992

First results from analysis of coordinated AVIRIS, TIMS, and ISM (French) data for the Ronda (Spain) and Beni Bousera (Morocco) peridotites

Ultramafic rocks are relatively rare at the Earth's surface but constitute the vast majority of the Earth by volume. Exposures of ultramafic bodies are therefore crucial for deducing many important processes that occur in the Earth's mantle. An important science question regarding the spatial distribution, abundance, and composition of mafic minerals in ultramafic bodies that can be examined with advanced sensor data is the melting process. When a lherzolite melts, clinopyroxene (cpx) melts first and therefore variations in the modal amount of cpx remaining in the mantle are a reflection of the amount of fractional melting that has occurred. Fe goes preferentially into the melt during melting but a 20 percent batch melting (i.e. closed system) acquires less Fe relative to 20 percent fractional melting (i.e. open system). Since the strength and wavelength of diagnostic absorptions is a strong function of Fe content, it is possible to make maps of the variation in Fe:Mg ratios which can be related to the general melting process. Accurate ground-truth information about local mineralogy provides internal calibration and consistency checks. Investigations using imaging spectrometer are very complementary to field studies because advanced sensor data can provide a synoptic view of modal mineralogy and chemical composition whereas field studies focus on detailed characterization of local areas. Two excellent exposures of ultramafic lithologies are being investigated with visible to mid-infrared imaging spectrometer data: the Ronda peridotite near Ronda, Spain and the Beni Bousera ophiolitic fragment in northern Morocco. Although separated by the Alboran Sea, these bodies are thought to be related and represent fertile sub-continental mantle. The Ronda peridotite is predominantly spinel lherzolite but grades into harzburgite and shows considerable variation in major and trace element compositions. Mafic layering and dykes (i.e. olivine gabbro) are also observed. This indicates some sections of the peridotite have experienced greater degrees of partial melting. The Beni Bousera peridotite also contains mafic layers and dykes and grades into harzburgite representing similar fundamental shifts in the bulk chemistry of this ultramafic body probably related to an episode of partial melting. The specific mode of emplacement of these bodies is controversial and important for understanding the tectonic evolution of this region. Our investigations are not necessarily designed to help resolve this controversy. Rather, these exposures provide excellent and unusual examples of fertile mantle which have undergone variable degrees of partial melting.

Mustard, J. F.↗