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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

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NASA NTRS1979

Extended duration orbiter study: CO2 removal and water recovery

Two electrochemical depolarized carbon dioxide concentrator subsystems were evaluated against baseline lithium hydroxide for (1) the baseline orbiter when expanded to accommodate a crew of seven (mission option one), (2) an extended duration orbiter with a power extension package to reduce fuel cell expendables (mission option two), and (3) an extended duration orbiter with a full capability power module to eliminate fuel cell expendables (mission option three). The electrochemical depolarized carbon dioxide concentrator was also compared to the solid amine regenerable carbon dioxide removal concept. Water recovery is not required for Mission Option One since sufficient water is generated by the fuel cells. The vapor compression distillation subsystem was evaluated for mission option two and three only. Weight savings attainable using the vapor compression distillation subsystem for water recovery versus on-board water storage were determined. Combined carbon dioxide removal and water recovery was evaluated to determine the effect on regenerable carbon dioxide removal subsystem selection.

Marshall, R. D.↗

NASA NTRS1979

Low NO(x) heavy fuel combustor program

The 'low nitrogen oxides heavy fuel combustor' program is described. Main program objectives are to generate and demonstrate the technology required to develop durable gas turbine combustors for utility and industrial applications, which are capable of sustained, environmentally acceptable operation with minimally processed petroleum residual fuels. The program will focus on 'dry' reductions of oxides of nitrogen, improved combustor durability, and satisfactory combustion of minimally processed petroleum residual fuels. Other technology advancements sought include: fuel flexibility for operation with petroleum distillates, blends of petroleum distillates and residual fuels, and synfuels (fuel oils derived from coal or shale); acceptable exhaust emissions of carbon monoxide, unburned hydrocarbons, sulfur oxides and smoke; and retrofit capability to existing engines.

Lister, E.↗

NASA NTRS1980

Fuel/engine/airframe tradeoff study, phase 1

The effects of broadening the specifications for JP-4 and JP-8 fueled on the performance and cost of all USAF aircraft presently using JP-4 as well as those expected to be introduced into the force structure by 1983 are investigated. Test results indicated that there was no impact on engine performance, turbine durability, and coking, however there was a small maintenance cost increase as a result of a small combustor life decrease. Using JP-4 as standard fuel will avoid the use of high demand middle distillate fuels and give producers flexibility. Extensive use of JP-8 in the United States will increase middle distillate demand and cause a slight increase in engine hot-section maintenance. It is also concluded that the maximum allowable freeze point of JP-4 or JP-8 cannot be increased without degrading system performance and safety as critical conditions are approached.

Peacock, A. T.↗

NASA NTRS1980

Fuels characterization studies

Current analytical techniques used in the characterization of broadened properties fuels are briefly described. Included are liquid chromatography, gas chromatography, and nuclear magnetic resonance spectroscopy. High performance liquid chromatographic ground-type methods development is being approached from several directions, including aromatic fraction standards development and the elimination of standards through removal or partial removal of the alkene and aromatic fractions or through the use of whole fuel refractive index values. More sensitive methods for alkene determinations using an ultraviolet-visible detector are also being pursued. Some of the more successful gas chromatographic physical property determinations for petroleum derived fuels are the distillation curve (simulated distillation), heat of combustion, hydrogen content, API gravity, viscosity, flash point, and (to a lesser extent) freezing point.

Seng, G. T.↗

NASA NTRS1980

Low NO/x/ heavy fuel combustor program

The paper deals with the 'Low NO/x/ Heavy Fuel Combustor Program'. Main program objectives are to generate and demonstrate the technology required to develop durable gas turbine combustors for utility and industrial applications, which are capable of sustained, environmentally acceptable operation with minimally processed petroleum residual fuels. The program will focus on 'dry' reductions of oxides of nitrogen (NO/x/), improved combustor durability and satisfactory combustion of minimally processed petroleum residual fuels. Other technology advancements sought include: fuel flexibility for operation with petroleum distillates, blends of petroleum distillates and residual fuels, and synfuels (fuel oils derived from coal or shale); acceptable exhaust emissions of carbon monoxide, unburned hydrocarbons, sulfur oxides and smoke; and retrofit capability to existing engines.

Lister, E.↗

NASA NTRS1981

Corrosion fatigue of Inconel 718 and Incoloy 903

Corrosion fatigue tests were conducted on Inconel 718 and Incoloy 903 in distilled water, 500 ppm NaCl, and 3.5% NaCl. Results were compared to the endurance limit in air. For Inconel 718, the corrosion fatigue strength (CFS) IN 3.5% NaCl WAS 328 MPa or 75 percent of the endurance limit. For Incoloy 903, the CFS ranged from 234 MPa in distilled water (68 percent of the endurance limit) to 103 MPa in 3.5% NaCl (30 percent of the endurance limit). Results indicate that, for components which have limited fatigue life, an evaluation of the combined effects of fatigue and the corrosive atmosphere must be considered in projecting useful lifetimes.

Franklin, D. B.↗

NASA NTRS1982

Silicon production process evaluations

Engineering design of the third distillation column in the process was accomplished. The initial design is based on a 94.35% recovery of dichlorosilane in the distillate and a 99.9% recovery of trichlorosilane in the bottoms. The specified separation is achieved at a reflux ratio of 15 with 20 trays (equilibrium stages). Additional specifications and results are reported including equipment size, temperatures and pressure. Specific raw material requirements necessary to produce the silicon in the process are presented. The primary raw materials include metallurgical grade silicon, silicon tetrachloride, hydrogen, copper (catalyst) and lime (waste treatment). Hydrogen chloride is produced as by product in the silicon deposition. Cost analysis of the process was initiated during this reporting period.

Source record↗

NASA NTRS1985

Space shuttle revitalization system

The Space Shuttle air revitalization system is discussed. The sequential steps in loop closure are examined and a schematic outline of the regenerative air revitalization system is presented. Carbon dioxide reduction subsystem concepts are compared. Schemes are drawn for: static feedwater electrolysis cell, solid polymer electrolyte water electrolysis cell, air revitalization system, nitrogen generation reactions, nitrogen subsystem staging, vapor compression distillation subsystem, thermoelectric integrated membrane evaporation subsystem, catalytic distillation water reclamation subsystem, and space shuttle solid waste management system.

Quattrone, P. D.↗

NASA NTRS1984

Henry's law constants for dimethylsulfide in freshwater and seawater

Distilled water and several waters of varying salinity were subjected, over a 0-32 C temperature range, to measurements for Henry's law constants for dimethylsulfide. Values for distilled water and seawater of the solubility parameters A and C are obtained which support the concept that the concentration of dimethylsulfide in the atmosphere is far from equilibrium with seawater.

Dacey, J. W. H.↗

NASA NTRS1985

Mineral chemistry and origin of spinel-rich inclusions in the Allende CV3 chondrite

The present electron probe microanalysis of 20 spinel-rich inclusions in Allende indicates that the mineralogy of spinel-rich Allende inclusions is similar to that of fine grained Ca, Al-rich inclusions (CAIs) in ALH-77003 and rims on coarse grained CAIs in Allende. The mineralogy, mineral chemistry, and bulk chemistry of the inclusions indicate that they are not primitive aggregates of crystalline nebular condensates, but rather aggregates of minute concentric objects that are presently interpreted to be a fractionated distillation residue that lost Ca, Si-rich partial melt. It is suggested that interstellar dust aggregates were melted or distilled into Allende inclusions by aerodynamic drag heating, in regions of the nebula where the dust/gas ratio was so enhanced that the local oxygen fugacity was raised by several order of magnitude and liquids became thermodynamically stable.

Kornacki, A. S.↗

NASA NTRS1986

Utilization of membranes for H2O recycle system

Conceptual studies of closed ecological life support systems (CELSS) carried out at NAL in Japan for a water recycle system using membranes are reviewed. The system will treat water from shower room, urine, impure condensation from gas recycle system, and so on. The H2O recycle system is composed of prefilter, ultrafiltration membrane, reverse osmosis membrane, and distillator. Some results are shown for a bullet train of toilet-flushing water recycle equipment with an ultraviltration membrane module. The constant value of the permeation rate with a 4.7 square meters of module is about 70 1/h after 500th of operation. Thermovaporization with porous polytetrafluorocarbon membrane is also proposed to replce the distillator.

Ohya, H.↗

NASA NTRS1985

Phase change water processing for Space Station

The use of a vapor compression distillation subsystem (VCDS) for water recovery on the Space Station is analyzed. The self-contained automated system can process waste water at a rate of 32.6 kg/day and requires only 115 W of electric power. The improvements in the mechanical components of VCDS are studied. The operation of VCDS in the normal mode is examined. The VCDS preprototype is evaluated based on water quality, water production rate, and specific energy. The relation between water production rate and fluids pump speed is investigated; it is concluded that a variable speed fluids pump will optimize water production. Components development and testing currently being conducted are described. The properties and operation of the proposed phase change water processing system for the Space Station, based on vapor compression distillation, are examined.

Zdankiewicz, E. M.↗

NASA NTRS1987

Cellular monotectic model solidification

Succinonitrile (sn) was purified to a superior level using a fractional recrystallization method. The melting point of the best twice recrystallized sn was not raised by following with double distillation. This was tested using differential scanning calorimetry. The peak shape on melting also proved that double distillation after double recrystallization did not improve the quality. Stability and phase diagrams for succinonitrile and glycerol are presented.

Kaukler, William F.↗

NASA NTRS1989

Nonaggregating Microspheres Containing Aldehyde Groups

Cobalt gamma irradiation of hydrophilic monomers in presence of acrolein yields exceptionally-stable, nonaggregating microspheres. Mixtures of 2-hydroxyethyl methacrylate (HEMA) and acrolein form homogeneous solutions in distilled water containing 0.4 percent polyethylene oxide (PEO). After deaeration with nitrogen, mixtures irradiated at room temperature with gamma rays from cobalt source; total exposure time 4 hours, at rate of 0.2 milliroentgen per hour. Reaction product centrifuged three times for purification and kept in distilled water.

Rembaum, Alan↗

NASA NTRS1988

Characterization of cobalt(II) chloride-modified condensation polyimide films

The effect of solvent extraction on the properties of cobalt(II) chloride-modified polyimide films was investigated. Solvent-cast films were prepared from solutions of cobalt chloride in poly(amide acid)/N,N-dimethylacetamide (DMAc) and were subsequently dried and cured in static air, forced air, or inert gas ovens with controlled humidity. The films were extracted by either of the three processes (1) soaking in a tray with distilled water at room temperature, (2) soxhlett extraction with distilled water, or (3) soxhell extraction with DMAc. Extraction with DMAc was found to remove both cobalt and chlorine from the films and to slightly increase bulk thermal stability and both surface resistivity and electrical resistivity.

Rancourt, J. D.↗

NASA NTRS1921

Comparison of hecter fuel with export aviation gasoline

Among the fuels which will operate at compression ratios up to at least 8.0 without preignition or "pinking" is hecter fuel, whence a careful determination of its performance is of importance. For the test data presented in this report the hecter fuel used was a mixture of 30 per cent benzol and 70 per cent cyclohexane, having a low freezing point, and distilling from first drop to 90 per cent at nearly a constant temperature, about 20 degrees c. below the average distillation temperature ("mean volatility") of the x gasoline (export grade). The results of these experiments show that the power developed by hecter fuel is the same as that developed by export aviation gasoline at about 1,800 r.p.m. at all altitudes. At lower speeds differences in the power developed by the fuels become evident. Comparisons at ground level were omitted to avoid any possibility of damaging the engine by operating with open throttle on gasoline at so high a compression. The fuel consumption per unit power based on weight, not volume, averaged more than 10 per cent greater with hecter than with x gasoline. The thermal efficiency of the engine when using hecter is less than when using gasoline, particularly at higher speeds. A generalization of the difference for all altitudes and speeds being 8 per cent. A general deduction from these facts is that more hecter is exhausted unburnt. Hecter can withstand high compression pressures and temperature without preignition. (author)

Dickinson, H C↗

NASA NTRS1992

Airborne rotary separator study

Several air breathing propulsion concepts for future earth-to-orbit transport vehicles utilize air collection and enrichment, and subsequent storage of liquid oxygen for later use in the vehicle mission. Work performed during the 1960's established the feasibility of substantially reducing weight and volume of a distillation type air separator system by operating the distillation elements in high 'g' fields obtained by rotating the separator assembly. The purpose of this study was to evaluate various fuels and fuel combinations with the objective of minimizing the weight and increase the ready alert capability of the plane. Fuels will be used to provide energy as well as act as heat sinks for the on-board heat rejection system. Fuel energy was used to provide power for air separation as well as to produce refrigeration for liquefaction of oxygen enriched air, besides its primary purpose of vehicle propulsion. The heat generated in the cycle was rejected to the fuel and water which is also carried on board the vehicle.The fuels that were evaluated include JP4, methane, and hydrogen. Hydrogen served as a comparison to the JP4 and methane cases.

Drnevich, R. F.↗

NASA NTRS1996

Liquefaction Of Coal With Surfactant And Disposable Catalyst

Fuels derived from coal more competitive with petroleum products. Improved coal-liquefaction process exploits synergistic effects of disposable iron oxide catalyst and cheap anionic surfactant. Efficiency of conversion achieved in significantly higher than efficiencies obtained with addition of either surfactant or catalyst alone. No costly pretreatment necessary, and increase in conversion achieved under processing conditions milder than those used heretofore in liquefaction of coal. Quality of distillates obtained after liquefaction in process expected superior to distillates obtained after liquefaction by older techniques.

Hickey, Gregory S.↗