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At least 181 records · Page 10

Causes and effects of a hole

Preliminary results from the U.S. National Ozone Expedition (NOZE) to Antarctica are reviewed. The NOZE ozonesonde measurements showed significant vertical structure in the hole, with 80 percent depletion in some of the 1 km layers but only 20 percent in adjacent layers. The depletion was confined to the 12-20 km region, beginning first at higher altitude and progressing downward. This is strong evidence against the theory that the ozone hole is due to solar activity producing odd nitrogen at high altitudes which is transported downwards, leading to enhanced odd-nitrogen catalytic cycles that destroy ozone. Nitrous oxide data show unusually low concentrations within the polar vortex, which is evidence against the theory that the hole is caused by a purely dynamical mechanism in which rising air motions within the polar vortex lead to reduced column densities of ozone. It is tentatively concluded that a chemical mechanism involving man-made chlorofluorocarbons is the likely cause of ozone depletion in the hole.

Margitan, J. J.↗

Influence of electron radiation and temperature on the cyclic, matrix dominated response of graphite-epoxy

The effects of electron radiation and elevated temperature on the matrix-dominated cyclic response of standard T300/934 and a chemically modified T300/934 graphite-epoxy are characterized. Both materials were subjected to 1.0 x 10 to the 10th rads of 1.0 MeV electron irradiation, under vacuum, to simulate 30 years in geosynchronous orbit. Cyclic tests were performed at room temperature and elevated temperature (121 C) on 4-ply unidirectional laminates to characterize the effects associated with irradiation and elevated temperature. Both materials exhibited energy dissipation in their response at elevated temperature. The irradiated modified material also exhibited energy dissipation at room temperature. The combination of elevated temperature and irradiation resulted in the most severe effects in the form of lower proportional limits, and greater energy dissipation. Dynamic-mechanical analysis demonstrated that the glass transition temperature, T(g), of the standard material was lowered 39 C by irradiation, wereas the T(g) of the modified material was lowered 28 C by irradiation. Thermomechanical analysis showed the occurrence of volatile products generated upon heating of the irradiated materials.

Reed, Susan M.↗

Structure property behavior of polyimide siloxane segmented copolymers

Procedures were developed for preparing soluble fully imidized polyimide-polydimethyl siloxane segmented copolymers of wide ranging compositions. At low siloxane levels, the materails behave as modified polyimides. At higher concentrations, the materials are analogous to thermoplastic elastomers. Characterization by dynamic mechanical and thermal analysis methods will be reported along with an assesment of the bulk mechanical properties and the surface behavior. The surface behavior is particularly interesting since the materials can be tailored to have siloxane surfaces even at rather low siloxane contents. This influences a number of properties such as the coefficient of friction and, importanly, the degradation of these materials under aggressive oxygen environments (e.g., atomic oxygen, oxygen plasma).

Arnold, C. A.↗

Physical aging in epoxy matrices and composites

Postcured specimens of Thornell 300 carbon-fiber/Fiberite 934 epoxy as well as Fiberite 934 epoxy resin were quenched from above the glass transition temperature and annealed at 140, 110, or 80 C for times up to 100,000 min. No weight gain or loss was observed during annealing at these temperatures, but significant time-dependent variations were observed in density, modulus, hardness, damping, moisture absorption ability, and thermal expansion characteristics. The relations between the excess thermodynamic properties of epoxy glasses and their time-dependent behavior are discussed. The discussion is illustrated by results obtained by differential scanning calorimetry, dynamic mechanical analysis, tensile testing, solid state nuclear magnetic resonance spectroscopy, and small-angle X-ray scattering.

Kong, Eric Siu-Wai↗

Body force circulation and the Antarctic Ozone minimum

A dynamical mechanism, which is relevant to the ozone-depletion problem and which involves a 'body force' circulation discussed by Eliassen (1951), is considered. The body force problem and its application to 'generic' upper-tropospheric wave-driving are discussed theoretically. Following a review of the interhemispheric differences in the winter and early-spring circulation, the elliptic equation governing the residual mean meridional streamfunction is derived, and its analytic-solution properties in negligible shear are discussed. Finally, a numerical solution is derived using the observed August winds under the assumption of radiative equilibrium, and the effect of diabatic heating is discussed.

Dunkerton, Timothy J.↗

Infrared measurements of column amounts of stratospheric constituents in the Antarctic winter, 1987

The discovery of Farman et al. of recent large depletions of ozone in the Antarctic stratosphere in the austral spring has aroused great interest because of its serious potential consequences, as well as its surprising nature. An airborne expedition, including 21 experiments on two aircraft, was mounted for Punta Arenas, Chile, in August and September, 1987, to gather a wide range of data to understand the origins and implications of this phenomenon, known as the ozone hole. As a part of this expedition, a high resolution Fourier transform spectrometer was flown on the DC-8, measuring the column amount of a number of trace gases above the flight altitude. Column results are presented only from the flight of September 21; results from other flights are included in an accompanying paper. The deduced column for ozone HCl, and NO2 deduced from the spectra, plotted as a function of latitude are shown. It should be noted that there are many other factors varying as well as the latitude, but latitude seems to be the variable which most clearly provides a passage across the vortex boundary. It can be seen that south 76 degrees S., the column of ozone, HCl, and NO2, all decreas markedly, The ratio of HCl to Hf, normally about 5:1 in midlatitudes, approaches unity. Clearly the chemistry of chlorine and nitrogen are disturbed in the region of low ozone. While dynamical theories could perhaps explain a reduction of these three gases in the same region, since all are of stratospheric origin, it is difficult to see how any purely dynamical mechanism could produce the observed HCl:HF ratio, since the two gases have similar origins. A close look at other species to be reported as well as the correlation with other measurements, such as ClO supports the conclusion that the ozone depletion is a result of chemical processes which deplete HCl and NOx relative to the midlatitude situation.

Mankin, William G.↗

Dynamical component of seasonal and year-to-year changes in Antarctic and global ozone

The dynamics of the ozone concetration components of the Antarctic ozone hole as related to seasonal and year-to-year temperature changes in August, September, October, and November during the 1979-1985 period is studied using a zonally averaged model in which all transport fields are fixed by input temperature data. The results suggest that, prior to 1984, both the seasonal and year-to year variability of the zonal-mean Antarctic ozone minimum and the surrounding maximum can be accounted for by temperature dynamics without invoking changes in chemical composition (e.g., chlorine content) or special chemistry. The same dynamical mechanism also accounts for the good simulation of the observed seasonal and latitudinal structure of column ozone in other parts of the world. However, chemical depletion of ozone may have become more important after 1984. The model also appears to underpredict the September ozone decline in years, leading to an underprediction of the recent minimum values in the Antarctic ozone hole.

Tung, Ka Kit↗

Tidal evolution of the Uranian satellites. II - An explanation of the anomalously high orbital inclination of Miranda

It is proposed that the current, anomalously high orbital inclination of the Uranian satellite, Miranda, can be accounted for by temporary capture into the 3:1 resonance with Umbriel. This would imply that the orbits of the satellites have tidally evolved sufficiently to have permitted passage through this resonance. Escape from resonance is suggested to have occurred by way of a novel dynamical mechanism, in which the trajectory encounters low-order commensurabilities between the libration frequency of the resonant argument and other fundamental system frequencies.

Tittemore, William C.↗

Lumped mass formulations for modeling flexible body systems

The efforts of Mechanical Dynamics, Inc. in obtaining a general formulation for flexible bodies in a multibody setting are discussed. The efforts being supported by MDI, both in house and externally are summarized. The feasibility of using lumped mass approaches to modeling flexibility in a multibody dynamics context is examined. The kinematics and kinetics for a simple system consisting of two rigid bodies connected together by an elastic beam are developed in detail. Accuracy, efficiency and ease of use using this approach are some of the issues that are then looked at. The formulation is then generalized to a superelement containing several nodes and connecting several bodies. Superelement kinematics and kinetics equations are developed. The feasibility and effectiveness of the method is illustrated by the use of some examples illustrating phenomena common in the context of spacecraft motions.

Rampalli, Rajiv↗

Thermomechanical properties of polymeric materials and related stresses

The thermomechanical properties of a number of widely used polymeric materials were determined by thermomechanical analysis and dynamic mechanical analysis. A combined profile of the coefficient of thermal expansion and the modulus change over a wide temperature range obtained by the analyses shows clearly the drastic effect of the glass transition on both the CTE and the modulus of a polymer, and the damaging potential due to such effect.

Lee, Sheng Yen↗

Evolution of comets into asteroids

This paper presents observational evidence, together with recent theoretical developments, supporting the hypothesis that at least some asteroids might be extinct or dormant cometary nuclei. The observations include the discovery of a number of apparent asteroids in chaotic Jupiter-crossing orbits; the IRAS discovery of 1983 TB, an asteroid in the same orbit as the Geminid meteor shower; the apparent low activity levels determined for several short-period comet nuclei including Comet Halley; and observations of possible cometary activity in some earth-crossing asteroids. Theoretical developments include explorations of dynamical mechanisms capable of delivering main-belt asteroids into earth-crossing orbits, and an understanding of possible processes which may affect comets during their long residence in the Oort cloud and lead to the formation of nonvolatile crusts before and after they enter the planetary system.

Weissman, Paul R.↗

Life cycles of persistent anomalies. II - The development of persistent negative height anomalies over the North Pacific Ocean

Consideration is given to the potential sources for the development of cases defined by strong and persistent negative height anomalies over the central North Pacific. The analyses of Dole (1986) are extended by providing a more complete synoptic description of the developments and additional diagnostic analysis to identify dynamical mechanisms responsible for the developments. The synoptic characteristics of the developments are reviewed and the barotropic and baroclinic processes of the developments are analyzed. The reproducibility and representativeness of the results are examined. The observed characteristics suggest that the large-scale flow anomalies develop as a result of an instability of three-dimensional wintertime mean flow.

Dole, Randall M.↗

Thermomechanical properties of polymeric materials and related stresses

The thermomechanical analysis (TMA) and dynamic mechanical analysis characterizations of a polymeric material yield useful data relating to the thermomechanical stresses of eight widely used polymeric materials. The materials encompass Lexan, Plexiglass, Epon, Conap, Uralane, Solithane, and Humiseal. A combined profile of the coefficient of thermal expansion (CTE) and the modulus change over a wide temperature range obtained by these analytical methods indicates the drastic effects of glass transition on both the CTE and the modulus of a polymer. TMA can also detect secondary transitions, and provides a convenient means for the study of a polymer's toughness.

Lee, Sheng Yen↗

Evidence for asymmetric inertial instability in the FIRE satellite dataset

One of the main goals of the First ISCCP Regional Experiment (FIRE) is obtaining the basic knowledge to better interpret satellite image of clouds on regional and smaller scales. An analysis of a mesoscale circulation phenomenon as observed in hourly FIRE satellite images is presented. Specifically, the phenomenon of interest appeared on satellite images as a group of propagating cloud wavelets located on the edge of a cirrus canopy on the anticylonic side of a strong, upper-level subtropical jet. These wavelets, which were observed between 1300 and 2200 GMT on 25 February 1987, are seen most distinctly in the GOES-West infrared satellite picture at 1800 GMT. The purpose is to document that these wavelets were a manifestation of asymmetric inertial instability. During their lifetime, the wavelets were located over the North American synoptic sounding network, so that the meteorological conditions surrounding their occurrence could be examined. A particular emphasis of the analysis is on the jet streak in which the wavelets were imbedded. The characteristics of the wavelets are examined using hourly satellite imagery. The hypothesis that inertial instability is the dynamical mechanism responsible for generating the observed cloud wavelets was examined. To further substantiate this contention, the observed characteristics of the wavelets are compared to, and found to be consistent with, a theoretical model of inertia instability by Stevens and Ciesielski.

Stevens, Duane E.↗

The influence of flowing afterglow exposure on the degradation of various polymeric materials

Changes in polymer properties which result after exposure to an atomic oxygen-rich environment of a flowing afterglow are presented. Dynamic mechanical and Fourier Transform Infrared (FTIR) spectra as well as scanning electron microscopy micrographs were employed to monitor variations in mechanical properties and chemical and physical structure. Polymers analyzed include polystyrene, PEKK, and a polyester.

Letton, Alan↗

The relationship between plate velocity and trench viscosity in Newtonian and power-law subduction calculations

The relationship between oceanic trench viscosity and oceanic plate velocity is studied using a Newtonian rheology by varying the viscosity at the trench. The plate velocity is a function of the trench viscosity for fixed Rayleigh number and plate/slab viscosity. Slab velocities for non-Newtonian rheology calculations are significantly different from slab velocities from Newtonian rheology calculations at the same effective Rayleigh number. Both models give reasonable strain rates for the slab when compared with estimates of seismic strain rate. Non-Newtonian rheology eliminates the need for imposed weak zones and provides a self-consistent fluid dynamical mechanism for subduction in numerical convection models.

King, Scott D.↗

Suppression of pressure oscillations in an open cavity by passive pneumatic control

A computational investigation has been conducted to determine the effectiveness of a passive control technique in suppressing the oscillations in an open cavity exposed to a supersonic flow. Time-accurate solutions of the unsteady, Reynolds-averaged, Navier-Stokes equations were obtained with an explicit predictor-corrector algorithm; the passive control was implemented through the use of a simple linear pressure-velocity law along the porous cavity floor. The computational code was validated by comparisons with experimental data for the cavity flow without control. The computational results with control demonstrate that the oscillations are suppressed; the fluid dynamic mechanism of the control is seen to be a stabilization of the free-shear layer. Spectral analysis of the unsteady data shows that the resonant frequencies are essentially unchanged by the control. Beneficial reductions in the cavity resonant drag are also observed.

Chokani, N.↗

Tidal evolution of planetary satellites

Early in the history of the Solar System, Europa and Ganymede may have evolved through a 3:1 mean-motion commensurability, which would have been encountered prior to the establishment of the current Laplace resonance involving Io, Europa, and Ganymede. If Europa and Ganymede passed through the 3:1 mean-motion commensurability, the orbital eccentricities of both satellites may have increased to large values during a phase of chaotic behavior, after which the satellites would have escaped from the resonance. In spite of the relatively large J sub 2 of Jupiter, Europa, and Ganymede are sufficiently massive and distant from the planet that resonances at the 3:1 mean-motion commensurability interact strongly, leading to chaotic behavior via the same kinds of dynamical mechanisms present at resonances among the Uranian satellites. As a result of the large eccentricity increases possible during the evolution of Europa and Ganymede through the 3:1 mean-motion commensurability, tidal heating may have melted water ice in the mantles of both satellites, and stresses on the lithosphere of both satellites due to tidal deformation may have been sufficient to cause extensive fracturing, making resurfacing possible. This may account for the post-heavy bombardment geological activity on both Europa and Ganymede. In addition, the effects of resonance passage on Ganymede may provide an explanation of the Ganymede-Callisto dichotomy by providing Ganymede with an intense source of internal heat and lithospheric stress not present in Callisto. Further possibilities of this evolution are presented.

Tittemore, William C.↗