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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Seismic anisotropy, dominant slip systems and phase transitions in the lowermost mantle

SUMMARY The presence of seismic anisotropy at the base of the Earth's mantle is well established, but there is no consensus on the deformation mechanisms in lower mantle minerals that could explain it. Strong anisotropy in magnesium post-perovskite (pPv) has been invoked, but different studies disagree on the dominant slip systems at play. Here, we aim to further constrain this by implementing the most recent results from atomistic models and high-pressure deformation experiments, coupled with a realistic composition and a 3-D geodynamic model, to compare the resulting deformation-induced anisotropy with seismic observations of the lowermost mantle. We account for forward and reverse phase transitions from bridgmanite (Pv) to pPv. We find that pPv with either dominant (001) or (010) slip can both explain the seismically observed anisotropy in colder regions where downwellings turn to horizontal flow, but only a model with dominant (001) slip matches seismic observations at the root of hotter large-scale upwellings. Allowing for partial melt does not change these conclusions, while it significantly increases the strength of anisotropy and reduces shear and compressional velocities at the base of upwellings.

58 GEOSCIENCES↗
NASA NTRS1990

Mantle-flow tectonics and the origin of Ishtar Terra, Venus

It is proposed that western Ishtar Terra formed due to compression and crustal thickening above a cylindrical mantle downwelling. A model for crustal deformation due to downwelling successfully reproduces many observed characteristics of western Ishtar. Although axisymmetric downwelling occur in numerical models of constant-viscosity mantle convection, there is no evidence for their existence in earth's mantle, where downwellings are sheet-like. Either modes of downflow in Venus and earth are fundamentally different, or differences in near-surface conditions and material behavior selectively emphasize surface expressions of the different downwelling modes.

Bindschadler, D. L.↗
NASA NTRS2010

Experimental Constraints on the Stability of Clinopyroxene (+) Magnesite in Iron Bearing Planetary Mantles: Implications for Nakhlite Formation

Carbon is present in various forms in the Earth s upper mantle (carbonate- or diamond-bearing mantle xenoliths, carbonatite magmas, CO2 emissions from volcanoes...). Moreover, there is enough carbon in chondritic material to stabilize carbonates into the mantles of Mars or Venus as well as in the Earth. However, the interactions with iron have to be constrained, because Fe is commonly thought to buffer oxygen fugacity into planetary mantles. [1] and [2] show evidences of the stability of clinopyroxene Ca(Mg,Fe)Si2O6 + magnesite (Mg,Fe)CO3 in the Earth s mantle around 6GPa (about 180km). The stability of oxidized forms of carbon (like magnesite) depends on the oxygen fugacity of the system. In the Earth s mantle, the maximum carbon content is 10000 ppm [3]. The fO2 parameter varies vertically as a function of pressure, but also laterally because of geodynamic processes like subduction. Thus, carbonates, graphite, diamond, C-rich gases and melts are all stable forms of carbon in the Earth s mantle. [4] show that the fO2 variations observed in SNC meteorites can be explained by polybaric graphite-CO-CO2 equilibria in the Martian mantle. [5] inferred from thermodynamic calculations that the stable form of carbon in the source regions of the Martian basalts should be graphite (and/or diamond). After [6], a metasomatizing agent like a CO2-rich melt may infiltrate the mantle source of nakhlites. However, according to [7] and [8], the FeO wt% value in the Martian bulk mantle is more than twice that of the Earth s mantle (KLB-1 composition by [9]). As iron and carbon are two elements with various oxidation states, Fe/C interaction mechanisms must be considered.

Martin, Audrey M.↗
NASA NTRS2010

Determining the Metal/Silicate Partition Coefficient of Germanium: Implications for Core and Mantle Differentiation.

Currently there are several hypotheses for the thermal state of the early Earth. Some hypothesize a shallow magma ocean, or deep magma ocean, or heterogeneous accretion which requires no magma ocean at all. Previous models are unable to account for Ge depletion in Earth's mantle relative to CI chondrites. In this study, the element Ge is used to observe the way siderophile elements partition into the metallic core. The purpose of this research is to provide new data for Ge and to further test these models for Earth's early stages. The partition coefficients (D(sub Ge) = c(sub metal)/c(sub silicate), where D = partition coefficient of Ge and c = concentration of Ge in the metal and silicate, respectively) of siderophile elements were studied by performing series of high pressure, high temperature experiments. They are also dependent on oxygen fugacity, and metal and silicate composition. Ge is a moderately siderophile element found in both the mantle and core, and has yet to be studied systematically at high temperatures. Moreover, previous work has been limited by the low solubility of Ge in silicate melts (less than 100 ppm and close to detection limits for electron microprobe analysis). Reported here are results from 14 experiments studying the partitioning of Ge between silicate and metallic liquids. The Ge concentrations were then analyzed using Laser Ablation Inductively Coupled Mass Spectrometry (LA-ICP-MS) which is sensitive enough to detect ppm levels of Ge in the silicate melt.

King, C.↗
NASA NTRS2007

Formation of CaS-MgS in Enstatite Chondrites and Achondrites as a Function of Redox Conditions and Temperature: Constraints on Their Evolution in a Planetesimal and in a Proto-planet

The cubic monosulfide series with the general formula (Mg,Mn,Ca,Fe)S are common phases in the enstatite chondrite (EH) and aubrite meteorite groups. In the Earth s mantle, sulfide minerals are associated with peridotites and eclogites. Study of these sulfide mineral systems is of interest for the mineralogy and petrology of planetary mantles. For example, MgS could occur in the primitive Earth and because it remains a low density phase compared to metal, would stay a separate phase during the core formation process, and thus not segregate to the core. (Mg,Ca,Mn,Fe)S sulphides might thus be important phases even in planetary differentiation processes. The importance of such minerals, and their formation, composition and textural relationships for understanding the genesis of enstatite chondrites and aubrites, has long been recognized. The main objective of this experimental study is to understand the formation and evolution of (Mg,Ca,Mn,Fe)S sulphides, particularly the oldhamite CaS and ningerite MgS, with pressure, temperature but also with redox conditions because EH and aubrites are meteorites that formed under reduced conditions. Piston-cylinder (PC) and multi-anvil (MA) experiments at high pressure (HP) and high temperature (HT) have been performed in order to simulate the evolution of these phases in a small planetary body from a planetesimal (with PC experiments) up to a proto-planet (with MA experiments).

Malavergne, Valerie↗
NASA NTRS2018

Core-Mantle Fractionation of Carbon in Earth and Mars: the Effects of Sulfur

Constraining carbon (C) fractionation between silicate magma ocean (MO) and core-forming alloy liquid during early differentiation is essential to understand the origin and early distribution of C between reservoirs such as the crust-atmosphere, mantle, and core of Earth and other terrestrial planets. Yet experimental data at high pressure (P)-temperature (T) on the effect of other light elements such as sulfur (S) in alloy liquid on alloy-silicate partitioning of C and C solubility in Fe-alloy compositions relevant for core formation is lacking. Here we have performed multi-anvil experiments at 6–13 GPa and 1800–2000 °C to examine the effects of S and Ni on the solubility limit of C in Fe-rich alloy liquid as well as partitioning behavior of C between alloy liquid and silicate melt (𝐷𝐷(sub C)(sup alloy/silicate)). The results show that C solubility in the alloy liquid as well as 𝐷𝐷(sub C)(sup alloy/silicate) decreases with increasing in S content in the alloy liquid. Empirical regression on C solubility in alloy liquid using our new experimental data and previous experiments demonstrates that C solubility significantly increases with increasing temperature, whereas unlike in S-poor or S-free alloy compositions, there is no discernible effect of Ni on C solubility in S-rich alloy liquid. Our modelling results confirm previous findings that in order to satisfy the C budget of BSE, the bulk Earth C undergoing alloy-silicate fractionation needs to be as high as those of CI-type carbonaceous chondrite, i.e., not leaving any room for volatility-induced loss of carbon during accretion. For Mars, on the other hand, an average single-stage core formation at relatively oxidized conditions (1.0 log unit below IW buffer) with 10-16 wt.% S in the core could yield a Martian mantle with a C budget similar to that of Earth’s BSE for a bulk C content of ~0.25-0.9 wt.%. For the scenario where C was delivered to the proto-Earth by a S-rich differentiated impactor at a later stage, our model calculations predict that bulk C content in the impactor can be as low as ~0.5 wt.% for an impactor mass that lies between 9-20% of present day Earth’s mass. This value is much higher than 0.05-0.1 wt.% bulk C in the impactor predicted by Li et al. (2016) because C-solubility limit of 0.3 wt.% in a S-rich alloy predicted by their models is significantly lower than the experimentally derived C-solubility of ~1.6 wt. % for the relevant S-content in the core of the impactor.

Carbon↗
NASA NTRS1986

The effects of mantle and anelasticity on nutations, earth tides, and tidal variations in rotation rate

The paper models the effects of mantle anelasticity on luni-solar nutations, on tidal deformation, on tidal variations in rotation rate, and on the eigenfrequency of the free core nutation. The results can be used to invert observations to solve for the anelastic contributions to the shear and bulk moduli of the upper and lower mantle. Specific anelastic models are used to numerically estimate the effects of anelasticity on these geodetic observables. The nutation estimates are compared with observational results. Among the conclusions: (1) mantle anelasticity is likely to be the most important source of damping for the free core nutation; (2) present VLBI nutation results are, in principle, accurate enough to usefully bound anelasticity at diurnal periods. But the discrepancy between the VLBI observed nutations and the 1984 IAU nutation model cannot be explained by anelasticity and is not yet well enough understood to allow anelasticity to be determined from the data.

Wahr, John↗
NASA NTRS2004

Low Abundances of Highly Siderophile Elements in the Lunar Mantle: Evidence for Prolonged Late Accretion

The highly siderophile elements (HSE: including Re, Au, Ir, Os, Ru, Pt, Pd, Rh) are strongly partitioned into metal relative to silicates. In the terrestrial planets these elements are concentrated in metallic cores. Earth s mantle has sufficiently high abundances of the HSE (~0.008 times CI abundances) that it has been hypothesized approximately 0.1-0.5% of the mass of the Earth was added following the last major interaction between the core and mantle [e.g. 1]. The additional material added to the Earth and Moon has been termed a late veneer , and the process has often been termed late accretion [2]. The timing of the dominant late accretionary period of the Earth and Moon is still poorly known. The abundances of HSE in the lunar mantle could provide important constraints on when the late veneer was added. The material that ultimately became the silicate portion of the Moon was likely stripped of most of its HSE prior to and during coalescence of the Moon. Consequently the initial lunar mantle likely had very low concentrations of the HSE. Unlike Earth, the generation of permanent lunar crust by ~4.4 Ga prevented subsequent additions of HSE to the lunar mantle via continued accretion. Thus, if a substantial portion of the late veneer was added after 4.4 Ga, the lunar mantle should have retained very low HSE concentrations. Conversely, if the late veneer was mostly added prior to 4.4 Ga, HSE abundances in the lunar mantle may be roughly similar to abundances in the terrestrial mantle.

Walker, R. J.↗
NASA NTRS1990

Study of the crust and mantle using magnetic surveys by Magsat and other satellites

This article summarizes some of the methodology and results for studies of the earth's mantle and crust. Mantle conductivity studies can be made either by studying signals impressed on the earth from outside, e.g., the ionosphere or magnetosphere, or by studing signals originating in the core and transmitted through the mantle. Crustal field studies begin with a careful selection of the data and subsequent removal of core and external fields by some sort of filtering. Average maps from different local times sometimes differ, presumably due to the remaining presence of fields of external origin. Several techniques for further filtering are discussed. Where large-area aeromagnetic maps are available, crustal maps derived from satellite data can be compared with upward continued data. In general, the comparisons show agreement, with some differences, particularly in and near the auroral belts. The satellite data are further reduced by various methods of inverse and forward modeling, sometimes including reduction to the pole. These techniques are generally unstable at the equator. Common methods of stabilizing the inversions include principle components analysis and ridge regression. Because of the presence of the core field, the entire crustal contribution from the field is not known. Also, there is a basic nonuniqueness to the inverse solutions. Nevertheless, magnetizations that are interpretable can be derived.

Langel, Robert A.↗
NASA NTRS2010

Conditions of Core Formation in the Early Earth: Single Stage or Heterogeneous Accretion?

Since approx.1990 high pressure and temperature (PT) experiments on metal-silicate systems have showed that partition coefficients [D(met/sil)] for siderophile (iron-loving) elements are much different than those measured at low PT conditions [1,2]. The high PT data have been used to argue for a magma ocean during growth of the early Earth [3,4]. In the ensuing decades there have been hundreds of new experiments carried out and published on a wide range of siderophile elements (> 80 experiments published for Ni, Co, Mo, W, P, Mn, V, Cr, Ga, Cu and Pd). At the same time several different models have been advanced to explain the siderophile elements in Earth's mantle: a) shallow depth magma ocean 25-30 GPa [3,5]; b) deep magma ocean; up to 50 GPa [6,7], and c) early reduced and later oxidized magma ocean [8,9]. Some studies have drawn conclusions based on a small subset of siderophile elements, or a set of elements that provides little leverage on the big picture (like slightly siderophile elements), and no single study has attempted to quantitatively explain more than 5 elements at a time. The purpose of this abstract is to identify issues that have lead to a difference in interpretation, and to present updated predictive expressions based on new experimental data. The resulting expressions will be applied to the siderophile element depletions in Earth's upper mantle.

Righter, Kevin↗
DOE OSTI2025

Thermoelastic Properties of Iron-Rich Ringwoodite and the Deep Mantle Aerotherm of Mars

The Martian mantle is considered to have a higher Fe/Mg ratio than the Earth's mantle. Ringwoodite, γ-(Mg,Fe) 2 SiO 4 , is likely the dominant polymorph of olivine in the core-mantle boundary (CMB) region of Mars. We synthesized anhydrous iron-rich ringwoodite with molar Mg/(Mg + Fe) = 0.44 and determined its thermal equation of state up to 35 GPa and 750 K by synchrotron X-ray diffraction. Using a third order Birch-Murnaghan equation of state, we obtain K T0 = 182 (3) GPa, K' = 4.6 (2), and α 0 = 3.18 (6) × 10 -5 K -1 . Using these results and an updated mineralogical model with an iron-rich composition of Mg/(Mg + Fe) = 0.75 for the Martian mantle, we estimate ~1900 K for the temperature of the D1000 seismic discontinuity inside Mars. The resulting adiabat predicts a warm aerotherm, which could explain the presence of partial melt at the CMB of Mars recently detected with seismic data from the 2019 InSight mission.

58 GEOSCIENCES↗
NASA NTRS1985

A model for core formation in the early Earth

Two basic types exogenous models were proposed to account for siderophile and chalcophile element abundances in the Earth's upper mantle. The first model requires that the Earth be depleted in volatiles and that, after a core formation event which extracted the most siderophile elements into the core, additional noble siderophile elements (Pt, Ir, Au) were added as a late veneer and mixed into the mantle. The second model postulates a reduced Earth with approximately CI elemental abundances in which a primary core forming event depleted all siderophile elements in the mantle. The plausibility of models which require fine scale mixing of chondritic material into the upper mantle is analyzed. Mixing in liquids is more efficient, but large degrees of silicate partial melting will facilitate the separation of magma from residual solids. Any external events affecting the upper mantle of the Earth should also be evident in the Moon; but siderophile and chalcophile element abundance patterns inferred for the mantles of the Earth and Moon differ. There appear to be significant physical difficulties associated with chondritic veneer models.

Jones, J. H.↗
NASA NTRS1993

Helium-3 from the mantle - Primordial signal or cosmic dust?

Helium-3 in hotspot magmas has been used as unambiguous evidence for the existence of a primordial, undegassed reservoir deep in the Earth's mantle. However, a large amount of helium-3 is delivered to the Earth's surface by interplanetary dust particles (IDPs). Recycling of deep-sea sediments containing these particles to the mantle, and eventual incorporation in magma, can explain the high helium-3/helium-4 ratios of hotspot magmas. Basalts with high helium-3/helium-4 ratios may represent degassing of helium introduced by ancient (probably 1.5 to 2.0 billion years old) pelagic sediments rather than degassing of primordial lower mantle material brought to the surface in plumes. Influx of IDPs can also explain the neon and siderophile compositions of mantle samples.

Anderson, Don L.↗
NASA NTRS1981

Investigation of geomagnetic field forecasting and fluid dynamics of the core

Progress in the use of MAGSAT data to confirm that the radius of the Earth's core-mantle boundary can be accurately determined magnetically is reported. The MAGSAT data was used in conjunction with a high quality manfield model for epoch 1965. The unsigned flux linking the core and mantle of the Earth is considered to be a legitimate invariant for a span of time. The value from MAGSAT of this constant is 16.056 GWb (gigawebers).

Benton, E. R.↗
NASA NTRS1985

Primordial magmaspheres and their lasting consequences

The lunar magmasphere is a useful but potentially misleading analog for the earliest evolution of other planetary objects. A significant fraction of the lunar magmasphere became a crust rich in buoyant cumulus plagioclase. Another significant fraction became a series of ultramafic cumulates (the mare basalt sources) complementary to the anorthosite. These events predetermined all subsequent lunar evolution. Empirically, the Moon was big enough to produce a magmasphere. Beyond a depth limit of roughly 200 km, nearly independent of the size of the planet, the remainder of the magmasphere will probably at all times be a single convective, and therefore essentially non-differentiating layer. The fraction of the mantle contained in the outer 200 km is of course inversely related to planet size. Compared to the Moon the Earth's mantle comprises a volume of 40 x greater and a pressure range 30 x greater. Steeper dP/dZ, favoring garnets and pyroxenes, also works to dampen differentiation in larger planets. One long term consequence of the Earth's magmasphere was probably a depletion of H2O in much of the mantle. Because water is a flux for mantle convection, anhydrous parts of the mantle probably had anomalously thick lithospheres and hot asthenospheres.

Warren, P. H.↗
NASA NTRS1974

The formation of the moon

Supporting evidence for the fission hypothesis for the origin of the moon is offered. The maximum allowable amount of free iron now present in the moon would not suffice to extract the siderophiles from the lunar silicates with the observed efficiency. Hence extraction must have been done with a larger amount of iron, as in the mantle of the earth, of which the moon was once a part, according to the fission hypothesis. The fission hypothesis gives a good resolution of the tektite paradox. Tektites are chemically much like products of the mantle of the earth; but no physically possible way has been found to explain their production from the earth itself. Perhaps they are a product of late, deep-seated lunar volcanism. If so, the moon must have inside it some material with a strong resemblance to the earth's mantle.

O'Keefe, J. A., III↗
NASA NTRS1984

The size of the lunar core

A 0.2 arc second phase shift in the 18.6 year forced precession of the lunar figure was inferred from analysis of lunar laser ranging data. The source of the phase shift is either viscous friction at a lunar core mantle boundary or solid friction caused by tidal flexing of the Moon by the Earth. Core mantle viscous coupling will explain the signature if the core radius R sub c approximately equals 330 km. On the other hand, solid friction can account for the signature only if the lunar solid friction 0 approximately equals 30 is abnormally small compared with that observed for, say, Mars (approximately equals 100 - 200). Although the inferred core radius is certainly within the limits imposed by the Apollo seismic experiment, it is significantly smaller than estimates of order 400-500 km from electromagnetic sounding. How accurate is the estimate of the R sub c derived from the phase shift? The effect of uncertainties in the frictional coupling mechanism, core density and ellipticity on the inferred core radius are discussed. The excitation of lunar free librations by core turbulence vis-a-vis other mechanisms (e.g., cometary or asteroidal impacts) and the influence of changes in lunar precession in the past on lunar dynamo generation are also examined.

Yoder, C. F.↗