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At least 181 records · Page 10

Interfacial Inversion of Stealth Surfactants

Amphiphilic macromolecular surfactants segregate to liquid–liquid interfaces, thereby reducing the interfacial tension and free energy. Here, we investigated “stealth surfactants” in the form of core–shell bottlebrush polymers comprised of pH-responsive diblock copolymer side chains forming a hydrophilic core and a hydrophobic shell, enabling solubility in oil. At liquid–liquid interfaces, these polymers undergo a structural “inversion”, with hydrophilic blocks segregating into the aqueous phase and hydrophobic blocks residing in the oil phase. The reconfiguration kinetics and surfactant properties are influenced by multiple factors, including the molecular weights of the backbone and side chain components, the hydrophilic-to-hydrophobic balance of the side chains, and the pH of the aqueous phase. An observed nonmonotonic dependence of interfacial tension with time is attributed to a progressive structural inversion, where the projected area of the macromolecule onto the interface decreases. To validate this inversion hypothesis, interfacial properties were characterized by sum-frequency generation vibrational spectroscopy, which revealed configurational changes of the core–shell bottlebrush polymers at the fluid interface and revealed a pH-dependent interfacial coverage. Coarse-grained molecular dynamics simulations supported these experimental findings, showing that the pH-responsive core and hydrophobic shell assume a time-averaged configuration with orientations parallel and perpendicular to the plane of the interface, respectively. These findings open routes to design multistimuli-responsive polymeric surfactants and compatibilizers, expanding their potential applications in advanced interfacial systems.

Stealth surfactants↗

In situ X-ray diffraction of silicate liquids and glasses under dynamic and static compression to megabar pressures

Properties of liquid silicates under high-pressure and high-temperature conditions are critical for modeling the dynamics and solidification mechanisms of the magma ocean in the early Earth, as well as for constraining entrainment of melts in the mantle and in the present-day core–mantle boundary. In this paper, we present in situ structural measurements by X-ray diffraction of selected amorphous silicates compressed statically in diamond anvil cells (up to 157 GPa at room temperature) or dynamically by laser-generated shock compression (up to 130 GPa and 6,000 K along the MgSiO 3 glass Hugoniot). The X-ray diffraction patterns of silicate glasses and liquids reveal similar characteristics over a wide pressure and temperature range. Beyond the increase in Si coordination observed at 20 GPa, we find no evidence for major structural changes occurring in the silicate melts studied up to pressures and temperatures exceeding Earth’s core mantle boundary conditions. This result is supported by molecular dynamics calculations. Our findings reinforce the widely used assumption that the silicate glasses studies are appropriate structural analogs for understanding the atomic arrangement of silicate liquids at these high pressures.

58 GEOSCIENCES↗

Elongation Factor Tu Acts as a Chaperone to Activate an Antibacterial RNase Toxin

Many Gram-negative bacterial species use contact-dependent growth inhibition (CDI) systems to deliver toxic proteins into neighboring competitors. CDI + strains deploy CdiA effector proteins, which translocate their C-terminal toxin (CT) domains into target bacteria through a receptor-mediated delivery pathway. To protect against auto-intoxication, CDI + bacteria also produce CdiI immunity proteins that neutralize CT toxin activity. Here, we present the crystal structure of the CT·CdiI O32:H37 complex from Escherichia coli O32:H37. CT O32:H37 adopts the same fold as the tRNase domain of colicin D, and the nucleases share similar catalytic centers. However, unlike colicin D, which cleaves the anticodon loops of tRNA Arg isoacceptors, CT O32:H37 exhibits nonspecific RNase activity. Notably, we find that endogenous elongation factor Tu (EF-Tu) co-purifies with the over-produced CT·CdiI O32:H37 complex. Although EF-Tu does not bind stably to CT O32:H37 in the absence of CdiI O32:H37 , the translation factor is required for toxic RNase activity in vitro. AlphaFold 3 modeling and site-directed mutagenesis indicate that CT O32:H37 interacts with the N-terminal GTPase domain of EF-Tu. EF-Tu appears to stabilize residue Trp52 within the hydrophobic core of the toxin, which in turn supports the RNase active site through an unusual hydrogen-bonding interaction with the catalytic His67 residue. Furthermore, EF-Tu is hijacked as an essential co-factor to organize the toxin's catalytic center.

Nhan, Dinh Quan [University of California, Santa B↗

Designing and prototyping extensions to the Message Passing Interface in MPICH

As HPC system architectures and the applications running on them continue to evolve, the MPI standard itself must evolve. The trend in current and future HPC systems toward powerful nodes with multiple CPU cores and multiple GPU accelerators makes efficient support for hybrid programming critical for applications to achieve high performance. However, the support for hybrid programming in the MPI standard has not kept up with recent trends. The MPICH implementation of MPI provides a platform for implementing and experimenting with new proposals and extensions to fill this gap and to gain valuable experience and feedback before the MPI Forum can consider them for standardization. Here, in this work, we detail six extensions implemented in MPICH to increase MPI interoperability with other runtimes, with a specific focus on heterogeneous architectures. First, the extension to MPI generalized requests lets applications integrate asynchronous tasks into MPI’s progress engine. Second, the iovec extension to datatypes lets applications use MPI datatypes as a general-purpose data layout API beyond just MPI communications. Third, a new MPI object, MPIX_Stream, can be used by applications to identify execution contexts beyond MPI processes, including threads and GPU streams. MPIX stream communicators can be created to make existing MPI functions thread-aware and GPU-aware, thus providing applications with explicit ways to achieve higher performance. Fourth, MPIX Streams are extended to support the enqueue semantics for offloading MPI communications onto a GPU stream context. Fifth, thread communicators allow MPI communicators to be constructed with individual threads, thus providing a new level of interoperability between MPI and on-node runtimes such as OpenMP. Lastly, we present an extension to invoke MPI progress, which lets users spawn progress threads with fine-grained control to adapt the communication performance to their application designs. We describe the design and implementation of these extensions, provide usage examples, and highlight their expected benefits with performance results.

97 MATHEMATICS AND COMPUTING↗

2020 ETI Annual Summer School: Data Science and Engineering

The Consortium for Enabling Technologies & Innovation (ETI) was established in 2019 to address emerging technologies within the context of nuclear nonproliferation. ETI creates a research and education environment to support cross-cutting technologies across three core disciplines: 1) computer and engineering science research specifically in a form of machine learning and high performance computing (HPC), 2) advanced manufacturing, and 3) nuclear detection technologies. For outreach and development, ETI hosted the first of three summer schools from August 24-28, 2020 with the theme of “Data Science and Engineering”. The school was hosted in an on-line format and had over 200 participants. The recorded content is available on-line as a resource for students. The summer school had four modules: 1) Fundamentals of data Applications, 2) Computational Machine Learning, 3) Bayesian Modeling and Inference, and 4) Data Science for Safeguards. Modules contained both lectures as well as student exercises. Poll Everywhere was utilized in some modules as an on-line method to engage large groups of students. Upcoming ETI Summer Schools include Novel Instrumentation in 2021 and Advanced Manufacturing in 2022.

Biegalski, Steven R.↗

Lessons from Artist in Residence Program Design and Impact

As a national laboratory, Pacific Northwest National Laboratory (PNNL) seeks to be on the leading edge of public interest research and deliver innovation, a core value of the institution. Through the support of the U.S. Department of Energy’s Water Power Technologies Office, PNNL has convened a workshop entitled Advancing Energy Futures through Art in Seattle, Washington, on August 19th and 20th, 2024. An explicit focus on Artist in Residence (AiR) programs initiates the discussion, as this is one of the few clear places where public interest research, artistic engagement, and energy futures have aligned. The workshop proposes to hear from program managers of successful AiR programs, scientists, and artists who work in the energy futures space, to discuss AiR program models and successful modalities for art and storytelling. This paper is provided as background context for workshop participants.

99 GENERAL AND MISCELLANEOUS↗

Dynamic System Scaling Application to Accelerated Nuclear Fuel Testing

The development of nuclear fuel and materials requires a continuous effort to investigate the acute and prolonged effects of irradiation, thermal-material stress, chemical change, or other conceivable damage mechanics acquired during normal operation or accident scenarios throughout its lifetime. As in-core fuel property measurement techniques advance to support in the real-time, non-invasive, and enhanced accuracy realm, it is the future of fuel development to pursue to higher degrees of control, predictability of integral test behavior via separate effects test (SET), and shorter test time intervals. The fuel development life cycle from initial concept to commercial licensing is approximated to be 20 years and current literature suggests by optimizing fuel performance codes with SETs, the process could possibly be compressed to 5 to 10 years. Recently, a research group in the Idaho National Laboratory (INL) is testing reduced scale fuel rods and increased power density to accelerate evolution of fuel phenomena in metallic fuels. In support of nuclear fuel rod development, compressing fuel test process, and accelerating fuel phenomena, it was the purpose of this study to investigate nuclear fuel performance phenomena via literature review and effectively scale the initial conditions, boundary conditions, and geometric properties to describe the time-dependent response including to fuel burnup, thermal and mechanical stress, transmutations and inter-diffusion, and other relevant observed phenomena. The study was based on BISON simulations of historic EBR-II metallic fuel experiments and Dynamical System Scaling (DSS) method are utilized to assess effects of scaling activity including fuel phenomena acceleration and calculations of time-dependent distortions. The research successfully scaled metallic fuel phenomena, accelerated fuel testing, and assessed the distortions for each scaled case derived.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An Overview of Mesoscale Convective Systems: Global Climatology, Satellite Observations, and Modeling Strategies

Deep convection is responsible for redistributing water as well as energy and providing vital water resources for many regions of the world. Cumulonimbus clouds aggregation into a single storm system develop mesoscale convective systems (MCS). MCSs have precipitation covering a horizontal region on the scale of 100?km or more. After more than the last seven decades, MCS has been gradually received wide attention in the scientific community as an important component of the Earth's hydrologic cycle and energy balance. MCSs differ from ordinary deep convection because of the mesoscale circulations consisting of a layer of air overturning on a scale much larger than those created by individual convective updrafts or downdrafts. Moreover, a key feature that separates MCS from ordinary deep convection is the significant portion of stratiform precipitation that results in the production and detrainment of a large number of ice particles from their organized convective cores and continues the mesoscale ascent that supports ice growth and aggregation as the crystals fall. This significant stratiform precipitation gives rise to top-heavy latent heating profiles that have substantial impacts on the upper-level global circulations, especially for those MCS that have a larger portion of stratiform rainfall. Top-heavy latent heating profiles are more frequent over the ocean than over the land. These unique features of MCS suggest that they are important for the hydrologic cycle, general circulation, and radiative balance of the climate system. In this chapter, we focus on the recent advances in the climatological perspective of MCS as well as the research tools used to better understand MCS after the advent of the satellite era. We will discuss both tropical and midlatitude MCS, the influence of modes of tropical climate variability on MCS, and the new insight from satellite observations on MCS interaction with the land surface.

Chakraborty, Sudip↗

Advanced Characterization Capabilities for Nuclear Materials via Nuclear Science User Facilities (NSUF)

Advanced post-irradiation examination (PIE) techniques are required to design new or improved nuclear materials, characterize, and understand in-core behavior of fuel and materials, and support the qualification of new reactor materials. The Nuclear Science User Facilities (NSUF) is the U.S. Department of Energy Office of Nuclear Energy's only designated nuclear science user facility. NSUF provides researchers access to PIE capabilities at Idaho National Laboratory and at a diverse mix of university, national laboratory and industrial partner institutions. The PIE capabilities include novel destructive and non-destructive techniques for radiation damage characterization, such as advanced diffraction techniques (X-ray, electron, or neutron) coupled to extreme environments; in-situ observation of microstructural evolution under irradiation; in-situ irradiation to monitor corrosive attack in coolant environments; in-situ irradiation and mechanical testing; and test methods for synergistic effects of superimposed extreme environments (temperature, irradiation, stress, corrosion) on materials behaviors. This talk will provide an overview of NSUF PIE capabilities.

36 MATERIALS SCIENCE↗

Strain gauge for testing microreactor hexagonal core blocks in the Single Primary Heat Extraction and Removal Emulator

To support the development and deployment of microreactor technologies, experiments that help verify and validate reactor systems and components are performed at non-nuclear test facilities. The Single Primary Heat Extraction Removal Emulator at Idaho National Laboratory is one of these test facilities and was used to monitor a test article that has a prototypic geometry of a heat-pipe cooled microreactor core block. To collect crucial temperature and strain data during testing, temperature and strain sensing fiber optics were embedded to the surface of the test article using an ultrasonic additive manufacturing technique. To support and provide benchmark strain data for the embedded sensors, a commercial resistive strain gauge was attached. This report will discuss the results from the deployment of the commercial strain gauge which includes the setup/attachment strategies, data acquisition, and analysis of the strain data.

36 MATERIALS SCIENCE↗

New Ultrafast Scintillators with Core Valence Luminescence: Cs 2 MgCl 4 and Cs 3 MgCl 5

Future experiments in high energy physics and medical imaging require radiation detectors having properties which are not presently available. The main limitations arise from lack of suitable scintillation crystals. This dilemma prompts the need for research leading to the discovery of new fast and bright scintillator materials that combine unique properties to fulfil modern experiment requirements without compromises. In this work, single crystals of Cs 2 MgCl 4 and Cs 3 MgCl 5 up to 12 mm in diameter are grown via the vertical Bridgman method. Scintillation properties are reported for the first time, and core valence luminescence is observed for both compounds. X-ray excited radioluminescence emission of Cs 2 MgCl 4 is centered at 295 nm, with a scintillation decay time of 2.25 ± 0.05 ns and relatively high core-valence light yield of 2,200 ± 110 ph/MeV. Cs 3 MgCl 5 has two main emission peaks centered at 242 nm and 302 nm, decay time of 1.46 ± 0.05 ns, and light yield of 1,340 ± 70 ph/MeV. The better coincidence time resolution (CTR) is obtained with Cs 2 MgCl 4 , which is measured to be 129 ± 4 ps FWHM. Density functional theory (DFT) calculations are also performed and provide supporting evidence that the observed scintillation originates from core valence luminescence. Furthermore, the combination of speed and brightness of these new scintillators could be useful for fast timing applications in which moderately dense materials are required.

36 MATERIALS SCIENCE↗

Multidisciplinary Constraints on the Thermal‐Chemical Boundary Between Earth's Core and Mantle

Abstract Heat flux from the core to the mantle provides driving energy for mantle convection thus powering plate tectonics, and contributes a significant fraction of the geothermal heat budget. Indirect estimates of core‐mantle boundary heat flow are typically based on petrological evidence of mantle temperature, interpretations of temperatures indicated by seismic travel times, experimental measurements of mineral melting points, physical mantle convection models, or physical core convection models. However, previous estimates have not consistently integrated these lines of evidence. In this work, an interdisciplinary analysis is applied to co‐constrain core‐mantle boundary heat flow and test the thermal boundary layer (TBL) theory. The concurrence of TBL models, energy balance to support geomagnetism, seismology, and review of petrologic evidence for historic mantle temperatures supports Q CMB ∼15 TW, with all except geomagnetism supporting as high as ∼20 TW. These values provide a tighter constraint on core heat flux relative to previous work. Our work describes the seismic properties consistent with a TBL, and supports a long‐lived basal mantle molten layer through much of Earth's history.

58 GEOSCIENCES↗

Optimization of COMPASS-U Support Structure

The global support structure for Compass Upgrade (COMPASS-U) employs many bolted and pinned components to improve the manufacturability of the whole structures. This is a departure from other designs used for highly loaded tokamaks, like Alcator C-Mod which used large forgings. Modeling of the numerous connections and interfaces was a challenge. This article will describe how to optimize the C-frame support structure with the goal to eliminate differential displacements at those interfaces and, importantly, minimize toroidal mutual displacement at the sliding joint of the toroidal field (TF) coils. The global support structure consists of 16 C-frames, and it can be simplified as a 1/8th cyclic symmetry model due to the eight vertical rods mounting that connect bottom CS and PF1-3 assemblies to the C-frames. Structure variants with different connection webs between two neighboring C-frames have been analyzed. The preloading of bolts can be split into several preload substeps to simulate the real assembly process of the COMPASS-U support structure. Additionally, the TF crown and the wedge plate can be further improved to become a solid part to better hold the TF coils.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Observing Chemical and Morphological Changes in a Cu@TiO x Core@Shell Catalyst: Impact of Reversible Metal-Oxide Interactions on CO 2 Activation and Hydrogenation

A combination of several in-situ techniques (XRD, XAS, AP-XPS, E-TEM) was used to explore links between the structural and chemical properties of a Cu@TiO x catalyst under CO 2 hydrogenation conditions. The active phase of the catalyst involved an inverse oxide/metal configuration, but the initial core@shell motif was disrupted during the pre-treatment in H 2 . As a consequence of strong metal-support interactions, the titania shell cracked and Cu particles migrated from the core to on top of the oxide with the simultaneous formation of a Cu-Ti-O x phase. The generated Cu particles had a diameter of 20-40 nm and were decorated by small clusters of TiO x (< 5 nm in size). Results of in-situ XAS and XRD and images of E-TEM showed a very dynamic system, where the inverse oxide/metal configuration promoted the reactivity of the system towards CO 2 and H 2 . At room temperature, CO 2 oxidized the Cu nanoparticles (CO 2,gas → CO gas + O oxide ) inducing a redistribution of the TiO x clusters and big modifications in catalyst surface morphology. The generated oxide overlayer disappeared at elevated temperatures (> 180 °C) upon exposure to H 2 , producing a transient surface that was very active for the reverse water-gas shift reaction (CO 2 + H 2 → CO + H 2 O) but was not stable at 250 °C. When oxidation and reduction occurred at the same time, under a mixture of CO 2 and H 2 , the surface structure evolved toward a dynamic equilibrium that strongly depended on the temperature. Neither CO 2 nor H 2 can be considered as passive reactants. In the Cu@TiO x system, morphological changes were linked to variations in the composition of metal-oxide interfaces which were reversible with temperature or chemical environment and affected the catalytic activity of the system. Finally, the present study illustrates the dynamic nature of phenomena associated with the trapping and conversion of CO 2 .

36 MATERIALS SCIENCE↗

FTTN: Feature-Targeted Testing for Numerical Properties of NVIDIA & AMD Matrix Accelerators

While NVIDIA has been the dominant provider of GPUs for HPC and ML, now AMD has several offerings of GPUs. This encourages programmers to try out AMD GPUs for new codes and also port existing codes over. Unfortunately, without understanding the floating-point differences between these GPU types, software development or porting can introduce bugs—and currently such an understanding is lacking. The magnitude of this open question becomes clear if one imagines the the number of floating-point precision choices (FP16, FP32, etc.), floating-point formats (standard floats, brain-float, etc.), and execution units available (elementary units, matrix/tensor cores, etc.) Questions such as rounding modes and subnormal support are also important. Most of these answers are unknown today or are hard to access. We provide the first testing-guided approach that answers a significant number of these questions. We also devise tests to reveal internal information (e.g., extra bits kept) to make sure that our findings are reliable. Many of our tests employ systematically generated random-programs, others apply fast-math flags and some involve fused multiplyadd. Especially for tensor/matrix cores, the tests have nontrivial logic that we present Our testing approach is reusable for the plethora of GPUs yet to be introduced. Our findings include up to 7 ulps of difference between NVIDIA and AMD for sin and cos at FP32 precision and 3 ulp at FP64. In our study of matrix cores (NVIDIA) and tensor cores (AMD), we have extensively characterized rounding modes (truncation versus round-to-nearest), the number of extra internal bits kept (whether 3 bits are kept or not), subnormal support for inputs and outputs across four different floating-point formats and across NVIDIA A100 and AMD MI250X GPUs. We believe that this wealth of data becoming available for the first time may help avoid significant porting bugs when migrating code across these platforms.

Li, Xinyi↗

Oak Ridge National Laboratory Annual Sustainability Report 2023

ORNL, managed under contract by UT-Battelle LLC, is DOE’s largest science and energy laboratory and, as such, executes the widest range of mission capabilities. Diverse expertise spans a broad range of scientific and engineering disciplines, enabling research and science achievements to accelerate the delivery of solutions to the marketplace. ORNL supports DOE’s national missions of scientific discovery, clean energy, and security. To execute these activities, ORNL has grown significantly over 80 years of continuous operations, consisting of facilities with commissioning dates ranging from the 1940s to the present—an extraordinary set of distinctive scientific facilities and equipment. The complexities of such a variety of facilities require teamwork among divisions, a wide variety of conservation projects, and creative strategies to achieve the desired energy and water savings. Such a diverse and unique set of major facilities, totaling over 5.5 million square feet, with 6,000 employees, requires an innovative plan to accomplish advancements in operational efficiencies. ORNL is tasked with the management of an extraordinary set of distinctive scientific facilities and equipment for DOE. ORNL is mission-driven, and its mission has grown substantially over the decades. ORNL’s core research capabilities provide broad science and technology support for DOE in the areas of energy, environment, and national security. Currently, ORNL is a world leader in materials, neutron, and nuclear science and engineering, and in high-performance computing and data analytics. ORNL’s vast portfolio of research facilities must be maintained and carefully upgraded to protect the nation’s investment in scientific analysis. The goal of sustainable and resilient operations is to enable more effective execution of ORNL’s science and technology mission. Sustainable operational practices and enhanced resilience strive for excellent results while remaining diligent in energy conservation, environmental stewardship, asset management, and community engagement. The Sustainable ORNL Program (Sustainable ORNL) Continuous improvements in operational and business processes must be integrated into the fabric of the ORNL culture to maximize the return from the investment made in modernizing facilities and equipment. The Sustainable ORNL program promotes the legacy of system-wide best practices, management commitment, and employee engagement that will lead ORNL into a future of efficient, resilient, and sustainable operations. ORNL leadership and Sustainable ORNL champions receive regular status reports on the progress of each project and focus area (i.e., roadmap) and periodic summary reports. More information can be found at the program’s website. The Sustainable ORNL roadmap structure endorses 15 vital roadmaps. The figure below summarizes the current project assignments and demonstrates that each project contributes to the wellbeing of the whole. Continuous employee engagement and regular status reports confirm the ideals of the program. The roadmap structure is not static; as the science mission advances and the needs of the organization evolve, the Sustainable ORNL roadmap structure elements are modified to align with developing priorities. In 2022, Sustainable ORNL made roadmap changes to better align ORNL to support new federal requirements that have been issued.

54 ENVIRONMENTAL SCIENCES↗

Expansion of Hazards and Probabilistic Risk Assessments of a Light-Water Reactor Coupled with Electrolysis Hydrogen Production Plants

This report builds upon the body of work sponsored by the Department of Energy (DOE) Light-Water Reactor Sustainability (LWRS) Flexible Power Operation and Generation (FPOG) program that presented generic probabilistic risk assessments (PRAs) for the addition of a heat extraction system (HES) to light-water reactors to support the co-location of a high temperature hydrogen electrolysis facility (HTEF). Probabilistic and deterministic hazards assessments and risk analyses are leveraged throughout this report. Several improvements and new analyses are included in this report. First, higher amounts of detail in the specifications of the generic HTEFs are used to produce scaled results for a 100, 500, and 1000 MW nominal hydrogen production facility. An additional hazard assessment of 1000 kg of hydrogen storage is performed. The facility hazards and footprint are assessed to determine the safe distance required for placement near the nuclear power plant (NPP). Second, specific designs for corresponding HESs for the different levels of support required by the HTEFs are analyzed in the PRA model. Third, a hazards analysis of the specified HTEFs leads not only to effects of the quantified risk assessment for the NPP, but also qualitative hazards assessment for the community. Finally, a seismic analysis and a high winds analysis have each been added to the PRA. The results investigate the applicability of the potential licensing approaches which do not require a full United States (U.S.) Nuclear Regulatory Commission (NRC) licensing review. The PRAs are generic and include listed assumptions. The HTEF design built for this project has further eliminated many conservative assumptions from the prior PRAs in this series. The PRA results indicate that the 10 CFR 50.59 licensing approach is justified due to the minimal increase in initiating event frequencies for all design basis accidents, with none exceeding 7.7%. The PRA results for core damage frequency and large early release frequency support the use of NRC Regulation Guide 1.174 as further risk information that supports a change without a full licensing amendment review. The hazard analyses and PRA confirm the need for engineered blast barriers of storage tanks and the common production header leaving the HTEF. The hazards analyses and PRA also confirm with high confidence that using the assumptions of design in this report that the safety case for licensing an HES addition and an HTEF sited with its unprotected high-pressure stage components 187 meters from the NPP’s transmission towers (the most fragile structure, system, and component) is strong.

08 HYDROGEN↗

Sensitivity of the latitude of the westerly jet stream to climate forcing

The latitude of the westerly jet stream is influenced by a variety of climate forcings. Their effects often manifest as a tug-of-war between tropical forcing, characterized by tropical upper-tropospheric warming, and polar forcing, with a signature of Antarctic stratospheric cooling or Arctic amplification. Here we present a unified forcing-feedback frame work relating different climate forcings to their forced jet changes, in which the interactions between the westerly jet and synoptic storms are synthesized by a zonal advection feedback, analogous to the feedback framework for assessing climate sensitivity. This framework is supported by a prototype feedback analysis in the atmospheric dynamical core of a climate model with diverse thermal and mechanical forcings. Our analysis indicates that the latitude of a westerly jet is most sensitive to the thermally-induced jet speed changes near the tropopause. The jet shift also displays a larger sensitivity than linearity for the equatorward shift.

atmospheric dynamics, atmospheric variability, cli↗