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NASA NTRS1991

Combustion of unsupported methanol/dodecanol mixture droplets at low gravity

Experiments are reported on the combustion of free or unsupported methanol/dodecanol mixture droplets in a reduced gravity environment. The experiments were conducted in a drop tower. The Grashof number (based on drop diameter) in the moving frame of reference was on the order of 10 exp -5 for the period of droplet burning. Combustion of the mixture droplets was characterized by a multi-stage process indicative of diffusion controlled burning. The flame was not visible during the first stage because of the lighting used, but was visible (and spherical) in the final stage. The results suggested that the mixture droplets did not extinguish. By contrast, methanol droplets consistently extinguished. Microexplosions were not observed for mixtures with initial concentrations of equal volumes of methanol and dodecanol. However, most of the droplets containing initially 75 percent (by volume) of methanol exploded. The initiation of microexplosion, as defined by the occurrence of homogeneous nucleation within the droplet, is explained by comparing the calculated nonlinear variation of superheat limit with composition for a methanol/dodecanol mixture with the boiling point of dodecanol.

Yang, J. C.↗
NASA NTRS1979

Investigation of critical burning of fuel droplets

The general problem of spray combustion was investigated. The combustion of bipropellent droplets; combustion of hydrozine fuels; and combustion of sprays were studied. A model was developed to predict mean velocities and temperatures in a combusting gas jet.

Faeth, G. M.↗
NASA NTRS1991

Extinction of a Free Methanol Droplet in Microgravity

The combustion of isolated, unsupported methanol droplets under microgravity conditions has been studied in the NASA-Lewis 2.2-sec drop tower. The substitution of O2/He mixtures for O2/N2 mixtures results in a substantial increase in the oxygen index required for ignition, the rate of gasification, and the diameter at extinction. As a result, droplets with initial size larger than 1 mm can be produced, deployed, ignited, and burned to extinction, all under microgravity conditions in this facility. A comprehensive time dependent numerical model incorporating detailed multicomponent molecular transport mechanisms and complex elementary chemical kinetics was developed and applied to simulate the entire transient droplet combustion processes (ignition/quasi-steady burning/extinction). Model outputs show good agreement with the experimental measurements, without parameter adjustment. Analysis of modeling results shows that the thermal conductivity of the gas phase under combustion environments increased by a factor of two when the 50-percent O2/50 percent He mixture is used instead of air. The increased thermal conductivity accelerates the heat transfer from the flame front to the droplet surface, resulting in a factor of two increase in the burning rate.

Cho, S. Y.↗
NASA NTRS1991

Pressure-coupled vaporization and combustion responses of liquid-fuel droplets in high-pressure environments

The dynamic responses of liquid-fuel droplet vaporization and combustion to ambient pressure oscillations are examined. The analysis is based on the complete sets of conservation equations for both gas and liquid phases, and accommodates detailed treatments of finite-rate chemical kinetics and variable properties. With a full account of thermodynamic phase equilibrium at the droplet surface, the model enables a systematic examination of the effects of ambient flow conditions on the droplet behavior. The responses of hydrocarbon fuel droplets in both sub- and super-critical environments are investigated. Results indicate that the droplet gasification and burning mechanisms depend greatly on the ambient pressure. In particular, a rapid enlargement of the vaporization and combustion responses occurs when the droplet surface reaches its critical point, mainly due to the strong variations of latent heat of vaporization and thermophysical properties at the critical state.

Yang, Vigor↗
NASA NTRS2001

Some Recent Observations on the Burning of Isolated N-Heptane and Alcohol Droplets

In a joint program involving Prof. F.A. Williams of the University of California, San Diego and Dr. V. Nayagam of the National Center for Microgravity Research on Combustion and Fluid Dynamics, the combustion of liquid fuel droplets of n-heptane, n-decane, methanol, methanol-water, ethanol and ethanol-water having initial diameters between about 1 mm and 6 mm continues to be studied. The objectives of the work are to improve fundamental knowledge of droplet combustion dynamics for pure fuels and fuel-water mixtures through microgravity experiments and theoretical analyses. The Princeton contributions to the collaborative program supports the engineering design, data analysis, and data interpretation requirements for the study of initially single component, spherically symmetric, isolated droplet combustion studies through experiments and numerical modeling. The complementary UCSD contributions apply asymptotic theoretical analyses and are described in the published literature and in a companion communication in this conference. The combined program continues to focus on analyses of results obtained from Fiber Supported Droplet Combustion (FSDC) experiments (FSDC-2, STS- 94) conducted with the above fuels in shuttle cabin air and Droplet Combustion Experiment (DCE) data obtained for unsupported and fiber supported droplets of n-heptane in Helium-Oxygen mixtures and cabin air (STS-83, STS-94). The program is preparing for a second DCE experimental mission using methanol/methanol-water as fuels and helium-oxygen-nitrogen environments. DCE-2 is to be conducted aboard the International Space Station. Emphases of recent Princeton work are on the study of simple alcohols (methanol, ethanol) and alcohol/water mixtures as fuels, with time-dependent measurements of drop size, flame-standoff, liquid-phase composition, and finally, extinction. Ground based experiments have included bench-scale studies at Princeton and collaborative experimental studies in the 2.2 second drop tower at NASA-Glenn Research Center.

Dryer, F. L.↗
NASA NTRS2003

Droplet Vaporization In A Levitating Acoustic Field

Combustion experiments using arrays of droplets seek to provide a link between single droplet combustion phenomena and the behavior of complex spray combustion systems. Both single droplet and droplet array studies have been conducted in microgravity to better isolate the droplet interaction phenomena and eliminate or reduce the effects of buoyancy-induced convection. In most experiments involving droplet arrays, the droplets are supported on fibers to keep them stationary and close together before the combustion event. The presence of the fiber, however, disturbs the combustion process by introducing a source of heat transfer and asymmetry into the configuration. As the number of drops in a droplet array increases, supporting the drops on fibers becomes less practical because of the cumulative effect of the fibers on the combustion process. To eliminate the effect of the fiber, several researchers have conducted microgravity experiments using unsupported droplets. Jackson and Avedisian investigated single, unsupported drops while Nomura et al. studied droplet clouds formed by a condensation technique. The overall objective of this research is to extend the study of unsupported drops by investigating the combustion of well-characterized drop clusters in a microgravity environment. Direct experimental observations and measurements of the combustion of droplet clusters would provide unique experimental data for the verification and improvement of spray combustion models. In this work, the formation of drop clusters is precisely controlled using an acoustic levitation system so that dilute, as well as dense clusters can be created and stabilized before combustion in microgravity is begun. While the low-gravity test facility is being completed, tests have been conducted in 1-g to characterize the effect of the acoustic field on the vaporization of single and multiple droplets. This is important because in the combustion experiment, the droplets will be formed and levitated prior to ignition. Therefore, the droplets will begin to vaporize in the acoustic field thus forming the "initial conditions" for the combustion process. Understanding droplet vaporization in the acoustic field of this levitator is a necessary step that will help to interpret the experimental results obtained in low-gravity.

Ruff, G. A.↗
NASA NTRS1999

Combustion of Two-Component Miscible Droplets in Reduced Gravity

This paper presents recent theoretical and experimental results from an ongoing research program that deals with reduced-gravity combustion of bi-component droplets initially in the mm size range or larger. The primary objectives of the research are to study the effects of droplet internal flows, thermal and solutal Marangoni stresses, and species volatility differences on liquid species transport and overall combustion phenomena (e.g., gas-phase unsteadiness, burning rates, sooting, radiation, and extinction). The research program utilizes a reduced-gravity environment so that buoyancy effects are rendered negligible. Use of large droplets also facilitates visualization of droplet internal flows, which is important to this research. This program is a continuation of extensive ground based experimental and theoretical research on bi-component droplet combustion which has been ongoing for several years. The focal point of this research program is a flight experiment (Bi-Component Droplet Combustion Experiment, BCDCE). This flight experiment is still under development. However, supporting ground studies have been performed, and preliminary data have been obtained from flight experiments (Fiber Supported Droplet Combustion Experiment, FSDC-1 and FSDC-2). These flight experiments were performed during the STS-73/USML-2 and STS-94/MSL- I missions. In the experiments, droplets composed of low- and high-volatility species are burned. The low-volatility components are initially present in small amounts. As combustion of a droplet proceeds, the liquid surface mass fraction of the low-volatility component will increase with time, resulting in a sudden and temporary decrease in droplet burning rates as the droplet rapidly heats to temperatures close to the boiling point of the low-volatility component. This decrease in burning rates causes a sudden and temporary contraction of the flame. The decrease in burning rates and the flame contraction can be observed experimentally. Measurements of burning rates as well as the onset time for flame contraction allow effective liquid-phase species diffusivities to be calculated, e.g., using asymptotic theory. A goal of the research is to relate effective liquid species diffusivities to droplet internal flow characteristics. Droplet internal flows will be visualized in future flight and ground-based experiments.

Shaw, B. D.↗
NASA NTRS1991

Evaluation of an efficient statistical transport model for turbulent droplet dispersion in dilute combusting sprays

Evaluation of an efficient statistical transport model for turbulent droplet dispersion is made for a dilute spray of methanol droplets injected into a turbulent, axisymmnetric methane-fuelled diffusion flame burning in stagnant air. In the dispersion model, a computational parcel representing a group of physical particles (droplets) is considered to have a normal probability density function (pdf) in space. The mean is determined by Lagrangian tracking through a sequence of stochastically generated turbulent eddies and the variance is evaluated from a statistical formulation based on the linearized particle equations of motion. The basic validity of this model is established through comparison with available experimental data and with theoretical predictions using a conventional stochastic direct modeling approach. The conclusion of the evaluation is that the proposed dispersion model compares favorably with experimental data and provides a valid technique for simulating turbulent combusting sprays with significant computational savings over conventional methods.

Litchford, Ron J.↗
NASA NTRS1979

Dispersion of sound in a combustion duct by fuel droplets and soot particles

Dispersion and attenuation of acoustic plane wave disturbances propagating in a ducted combustion system are studied. The dispersion and attenuation are caused by fuel droplet and soot emissions from a jet engine combustor. The attenuation and dispersion are due to heat transfer and mass transfer and viscous drag forces between the emissions and the ambient gas. Theoretical calculations show sound propagation at speeds below the isentropic speed of sound at low frequencies. Experimental results are in good agreement with the theory.

Miles, J. H.↗
NASA NTRS1979

Dispersion of sound in a combustion duct by fuel droplets and soot particles

Dispersion and attenuation of acoustic plane wave disturbances propagating in a ducted combustion system are studied. The dispersion and attenuation are caused by fuel droplet and soot emissions from a jet engine combustor. The attenuation and dispersion are due to heat transfer and mass transfer and viscous drag forces between the emissions and the ambient gas. Theoretical calculations show sound propagation at speeds below the isentropic speed of sound at low frequencies. Experimental results are in good agreement with the theory.

Miles, J. H.↗
NASA NTRS1999

Some Recent Observations on the Burning of Isolated N-Heptane and Alcohol Droplets

In a joint program involving Prof F.A. Williams of the University of California, San Diego and Dr. Vedha Nayagam of the National Center for Microgravity Research on Fluid and Combustion, the combustion of liquid fuel droplets having initial diameters between about 1 mm and 6 mm is being studied. The objectives of the work are to improve fundamental knowledge of droplet combustion dynamics through microgravity experiments and theoretical analyses. The Princeton contributions to the collaborative program supports the engineering design, data analysis, and data interpretation requirements for the study of initially single component, spherically symmetric, isolated droplet combustion studies through experiments and numerical modeling. The complementary UCSD contributions apply asymptotic theoretical analyses and are described in the published literature and in a companion communication in this volume. Emphases of the Princeton work are on the study of simple alcohols (methanol, ethanol), alcohol/water mixtures, and pure alkanes (n-heptane, n-decane) as fuels, with time dependent measurements of drop size, flame-stand-off, liquid-phase composition, and finally, extinction. Ground based experiments have included bench-scale studies at Princeton and collaborative experimental studies in the 2.2 and 5.18 second drop towers at NASA-Glenn Research Center. Spacelab studies have included fiber-supported droplet combustion (FSDC) experiments in the Glovebox facility with accompanying numerical analyses. Experiments include FSDC-1, performed on the USML-2 mission in October, 1995 (STS-73) and FSDC-2, on the second flight of the MSL-1 mission in July, 1997 (STS-94).

Dryer, F. L.↗
NASA NTRS1995

Combustion of two-component miscible droplets in reduced gravity

This research focuses on the combustion of binary miscible droplets initially in the mm size range. Experiments are performed using the NASA Lewis 2.2 sec drop tower in Cleveland, Ohio, where mixtures of alkanes and/or alcohols are studied. The fuel components are selected to have significantly different volatilities. Initial oxygen mole fractions from about 0.15-0.5 and initial pressures from 0.2-2 atm are employed. Different inerts are used (He, CO2, Ar, N2) to change burning rates and sooting behaviors. Objectives are to observe the following: (1) Transient droplet diameters (including three-staged combustion behaviors and microexplosion; (2) Transient flow behaviors (sudden flame contraction, luminosity, extinction); and (3) Behaviors of observable soot particles. theoretical and computational research in support of this program has also been undertaken. This research includes analytical studies to determine the effects of small but nonzero gravitational levels on droplet gasification, analytical studies of hydrodynamic stability of spherically-symmetrical droplet gasification (to address the question as to whether spherically-symmetrical droplet gasification may be destabilized from capillary, i.e., Marangoni effects), and computational modeling of effects of capillary stresses on droplet gasification.

Shaw, Benjamin D.↗
NASA NTRS1990

Non-grey radiation in a liquid rocket combustion chamber

The effects of radiation on droplets gasification in liquid rocket combustion chambers has been studied. The modeling includes a Legendre pseudo-spectral collocation approximation to solve the Radiative Transfer Equation (RTE). The band model has been utilized to account for non-grey emitting and absorbing gases present in the comustion chamber. The GEMCHIP II code has been utilized to study the fuel and oxidizer droplets combustion and interaction. The submodels within this code are capable of accounting for group combustion and conjugate effects between many droplets. The radiative model has been coupled with the GEMCHIP II code accounting for radial effects only, to provide the tool for studying the combustion-radiation coupling effects in a bipropellant system. The results indicate that the gasification/combustion process will be enhanced upstream of the chamber causing thicker flame sheet and associated higher combustion efficiency.

Kehtarnavaz, H.↗
NASA NTRS1999

Pressure Effects on Combustion of Methanol and Methanol-Docecanol Droplets

The objective of this research is to improve understanding of the combustion of binary fuel mixtures in the vicinity of the critical point. Fiber-supported single droplets and two-droplet arrays of methanol and of mixtures of methanol and 1-dodecanol, initially 0.9 mm in diameter, were burned in room-temperature air at pressures from 0.1 MPa to 9.0 MPa in the NASA Lewis 2.2-second drop tower. The work is a continuation of a collaborative Japan-US research effort designed to increase knowledge of high-pressure combustion of fuel sprays, relevant to application in propulsive and power-production devices such as Diesel engines. Some previous publications from this cooperative program may be cited. All of the previous experiments concerned alkanes and alkane mixtures. The new research reported here addresses alcohols and alcohol mixtures, to ascertain the degree to which previous results for alkanes extend to alcohols. There have been many previous experimental studies of methanol droplet combustion and a few of alcohol mixtures, but not at the high pressures of interest here. There is some experimental information on methanol droplet combustion at elevated pressure but none on the alcohol mixtures extending to critical pressures, as in the present study.

Okai, K.↗
NASA NTRS1975

Investigation of critical burning of fuel droplets

Steady and unsteady combustion of liquid fuel droplets under rocket engine conditions was analyzed. Emphasis was placed on combustion at elevated pressures and temperatures. The results and their technical application to the design of liquid fueled rocket engines and the determination of combustion instability characteristics of these engines were summarized.

Faeth, G. M.↗