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NASA NTRS1986

Antarctic Meteorite Newsletter, volume 9, no. 2

Preliminary description and classifications of meteorites that were completed since publication of the February issue are contained. Most large (greater than 150 g) specimens (regardless of petrologic type) and all pebble sized (less than 150 g) specimens of special petrologic type are represented by separate descriptions. However, specimens of nonspecial petrologic type are listed only as single line entries. For convenience, new specimens are also recast by petrologic type. Each macroscopic description summarizes features that were visible to the eye at the time the meteorite was first examined. Classification is based on microscopic petrography and resonnaissance-level electron-probe microanalysis. The pairing list was updated.

Gooding, J. L.↗

NASA NTRS1989

The interface in tungsten fiber reinforced niobium metal-matrix composites

The creep resistance of tungsten fiber reinforced niobium metal-matrix composites was evaluated. The interface region between the fiber and matrix was characterized by microhardness and electron probe microanalysis measurements which indicated that its properties were between those of fiber and matrix. However, the measured properties of the composite exceeded those calculated by the rule of mixtures even when the interface zone was assumed to retain all the strength of the fiber. The composite structure appeared to enhance the strengths of both the fibers and the matrix above what they exhibited in stand-alone tests. The effect of fiber orientation and matrix alloy composition on the fiber/matrix interface were also evaluated. Small alloying additions of zirconium and tungsten to the niobium matrix affected the creep resistance of the composites only slightly. A decrease in the creep resistance of the composite with increasing zirconium content in the matrix was ascribed to an increase in the diffusion rate of the fiber/matrix interdiffusion reaction, and a slight increase in the creep resistance of the composite was observed with an addition of 9 w percent tungsten to the matrix. In addition, Kirkendall void formation was observed at the fiber/matrix interface; the void distribution differed depending on the fiber orientation relative to the stress axis.

Grobstein, Toni L.↗

NASA NTRS1988

Petrology and provenance of Apollo 15 drive tube 15007/8

The petrology of submillimeter fractions of soils from 13 levels of Apollo 15 drive tube 15007/8 have been studied through grain size analysis, modal analysis of the 90-150 micron sieve fraction, and electron probe microanalysis of monomineralic fragments of olivine, pyroxene, and plagioclase from the soils. It is shown that core 15007/8 does not contain distinct lithologic units and probably contains soils of mixed maturity in which mixing has greatly dominated in situ reworking. No petrologic layering is found in the core. Abundances of KREEP basalts correlate with mare basalts and not with anorthosite, norite, and troctolite components from the Apennine Front. Some olivine and pyroxene fragments with mare basalt affinity are found to be optically and chemically unzoned, suggesting that they may have been derived from unusual source rocks.

Basu, Abhijit↗

NASA NTRS1989

Analysis of particulates of comet nucleus samples: Possible use of olivine as indicator phase

The electron microprobe is a proven instrument for particulate analysis and modifications are possible for in situ analysis of particulates in ice at temperatures near that of liquid nitrogen. Present sample requirements allow for polished samples with 0.25 x 0.25 dimensions to be maintained in the sample chamber of a modern electron probe (CAMECA SX-50) at a temperature of -150 C; larger samples are possible but at higher temperatures as determined by thermal conductivity. The major problem is transport and insertion of samples into the instrument through vacuum interlocks. The manufacturer of the above microprobe has designed an exchange mechanism to allow storage and transport of samples previously prepared for their sample holder which attaches to their instrument allowing extraction and insertion of samples while maintaining -150 C temperature. An important test will be the capability of preparing polished surfaces of an ice-particulate sample without loss of particles and at low temperatures. While thin sections of water ice are routine, these are not examined for particulate material and are prepared at temperatures easily obtained in room-size volumes. Anticipated problems include rounding of small grains in the relatively soft ice matrix and the technical problem of dry polishing.

Steele, I. M.↗

NASA NTRS1989

Geochemistry of polymict ureilite EET83309, and a partially-disruptive impact model for ureilite origin

Bulk-compositional data for the EET83309 polymict ureilite were obtained using INAA and radiochemistry procedures and electron probe analysis. It was found that the EET83309 has a bulk composition indistinguishable from ordinary ('monomict') ureilites for all elements except light-middle REEs (which are present in much higher concentrations), suggesting that polymict ureilites are mixtures of ordinary ureilites which were mixed on a very small number of parent bodies. Despite the light-REE enrichments, polymict ureilites are nearly devoid of basaltic (Al-rich) material. It is suggested that the missing basalt may have been blown off the parent body by a partially disruptive collision with a large C-rich projectile. This impact model of ureilite origin reconciles many paradoxical aspects of ureilite composition.

Warren, Paul H.↗

NASA NTRS1992

Terrestrial magma ocean and core segregation in the earth

According to the recent theories of formation of the earth, the outer layer of the proto-earth was molten and the terrestrial magma ocean was formed when its radius exceeded 3000 km. Core formation should have started in this magma ocean stage, since segregation of metallic iron occurs effectively by melting of the proto-earth. Therefore, interactions between magma, mantle minerals, and metallic iron in the magma ocean stage controlled the geochemistry of the mantle and core. We have studied the partitioning behaviors of elements into the silicate melt, high pressure minerals, and metallic iron under the deep upper mantle and lower mantle conditions. We employed the multi-anvil apparatus for preparing the equilibrating samples in the ranges from 16 to 27 GPa and 1700-2400 C. Both the electron probe microanalyzer (EPMA) and the Secondary Ion Mass spectrometer (SIMS) were used for analyzing the run products. We obtained the partition coefficients of various trace elements between majorite, Mg-perovskite, and liquid, and magnesiowustite, Mg-perovskite, and metallic iron. The examples of the partition coefficients of some key elements are summarized in figures, together with the previous data. We may be able to assess the origin of the mantle abundances of the elements such as transition metals by using the partitioning data obtained above. The mantle abundances of some transition metals expected by the core-mantle equilibrium under the lower mantle conditions cannot explain the observed abundance of some elements such as Mn and Ge in the mantle. Estimations of the densities of the ultrabasic magma Mg-perovskite at high pressure suggest existence of a density crossover in the deep lower mantle; flotation of Mg-perovskite occurs in the deep magma ocean under the lower mantle conditions. The observed depletion of some transition metals such as V, Cr, Mn, Fe, Co, and Ni in the mantle may be explained by the two stage process, the core-mantle equilibrium under the lower mantle conditions in the first stage, and subsequent downwards separation of the ultrabasic liquid (and magnesiowustite) and flotation of Mg-perovskite in the lower mantle.

Ohtani, Eiji↗

NASA NTRS1992

Surface migration and volume diffusion in the AgGaSe2-Ag2Se system

Surface migration and volume diffusion in the Ag2Se-AgGaSe2 system were investigated using reactive diffusion couples which were analyzed by X-ray diffraction, optical microscopy, and electron probe microanalysis. The surface diffusivities of all mobile species are found to be much larger than volume diffusivities. The results of the study suggest that Se moves together with Ag and Ga to maintain binary (Ag2Se and Ga2Se3) stoichiometry and electroneutrality. The dominance of surface migration kinetics can account for the uniform annihilation of second-phase precipitates during heat treatments.

Kim, N.-H.↗

NASA NTRS1993

The Mn-Fe negative correlation in olivines in ALHA 77257 ureilite

An electron probe microanalyzer is used to measure the Mn, Fe, and oxygen zoning profiles of olivines in the ALHA 77257 ureilite. This is done to study the effects of reduction on the Mn-Fe value, as ureilite olivines exhibit thin reduced rims. Since the Mn content gradually increases toward the rim of ureilite olivines, while the Fa (= 100 x Fe/(Mg + Fe), mol percent) component decreases, the Mn-Fe content of olivine is likely related to redox conditions. The results of melting experiments suggest that the Mn-Fe positive correlation is related to temperature and that the negative correlation of Mn-Fe in olivine and low-Ca pyroxene is related to reduction.

Miyamoto, M.↗

NASA NTRS1993

Microstructural evolution of NARloy-Z at elevated temperatures

Microstructural evolution was studied in samples of wrought and vacuum plasma sprayed (VPS) NARloy-Z exposed to temperatures up to 970 C (1,780 F) for up to 60 h. Samples were heated in a vacuum furnace, followed by rapid quenching in helium (He) gas at a cooling rate of 166 C (300 F) per second. Microstructural analyses were conducted using optical microscopy, scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). In both the wrought and VPS conditions, precipitates rich in silver (Ag) and zirconium (Zr) were present in the matrix and at the grain boundaries even after long exposure to elevated temperatures. Islands rich in oxygen (O2) and Zr were also observed, as well as incipient melting at the grain boundary triple points. Results indicated that the alloy cannot be homogenized by heat treatment at elevated temperatures.

Singh, J.↗

NASA NTRS1993

Diffusion in liquid state and solidification of binary system (M-7)

Diffusion is one of the most fundamental physical phenomena. It relates to the manufacturing of almost all materials. Therefore, the precise knowledge of diffusivities of relevant materials is necessary for the optimization of these processes. On the other hand, such knowledge is indispensable to understanding the diffusion mechanism and structure of liquid metal in the field of physical metallurgy. Many diffusion experiments on solid metal were undertaken and a lot of data were accumulated. But on liquid metals there are few measurements because of experimental difficulties, such as thermal convection, induced by very slight temperature gradients in the specimen. Under microgravity conditions, the movement of liquid metal due to density differences and thermal convection must be suppressed markedly. Therefore, the transportation process will be controlled only by the diffusion of constituent atoms. These conditions offer the optimum environments for the diffusion experiment. The experiments are briefly described. Diffusion couples are prepared by attaching end to end two rods of different pure metals using hot press equipment. These couples are inserted into a graphite crucible and then doubly enclosed by two silica ampoules, respectively. The specimen is inserted into a tantalum cartridge, which is welded in a vacuum using an electron-beam apparatus. These cartridges are charged in the continuous heating furnace in space and held at a given temperature for a predetermined time and then solidified. The concentration distribution of elements in these specimens will be measured along the rod axis by means of an electron probe microanalyzer. The counterdiffusivity of the liquid metal binary system is determined on the basis of the compensated concentration distribution profile for thermal contraction.

Dan, T.↗

NASA NTRS1993

Experimentally reproduced relict enstatite in porphyritic chondrules of enstatite chondrite composition

Experiments are presented that test a model for the origin of porphyritic pyroxene (PP) chondrules in enstatite chondrites that contain phenocrysts of enstatite with blue cathodoluminescence (CL) set in a matrix of radial, dendritic enstatite with red CL. Established one-atmosphere, gas-mixing techniques were used. Relict enstatite phenocrysts with blue CL in a matrix of coarsely radial to dendritic enstatite with red CL were successfully produced. The relict crystals are preserved in runs with a melt time of 36 minutes or less at 1537 C. The relicts remain angular with smooth crystal/melt interfaces, and thus melting has occurred uniformly. Partial melting does occur along fractures produced when the blue CL enstatite was initially grown and cooled through the proto/ortho enstatite transition with the attendent volume change. There is either reaction with the melt and diffusion of Mn and Cr into the blue CL En, or there is an overgrowth of red CL En along the fractures. The bulk of the relicts remain blue. The melt enclosing the relicts crystalized to a coarsely radial to dendritic to micro porphyritic texture comprised of enstatite that has a bright red CL with decreasing melt time. The blue CL En has Mn and Cr contents at or below detection limits of the electron probe as described in earlier studies and in natural blue CL En. In the red CL En in this study, the Mn, Al2O3, and Cr are at previously observed levels and the levels change rapidly.

Lofgren, Gary E.↗

NASA NTRS1993

Preliminary AEM study of the microstructure and composition of metal particles in ordinary chondrites

The purpose of this study is to examine the microstructure and composition of the metal particles in ordinary chondrites using analytical electron microscopy (AEM) techniques. Since the phases produced within the metal particles are very fine, the application of various AEM techniques for structural and chemical characterization is critical. However, thin specimen preparation for AEM study has proven very difficult because of the matrix silicate which is present. This is the first AEM study of the metal particles in chondrites. A type 6 chondrite, Saint Severin (LL6), was selected for examination because the metal phases have been reheated into the single phase taenite region (greater than 700 C), and cooled slowly to lower temperatures. A combination of electron optical instruments was employed including a field emission gun (FEG) JEOL 840F high resolution scanning electron microscope (HRSEM), a JEOL 6300F FEG-HRSEM, a Philips 400T AEM, and a JEOL 733 electron probe microanalyzer (EPMA).

Yang, C. W.↗

NASA NTRS1994

Phase E in a water-saturated peridotite system at 9.3 GPa

The stability of hydrous phases in a natural upper mantle system has been investigated at 9.3 GPa using a gel of KLB-1 peridotite composition with brucite which contains 14 wt. percent (30 atom. percent) water. No hydrous mineral was found at 950 (+150 -50) degree C. At 800 degree C, an assemblage of phase A, phase E, enstatite, clinohumite, and garnet is obtained. Although there is a significant thermal gradient over the sample, phase E is found to be surrounded by phase A in the lower temperature part. Electron probe analyses show that phase E has 35.5 SiO2, 4.4 Al2O3, 41.1 MgO and 8.5 wt. percent FeO* (Mg value is 90) with an oxide sum of 89.7 wt. percent, and possesses a stoichiometry similar to that proposed by Kanzaki. CaO and TiO2 are both less than 0.1 wt. percent. Coexisting phase A has 0.5 wt. percent CaO but only 0.4 wt. percent Al2O3 concentration. Phase A coexists with only enstatite in the water-saturated MgO-FeO-SiO2 system at 800 degree C and 9.3 GPa as well as the results in the water-saturated MgO-SiO2 system. Therefore it is suggested that the addition of Al2O3 expands the stability field of phase E to lower than 13 - 17 GPa in the water-saturated MgO-SiO2 system.

Kawamoto, Tatsuhiko↗

NASA NTRS1993

Observations of the nightside Venus ionosphere: Final encounter of the Pioneer Venus Orbiter Ion Mass Spectrometer

During the last orbital sequences of the Pioneer-Venus spacecraft prior to final encounter and atmospheric entry, data were obtained by the Orbiter Ion Mass Spectrometer (OIMS) at the lowest periapsis altitudes of the mission. These data verified OIMS observations of the nightside ionospheric peak reported earlier in the mission, and revealed additional details related to composition, energetics and maintenance of the nightside ionosphere. OIMS observations of the ion peak during the final encounter sequence are compared with radio occultation data and OIMS peak observations obtained earlier. OIMS ion density and Orbiter Electron Temperature Probe (OETP) electron density are found to correlate near the peak. Coupling of mass channels 30 and 32 during nightside passes is observed and its interpretation considered. Changes in high altitude composition of the nightside ionosphere, especially the relative changes in O(+) and H(+), are described.

Cloutier, P. A.↗

NASA NTRS1994

The Pasamonte unequilibrated eucrite: Pyroxene REE systematic and major-, minor-, and trace-element zoning

We are evaluating the trace-element concentrations in the pyroxenes of Pasamonte. Pasamonte is a characteristic member of the main group eucrites, and has recently been redescribed as a polymict eucrite. Our Pasamonte sample contained eucritic clasts with textures ranging from subophitic to moderately coarse-grained. This study concentrates on pyroxenes from an unequilibrated, coarse-grained eucrite clast. Major-, minor-, and trace-element analyses were measured for zoned pyroxenes in the eucritic clast of Pasamonte. The major- and minor-element zoning traverses were measured using the JEOL 733 electron probe with an Oxford-Link imaging/analysis system. Complemenatry trace elements were then measured for the core and rim of each of the grains by SIMS. The trace elements analyzed consisted of eight REE, Sr, Y, and Zr. These analyses were performed on a Cameca 4f ion probe. The results of the CI chondrite normalized (average CI trace-element analyses for several grains and the major- and minor-element zoning patterns from a single pyroxene grain are given. The Eu abundance in the cores of the pyroxenes represents the detection limit and therefore the (-Eu) anomaly is a minimum. Major- and minor-element patterns are typical for igneous zoning. Pyroxene cores are Mg enriched, whereas the rims are enriched in Fe and Ca. Also, Ti and Mn are found to increase, while Cr and Al generally decrease in core-to-rim traverses. The cores of the pyroxenes are more depleted in the Rare Earth Elements (REE) than the rims. Using the minor- and trace-element concentrations of bulk Pasamonte and the minor- and trace-element concentrations from the cores of the pyroxenes in Pasamonte measured in this study, we calculated partition coefficients between pyroxene and melt. This calculation assumes that bulk Pasamonte is representative of a melt composition.

Pun, A.↗

NASA NTRS1994

Measuring glass abundances in lunar agglutinates

The purpose of this study is to develop a standard method for measuring modal abundances of glass in single agglutinates in the lunar regolith. Not only does agglutinitic glass increase in single agglutinates as clasts of older agglutinates get incorporated into newer agglutinates with increasing maturity, but it is in this glassy phase that nanophase superparamagnetic Fe metal originates as a result of reduction reactions during the agglutination process. We report the results of two sets of independent measurements using two different methods to determine the proportion of glass in single agglutinates. We have used polished grain mounts (PGM) of five hand-picked single agglutinates from Apollo 16 soil 61181. The ISI Scanning Electron Microscope (SEM) fitted with a high-resolution Backscattered Electron (BSE) detector was used to collect high-contrast BSE images of the agglutinates. Several images were collected to represent each single agglutinate. The contrast, brightness, and focus were adjusted to optimize each image collected. Histograms of the grayscale range for all images produced four 'peaks' corresponding to epoxy, glass, crystalline phases, and metal grains. We analyzed every grid point for 12 elements with a less than 1 micron electron beam using a CAMECA SX-50 electron probe microanalyzer (EPM). If any analysis was not within about 10% of the stoichiometry of a known lunar mineral, we considered that point to be nonmineralic. Our results show that there is a remarkable correspondence in the glass percentages obtained by the two methods. The EPM method may overestimate glass because secondary fluorescence from dusty clasts in agglutinitic glass can give the appearance of nonmineralic targets. The BSE method may underestimate glass because the diversity of compositions of agglutinitic glass may not be contained under one grayscale 'peak' during image analysis.

Strait, M. M.↗

NASA NTRS1993

Observations of the Nightside Venus Ionosphere: Final Encounter of the Pioneer Venus Orbiter Ion Mass Spectrometer

During the last orbital sequences of the Pioneer Venus spacecraft prior to final encounter and atmospheric entry, data were obtained by the Orbiter Ion Mass Spectrometer (OIMS) at the lowest periapsis altitudes of the mission. These data verified OIMS observations of the nightside ionospheric peak reported-earlier in the mission, and revealed additional details related to composition, energetics and maintenance of the nightside ionosphere. OIMS observations of the ion peak during the final encounter sequence are compared with radio occultation data and OIMS peak observations obtained earlier. OIMS ion density and Orbiter Electron Temperature Probe (OETP) electron density are found to correlate near the peak. Coupling of mass channels 30 and 32 during nightside passes is observed and its interpretation considered. Changes in high altitude composition of the nightside ionosphere, especially the relative changes in O(+) and H(+), are described.

Cloutier, P. A.↗

NASA NTRS1996

Preparation and Thermoelectric Properties of the Skutterudite-Related Phase Ru(0.5)Pd(0.5)Sb3

A new skutterudite phase Ru(0.5)Pd(0.5)Sb3 was prepared. This new phase adds to a large number of already known materials with the skutterudite structure which have shown good potential for thermoelectric applications. Single phase, polycrystalline samples were prepared and characterized by x-ray analysis, electron probe microanalysis, density, sound velocity, thermal-expansion coefficient, and differential thermal analysis measurements. Ru(0.5)Pd(0.5)Sb3 has a cubic lattice, space group Im3 (T(sup 5, sub h)), with a = 9.298 A and decomposes at about 920 K. The Seebeck coefficient, the electrical resistivity, the Hall effect, and the thermal conductivity were measured on hot-pressed samples over a wide range of temperatures. Preliminary results show that Ru(0.5)Pd(0.5)Sb3 behaves as a heavily doped semiconductor with an estimated band gap of about 0.6 eV. The lattice thermal conductivity of Ru(0.5)Pd(0.5)Sb3 is substantially lower than that of the binary isostructural compounds CoSb3 and IrSb3. The unusually low thermal conductivity might be explained by additional hole and charge transfer phonon scattering in this material. The potential of this material for thermoelectric applications is discussed.

Caillat, T.↗