SEARCH · Search NASA

Results for “GEO”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 181 records · Page 10

All sources NASA NTRS DOE OSTI

NASA NTRS2020

Assimilating All-Sky Microwave Radiance Data to Improve NASA GEOS Forecasts and Analysis

The NASA Global Modeling and Assimilation Office (GMAO) has been pursuing efforts to utilize all-sky (clear+cloudy+precipitating) MW radiance data and has developed a system to assimilate all-sky GPM Microwave Imager (GMI) radiance data in the Goddard Earth Observing System (GEOS) during the last PMM funding period. The system provides additional constraints on the analysis process near the storm regions and adjusts the geophysical parameters such as precipitation, cloud, moisture, surface pressure, and wind by combining information from GMI radiance measurements and model forecasts in an optimal manner. The system proved that assimilating the GMI all-sky radiance data improve the GEOS atmospheric analyses and forecasts. This all-sky data framework has been included in the GEOS Forward Processing (FP) system since July 11, 2018 and assimilates all-sky GMI data in real-time for GEOS global analysis and forecast production at the GMAO. We are currently extending this all-sky GMI radiance data assimilation system to assimilate more all-sky MW radiance data from other sensors such as the Microwave Humidity Sounder (MHS), the Advanced Technology Microwave Sounder (ATMS), the Special Sensor Microwave Imager/Sounder (SSMIS), Advanced Microwave Scanning Radiometer 2 (AMSR2), and the Sounder for Atmospheric Profiling of Humidity in the Intertropics by Radiometery (SAPHIR) onboard the GPM constellation spacecrafts. Preliminary results from this extended all-sky system show increased benefit from cloud- and precipitation-affected MW radiances with much larger spatial and temporal coverages compared to the all-sky system assimilating GMI alone and improved GEOS forecast skills especially for lower tropospheric humidity fields.

Kim, Min-Jeong↗

NASA NTRSDate not supplied

Joint Assimilation of Surface, GEO, and LEO CO, NO2, and O3 In Situ and Partial Column/Profile Retrievals with WRF-Chem/DART

Low earth orbiting (LEO) satellites like OMI or TROPOMI and geostationary satellites like TEMPO (to be launched January 2023) provide ozone (O3) retrieval profiles that extend into the stratosphere. Regional models like WRF-Chem generally do not include the stratosphere and have vertical grids that end near the tropopause. This causes difficulties when assimilating O3 retrievals (both column and profile retrievals) because the respective observation forward operators require model O3 profiles that extend into the stratosphere. In this presentation, we look at results from assimilating O3 observation from surface (in situ measurements), multiple LEO (profile retrievals), and GEO (proxy profile retrievals) platforms in as regional model where we use a global chemical transport model (GCTM) to provide O3 upper boundary conditions (BCs) to enable application of the O3 observation forward operators. We will also present results from assimilating O3 retrievals together with carbon monoxide (CO) observations from surface (in situ measurements) and multiple LEO platforms (column and profile retrievals), and nitrogen dioxide (NO2) observations from surface (in situ measurements), multiple LEO (column retrievals), and GEO (proxy column retrievals) platforms. Our joint assimilation experiments show that sometimes the observations complement each, e.g., when assimilating surface and satellite CO or NO2 observations, and sometimes the observations conflict with each other, e.g., when assimilating observations that are biased with respect to other observations (e.g., CO retrievals), or when the assimilation increments conflict due to their chemical interaction (e.g., surface O3 and NO2 retrievals). Results from assimilation of O3 retrieval profiles in regional model are preliminary and will also be discussed in our presentation. Our expectation is that using GCTM O3 as upper BCs in the regional model for evaluation of the O3 forward operator will improve our O3 forecasts. In summary, we will present results from jointly assimilating surface, LEO, and GEO CO, NO2, and O3 in situ and satellite observations in a regional model with dynamic emissions estimation. This study uses proxy GEO observations as a prelude to actual observations because the GEO platform will not be launched until after our presentation.

WRF-Chem/DART↗

NASA NTRSDate not supplied

Near Real Time Air Quality Forecasts Using the NASA GEOS Model

This presentation provides an overview of NASA's Global Modeling and Assimilation Office (GMAO) high-resolution global forecast and reanalysis products for weather, aerosols, and air quality. The NASA Global Earth Observing System (GEOS) model radiatively coupled to GOCART aerosol module assimilates 2-dimensional column-integrated aerosol optical depth (AOD) at one wavelength (550 nm) in order to constrain the model's background AOD in order to have the best historical estimate and forecasts of AOD and particulate matter. Furthermore, the GEOS model has been expanded to provide global near-real-time 5-day forecasts of atmospheric composition at unprecedented horizontal resolution of 0.25 degrees (~25 km). This composition forecast system (GEOS-CF) combines the operational GEOS weather forecasting model with the state-of-the-science GEOS-Chem chemistry module (version 12) to provide detailed analysis of a wide range of air pollutants such as ozone, carbon monoxide, nitrogen oxides, and fine particulate matter (PM2.5).

K Emma Knowland↗

NASA NTRSDate not supplied

Near Real Time Air Quality Forecasts Using the NASA GEOS Model

K Emma Knowland↗

NASA NTRSDate not supplied

Understanding and Utilizing PBL Height Data from Multiple Observing Systems in the GEOS System

The accuracy of PBL height simulation is a key issue in many applications including forecasting near surface meteorology and air quality, however, it is a very challenging problem due to the lack of not only comprehensive, global Planetary Boundary Layer (PBL) observations but also a strategy and infrastructure to utilize PBL height data from a variety of sensors. Following the designation of PBL as an incubation class observable in the 2017 Decadal Survey, the PBL Incubation Study Team Report [14] made clear that “a future global PBL observing system requires modeling and data assimilation as essential components.” There is an urgent need for global modeling development in order to utilize Program of Record (POR) observations, assess their impacts, and identify gaps to be filled by future PBL missions. Our overall objective is to develop PBL data assimilation capabilities in the NASA Global Earth Observing System (GEOS), focusing on PBL height from multiple observing systems, to support the assessment and use of future PBL observations. The NASA GEOS system is composed of the GEOS global atmospheric general circulation model (AGCM) and the atmospheric data assimilation system (ADAS). The PBL parameterizations include the “Lock” K-profile scheme driven by surface and cloud-top buoyancy fluxes ([4]), and the “Louis” local scheme for stable conditions based on the Richardson number ([5]). Above the mixed layer defined by the Lock surface plume, shallow cumulus convection is represented by the mass flux scheme of [9]. Additional parameterizations are summarized in [1]. The ADAS employs the hybrid 4D Ensemble- Variational (EnVar) configuration ([15]), with the ensemble providing flow-dependent background error covariance information. The resultant analysis increments are fed back to the forecast model through the 4D incremental analysis update (IAU) approach ([11]). In this study, PBL height data are being or have been generated from radiosondes, GNSS RO, satellite (CATS, CALIPSO and ICESat-2) and ground-based (MPLNET) lidars, and wind profiler. Investigations have been conducted to specify quality marks for PBL height retrievals for the data assimilation purpose. These PBL height data have different strengths and weaknesses ([2], [3], [6], [7], [8], [10]), and the satellite PBL height data provide better global coverage and complement in-situ PBL height data. Radiosondes offer high accuracy and in situ measurement of temperature and humidity profiles, but with poor spatio-temporal sampling. The in-situ observing systems like MPLNET and wind profiler provide long history of PBL height records at each station. The GNSS RO based PBL height is retrieved based on the sharp gradients in refractivity profile that represent the fine vertical structure of temperature and moisture changes above the PBL. However, not all RO refractivity profiles reach the surface depending on location and regime, and RO refractivity retrievals can be negatively biased below 2km. The PBL height data from satellite lidars provide high resolution along track PBL height retrievals, but over land they are affected by previous day convective PBL aerosol and strongly associated with mixing layer and retrievals cannot be made below thick, attenuating clouds. A successful assimilation of PBL height data requires a thorough understanding of the observing method and the retrieval algorithm for each observing system in order to use the PBL height data from multiple observing systems properly. Due to the sensitivity of PBL height data to the observing method and choice of algorithm, it is important to use a model definition appropriate for each observation type to compute differences between PBL height data and model PBL height (OmFs). The GEOS model currently includes two PBL height definitions suitable for direct comparison with observed PBL height, and additional definitions are being added in this study. Evaluation of different model PBL height definitions is underway. Meanwhile, efforts have been made in the GEOS data assimilation system to develop PBL height data assimilation capability. PBL height data can be assimilated using two different approaches. The traditional approach is to construct an observation operator and its tangent linear and adjoint, which link control variables to PBL height data from each observing system. This observation operator can be very complicated, e.g., the lidar-based PBL height observation operator includes the backscatter lidar forward observation operator, the algorithm to derive PBL height from attenuated total backscatter, interpolation, and calculations handling the mismatch between observed and model scales. The other approach is to augment PBL height to the control variable vector, and it is adopted in this study. The latter approach was also used in previous studies, e.g., the assimilation of PBL height data from radiosonde and aircraft in the Real Time Mesoscale Analysis (RTMA) system for a dispersion modelling study ([13]); the PBL height assimilation study using lidar PBL height data at Greensburg, Kansas for a field campaign ([12]). The PBL height assimilation from multiple observing systems in this study allows us to take advantage of the diverse PBL height data that provide much better global coverage collectively under different meteorological conditions and with different temporal and spatial scales. As all the PBL heights are tightly coupled with the PBL thermodynamic variables, the strong correlations, which are provided by the 4D ensemble forecast, enable PBL height data from various sources to interact and combine coherently and provide additional information for PBL temperature and moisture fields. The results of comparisons among PBL height data from different sources and the evaluation of the model PBL height definitions with the PBL height data will be presented, and the PBL height data synergy strategies and preliminary results will also be discussed at the conference.

Y. Zhu↗

NASA NTRSDate not supplied

Tropospheric Ozone in the NASA GEOS Model: Effects of Satellite NO2 Data Assimilation and Improvements in Background NOx Chemistry

Tropospheric ozone is a major atmospheric oxidant, the primary source of the hydroxyl radical, and a greenhouse gas. In the troposphere, it is produced from the oxidation of carbon monoxide and volatile organic compounds in the presence of nitrogen oxides (NOx=NO+NO2) or has its origins in the stratosphere. The tropospheric ozone burdens in global atmospheric chemistry models disagree by a factor of 1.5, indicating an incomplete understanding of ozone sources and sinks. Here we examine the tropospheric ozone simulation in NASA Global Modeling and Assimilation Office’s (GMAO’s) GEOS model with the GEOS-Chem chemistry mechanism (version 14.2), using observations from satellites, aircraft, ozonesondes, and surface sites. This modeling framework is used to produce GMAO’s GEOS Composition Forecasts (GEOS-CF), and it has been updated extensively with new emission inventories, improved model physics, satellite data assimilation capability, and an up-to-date chemical mechanism that includes tropospheric halogen chemistry and NOx recycling from particulate nitrate. Earlier versions of the model using GEOS-Chem version 12.0 showed an underestimate in tropospheric ozone in the northern hemisphere. We evaluate the ozone simulation in the updated model, focusing on the effects of assimilating satellite NO2 data from the Ozone Monitoring Instrument (OMI), constraining stratospheric ozone to satellite data, and updates to the NOx chemistry. We will examine changes in the vertical profiles of tropospheric ozone over the US in support of the Tropospheric Emissions: Monitoring of Pollution (TEMPO), and discuss implications for the tropospheric ozone budget.

V. Shah↗

NASA NTRSDate not supplied

A11I-2104 Evaluation of the NASA GEOS Chemistry-Climate Model Coupled Atmosphere-Ocean Configuration for its Suitability to Simulations of Atmospheric Composition in a Changing Climate

The NASA Goddard Earth Observing System Chemistry-Climate Model (GEOSCCM) is a full tropospheric-stratospheric chemistry enabled configuration of the NASA GEOS Earth system model. Among the objectives for research performed with GEOSCCM is to understand the impacts of climate change on recovery of the stratospheric ozone layer over the twenty-first century. Simulations performed in the past with GEOSCCM did not have an interactive ocean and were driven with projected sea surface temperature and sea ice boundary conditions provided by external models. This method limits the application of GEOSCCM for climate study because it doesn’t allow the feedback of composition changes to ocean. For a full representation of the chemistry-climate feedbacks in the Earth System, we have developed a configuration of GEOSCCM that makes use of the MOM5 ocean general circulation model coupled to the GEOS atmospheric general circulation model. This configuration leverages development of the GEOS Sub-seasonal-to-Seasonal (S2S) prediction system, and includes interactive, radiatively coupled aerosols and two-moment, aerosol-aware cloud microphysics. W e have assessed the baseline model climate sensitivity with an Monday, 11 December 2023 08:30 - 12:50 Poster Hall A-C - South (Exhibition Level, South, MC) experiment performed under pre-industrial (e.g., year 1850) greenhouse gas conditions and a second experiment under 4xCO2 conditions, similar to the typical CMIP protocol. The GEOS model is demonstrated to have a climate sensitivity of a 2.6 K increase in global mean surface temperature for an equivalent doubling of CO2 from pre-industrial conditions, in line with current CMIP models. This configuration of the GEOS model is suitable for application to multidecadal to century-long simulations of climate system response to changing greenhouse gas levels. We report here our evaluation of the climate diagnostics of this configuration and discuss future directions for work with this model configuration, including an ongoing twenty-first century projection experiment based on the Chemistry-Climate Model Intercomparison project protocol.

models↗

NASA NTRSDate not supplied

Tropospheric Ozone in the NASA GEOS Model: Effects of Satellite Data Assimilation and Improvements in Background NO x Chemistry

Tropospheric ozone is a major atmospheric oxidant, the primary source of the hydroxyl radical, and a greenhouse gas. In the troposphere, it is produced from the oxidation of carbon monoxide and volatile organic compounds in the presence of nitrogen oxides (NO x =NO+NO 2 ) or has its origins in the stratosphere. The tropospheric ozone burdens in global atmospheric chemistry models disagree by a factor of 1.5, indicating an incomplete understanding of ozone sources and sinks. Here we examine the tropospheric ozone simulation in NASA Global Modeling and Assimilation Office’s (GMAO’s) GEOS model with the GEOS-Chem chemistry mechanism (version 14.2), using observations from satellites, aircraft, ozonesondes, and surface sites. This modeling framework is used to produce GMAO’s GEOS Composition Forecasts (GEOS-CF), and it has been updated extensively with new emission inventories, improved model physics, satellite data assimilation capability, and an up-to-date chemical mechanism that includes tropospheric halogen chemistry and NOx recycling from particulate nitrate. Earlier versions of the model using GEOS-Chem version 12.0 showed an underestimate in tropospheric ozone in the northern hemisphere. We evaluate the ozone simulation in the updated model, focusing on the effects of assimilating satellite NO 2 data from the Ozone Monitoring Instrument (OMI), constraining stratospheric ozone to satellite data, and updates to the NOx chemistry. We will examine changes in the vertical profiles of tropospheric ozone over the US in support of the Tropospheric Emissions: Monitoring of Pollution (TEMPO), and discuss implications for the tropospheric ozone budget.

Viral Shah↗

NASA NTRSDate not supplied

The Transition of Satellite Observations Assimilated in GEOS to JEDI

The Goddard Earth Observing System (GEOS) is used by NASA’s Global Modeling and Assimilation Office (GMAO) to produce weather, climate, and air quality forecasts and reanalysis datasets. In order to incorporate the Joint Effort for Data assimilation Integration (JEDI) system into GEOS it is necessary to provide a validated set of input observations in JEDI. The GMAO, in collaboration with the Joint Center for Satellite Data Assimilation (JCSDA), is developing the Unified Forward Operator (UFO) in JEDI and adding all the necessary features to replicate the existing capability of the Gridpoint Statistical Interpolation (GSI)–based GEOS atmospheric data assimilations system. GMAO has been adding, validating, and updating procedures to assimilate the vast array of satellite and conventional observations assimilated in GEOS, including the GEOS all-sky microwave radiance assimilation framework to assimilate those observations in the UFO. Robust tests have been conducted to ensure correct configurations of observational data bias correction, quality control, and observation error in UFO and good agreements between UFO and GSI results. Our work on satellite observations will be reported in this presentation.

Jianjun Jin↗

NASA NTRSDate not supplied

Satellite Data Assimilation in the GEOS Atmospheric Data Assimilation System

The Goddard Earth Observing System (GEOS) is used for weather, climate, and air quality forecasts and producing reanalysis datasets. Its atmospheric data assimilation system (ADAS) is a hybrid–4DEnVar system. Various satellite radiance, atmospheric motion vector (winds), aircraft, and convectional data are assimilated by this system to produce global atmospheric states. The GEOS ADAS is enhanced by considering correlated observational errors among infrared radiance observations and assimilating new microwave radiance data in all-sky conditions. Historical microwave radiance data are tested within the all-sky microwave radiance assimilation framework and show beneficial effect in the preparation of the next GEOS reanalysis product. In this seminar, I will present the procedures of to assimilate microwave radiance data in all-sky conditions in the GEOS-ADAS. I will also discuss our efforts to update GEOS ADAS by assimilating more satellite data such as geostationary infrared observations and new observations made by the Advanced Technology Microwave Sounder (ATMS) aboard NOAA 21 polar orbit satellite.

Jianjun Jin↗

NASA NTRS2024

Tropical Cyclones in the GEOS-S2S-2 Subseasonal Forecasts

This paper analyzes the climatology, prediction skill, and predictability of tropical cyclones (TCs) in NASA’s Global Earth Observing System Subseasonal to Seasonal (GEOS-S2S) forecast system version 2. GEOS reasonably simulates the number and spatial distribution of TCs compared to observations except in the Atlantic where the model simulates too few TCs due to low genesis rates in the Caribbean Sea and Gulf of Mexico. The environmental conditions, diagnosed through a genesis potential index, do not clearly explain model biases in the genesis rates, especially in the Atlantic. At the storm-scale, GEOS reforecasts replicate several key aspects of the thermodynamic and dynamic structure of observed TCs, such as a warm core and the secondary circulation. The model, however, fails to simulate an off-center eyewall when evaluating vertical velocity, precipitation and moisture. The analysis of prediction skill of TC genesis and occurrence shows that GEOS has comparable skill to other global models in WMO S2S archive and that its skill could be further improved by increasing the ensemble size. After calibration, GEOS forecasts are skillful in the Western North Pacific and Southern Indian Ocean up to 20 days in advance. A model-based predictability analysis demonstrates the importance of the Madden-Julian Oscillation (MJO) as a source of predictability of TC occurrence beyond the 14 day lead-time. Forecasts initialized under strong MJO conditions show evidence of predictability beyond week 3. However, due to model biases in the forecast distribution there are notable gaps between MJO-related prediction skill and predictability which require further study.

Jorge L. Garcia-Franco↗

NASA NTRS2014

The GOddard SnoW Impurity Module (GOSWIM) for the NASA GEOS-5 Earth System Model: Preliminary Comparisons with Observations in Sapporo, Japan

The snow darkening module evaluating dust, black carbon, and organic carbon depositions on mass and albedo has been developed for the NASA Goddard Earth Observing System, Version 5 (GEOS-5) Earth System Model, as the GOddard SnoW Impurity Module (GOSWIM). GOSWIM consists of the snow albedo scheme from a previous study (Yasunari et al. 2011) with updates and a newly developed mass concentration scheme, using aerosol depositions from the chemical transport model (GOCART) in GEOS-5. Compared to observations at Sapporo, the numerical experiments, forced by observation-based meteorology and aerosol depositions from GOES-5, better simulated the seasonal migration of snow depth, albedos, and impurities of dust, BC, and OC in the snow surface. However, the magnitude of the impurities is underestimated, compared to the sporadic snow impurity measurements. Increasing the deposition rates of dust and BC could explain the differences on the snow darkening effect between observation and simulation. Ignoring BC deposition can possibly lead to an extension of snow cover duration in Sapporo for four days. Comparing the off-line GOSWIM and the GEOS-5 global simulations, we found that determining better local precipitation and deposition rates of the aerosols are key factors in generating better GOSWIM snow darkening simulation in NASA GEOS-5.

land surface processes↗

NASA NTRS2017

GEOS-5 Seasonal Forecast System

Ensembles of numerical forecasts based on perturbed initial conditions have long been used to improve estimates of both weather and climate forecasts. The Goddard Earth Observing System (GEOS) Atmosphere-Ocean General Circulation Model, Version 5 (GEOS-5 AOGCM) Seasonal-to-Interannual Forecast System has been used routinely by the GMAO since 2008, the current version since 2012. A coupled reanalysis starting in 1980 provides the initial conditions for the 9 month experimental forecasts. Once a month, sea surface temperature from a suite of 11 ensemble forecasts is contributed to the North American Multi-Model Ensemble (NMME) consensus project, which compares and distributes seasonal forecasts of ENSO events. Since June 2013, GEOS-5 forecasts of the Arctic sea-ice distribution were provided to the Sea-Ice Outlook project. The seasonal forecast output data includes surface fields, atmospheric and ocean fields, as well as sea ice thickness and area, and soil moisture variables. The current paper aims to document the characteristics of the GEOS-5 seasonal forecast system and to highlight forecast biases and skills of selected variables (sea surface temperature, air temperature at 2 m, precipitation and sea ice extent) to be used as a benchmark for the future GMAO seasonal forecast systems and to facilitate comparison with other global seasonal forecast systems.

GEOS-5↗

NASA NTRSDate not supplied

Investigating seasonal ENSO forecast amplitude calibration for GEOS-S2S-2

The GEOS-S2S-2 is a global coupled model and assimilation system, encompassing many aspects of the Earth climate system. This project looked at seasonal (nine-month) ensemble forecasts, over the period from 1982 through the present. We explored and validated a forecast amplitude correction technique used by the North American Multi-Model Ensemble (NMME), of which GEOS is a member, for Niño3.4 sea-surface temperature (SST) anomaly predictions. The method relies on deriving a set of correction factors based on the standard deviations of hindcast and observed SST anomalies. This algorithm was implemented at the Global Modeling and Assimilation Office (GMAO) and applied to the GEOS-S2S-2 Niño 3.4 hindcasts. In general, the correction reduced the forecast amplitude. This improved the quality of the forecasts when measured by the root mean square error (RMSE) of the ensemble mean forecast. RMSE decreased for most initialization months and forecast leads. The correction had a larger impact on seasons with strong El Niño-Southern Oscillation (ENSO) events than neutral seasons. The effects of the correction on the ensemble characteristics were also examined, and a variation of the algorithm was proposed that preserves the ensemble spread. The outcome of this project is a tool that can be used to calibrate GEOS-S2S-2 ENSO forecasts and potentially improve the precision of multi-model El Niño outlooks.

ENSO↗

NASA NTRS2018

Advancing the Science of Both Coastal Ocean Biophysics and Atmospheric Pollution Chemistry: A Final Report to the Nasa Earth Science Division by the GEO-CAPE Team

The 2007 Decadal Survey (DS) included the recommendation for the Geostationary Coastal and Air Pollution Events (GEO-CAPE) mission to launch in 2013–2016 to advance the science of both coastal ocean biophysics and atmospheric-pollution chemistry. In 2009 the NASA Earth Science Division (ESD) initiated study activities for GEO-CAPE and 8 other near- to medium-term missions to help determine the readiness of these conceptual missions to begin the formulation phase. In FY15 the GEO-CAPE mission study team completed a white paper summarizing the results of the pre-formulation work accomplished to date: https://geo-cape.larc.nasa.gov/pdf/GEO-CAPE_2009-2015_SummativeWhitePaper.pdf The team was directed to complete a final report in FY18. This document, prepared as an addendum to the FY15 white paper, serves as the GEO-CAPE final report and focuses only on FY16-18 activities and on summarizing the final state.

Geostationary Coastal and Air Pollution Events↗

DOE OSTI2022

Unique Role of GeO 2 as a Noninvasive Promoter of Nano‐Sized Zeolite Crystals

Abstract The synthesis of zeolites with nano‐sized dimensions is often limited to a narrow design space that conventionally relies upon the design of organics to direct hierarchical materials. Here, it is demonstrated that the addition of an inorganic modifier, germanium oxide (GeO 2 ), to a zeolite growth mixture directs the formation of crystals with ultrasmall dimensions. This effect is observed for zeolites ZSM‐11 and ZSM‐5 over a range of synthesis conditions wherein the role of GeO 2 in zeolite crystallization deviates from its typical function as a heteroatom. Notably, the final products contain trace amounts of Ge, which indicates the inorganic modifier does not compete for sites in the zeolite framework based on its formation of a discrete phase that enables GeO 2 recovery. Catalytic tests using the methanol‐to‐hydrocarbons reaction reveal significant enhancement in the performance of zeolite catalysts prepared with GeO 2 compared to reported examples of nano‐sized zeolites. These findings highlight a potentially generalizable and commercially viable synthesis method to reduce mass‐transport limitations in zeolites for diverse applications.

Chemistry↗

DOE OSTI2021

Toward the predictive discovery of ambipolarly dopable ultra-wide-band-gap semiconductors: The case of rutile GeO 2

Ultrawide-band-gap (UWBG) semiconductors are promising for fast, compact, and energy-efficient power-electronics devices. Their wider band gaps result in higher breakdown electric fields that enable high-power switching with a lower energy loss. Yet, the leading UWBG semiconductors suffer from intrinsic materials' limitations with regard to their doping asymmetry that impedes their adoption in CMOS technology. Improvements in the ambipolar doping of UWBG materials will enable a wider range of applications in power electronics as well as deep-UV optoelectronics. These advances can be accomplished through theoretical insights on the limitations of current UWBG materials coupled with the computational prediction and experimental demonstration of alternative UWBG semiconductor materials with improved doping and transport properties. As an example, we discuss the case of rutile GeO2 (r-GeO 2 ), a water-insoluble GeO 2 polytype, which is theoretically predicted to combine an ultra-wide gap with ambipolar dopability, high carrier mobilities, and a higher thermal conductivity than β-Ga 2 O 3 . The subsequent realization of single-crystalline r-GeO 2 thin films by molecular beam epitaxy provides the opportunity to realize r-GeO 2 for electronic applications. Future efforts toward the predictive discovery and design of new UWBG semiconductors include advances in first-principles theory and high-performance computing software, as well as the demonstration of controlled doping in high-quality thin films with lower dislocation densities and optimized film properties.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Simulation of Chilled-water Injection at EGS Collab Testbed 2 using the GEOS simulation framework

This work seeks to model the chilled-water injection that occurred at EGS Collab Testbed 2 as part of experiment 3, using the open-source GEOS simulation framework. Modeling of this process, previously conducted using STOMP-GT, confirmed that thermal breakthrough was expected to occur during the chill water injection and may have been masked by strong Joule-Thompsons effects induced by large pressure drops between the fractures and the production wells. Building a GEOS numerical model of this process will allow to include additional physics. In fact, GEOS can model fully coupled thermo-poromechanical processes in fractured porous media and can be employed to model the process of artificially enhancing rock permeability by hydraulically fracturing the rocks. For example, the GEOS model could help understanding the dynamic nature of the EGS collab experiment 3 flow system. Since the limited time and resources do not allow for an extensive study, the focus is on building a baseline model of this process. As such, the main outcomes of this modelling efforts are listed below.

15 GEOTHERMAL ENERGY↗