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At least 181 records · Page 10

Investigations of atomic and molecular processes of NBI-heated discharges in the MAST Upgrade Super-X divertor with implications for reactors

This experimental study presents an in-depth investigation of the performance of the MAST-U Super-X divertor during NBI-heated operation (up to 2.5 MW) focussing on volumetric ion sources and sinks as well as power losses during detachment. The particle balance and power loss analysis revealed the crucial role of Molecular Activated Recombination and Dissociation (MAR and MAD) ion sinks in divertor particle and power balance, which remain pronounced in the change from ohmic to higher power (NBI heated) L-mode conditions. The importance of MAR and MAD remains with double the absorbed NBI heating. MAD results in significant power dissipation (up to ${\sim} 20\%$ of $P_\textrm{SOL}$), mostly in the cold ($T_e \lt 5$ eV) detached region. Theoretical and experimental evidence is found for the potential contribution of $D^-$ to MAR and MAD, which warrants further study. These results suggest that MAR and MAD can be relevant in higher power conditions than the ohmic conditions studied previously. Post-processing reactor-scale simulations suggests that MAR and MAD can play a significant role in divertor physics and synthetic diagnostic signals of reactor-scale devices, which are currently underestimated in exhaust simulations. This raises implications for the accuracy of reactor-scale divertor simulations of particularly tightly baffled (alternative) divertor configurations.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Balance of Plant Modeling and Real-Time Hardware-in-the-Loop Integration with the Microreactor Automated Control System

The advent of novel microreactor technology has driven a focused effort to explore safety and efficiency improvements that can be achieved through the use of automated system control. Development of control strategies, especially for initial demonstration, requires an adequate surrogate environment to safely research failure modes and control integration with realistic hardware delay. However, efficiency gains from control strategies are improved when the scope of controller action is expanded to include system-level dynamics such as downstream heat extraction and mass flow. For this reason, a balance-of-plant (BOP) model of a representative microreactor system has been developed using the TRANsient Simulation Framework of Reconfigurable Models library in Modelica. This model captures a reactor and primary NaK coolant loop that represent corresponding system components of the Microreactor Applications Research Validation and EvaLuation (MARVEL) design as well as a secondary coolant loop and heat extraction representative of the Microreactor Agile Non-Nuclear Experimental Test Bed (MAGNET). This model configuration allows for hardware-in-the-loop (HIL) integration with microreactor automated control system (MACS) hardware in real time through a Python-based gRPC client. Real-time simulation of model performance with emulated hardware and communication delay suggests that under independent proportional-integral-derivative control of BOP model drum dynamics and downstream heat extraction, stable power load following is achievable. A slight delay in load following, filtering of high-frequency dynamics, and localized temperature fluctation suggest room for improvement through the development of higher-level control strategies. The simulated coupling of the MAGNET facility lays the groundwork for future digital twin analysis with a coupled MACS-MAGNET HIL demonstration.

McConnell, Jono [ORNL] (ORCID:0000000238984741)↗

Energy demand reduction in the built environment using shallow geothermal integrated energy systems: Part II – Hybrid ground source heat pump for building heating

The research collection aims at finding the various possible opportunities for the effective integration of shallow geothermal energy (SGE) to decrease the energy demand in the built environment and to reduce emission associated with it. The direct utilization of SGE using a ground source heat pump (GSHP) has been reviewed in comprehensive review part I and part II. From the extensive review, we have found that the hybrid GSHP is needed to avoid ground thermal imbalance and peak demand. Hybrid GSHP can adopt various supplemental heat sources and sinks according to the local climatic conditions and the balance of energy demands. The primary focus on the integration of subsystems such as biomass, solar energy (PV, PVT, and collector), phase change material, micro gas turbine, and absorption heat pump with GSHP is presented for heating application. This comprehensive review part III highlights the recent research findings and a potential gap in hybrid GSHP for further research and developments

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Introduction to this special section: Geothermal energy

Geothermal energy is a global renewable resource that has the potential to provide a significant portion of baseload energy in many regions. In the United States, it has the potential to provide 8.5% of the electric generation capacity by the middle of the century. In general, geothermal systems require heat, permeability, and water to be viable for energy generation. However, with current technologies, only heat is strictly necessary in a native system. Engineered geothermal systems (EGS) introduce water into the subsurface at elevated pressures and reduced temperatures and enhance permeability through hydraulic and/or shear fracturing. Additionally, although moderate- to high-temperature resources currently dominate geothermal energy production, low-temperature resources have been utilized for direct-use cases. When well balanced and maintained, geothermal resources can produce significant amounts of heat and achieve long-term sustainability on the order of an estimated tens to hundreds of years.

15 GEOTHERMAL ENERGY↗

Dissecting Nearby Galaxies with piXedfit. I. Spatially Resolved Properties of Stars, Dust, and Gas as Revealed by Panchromatic SED Fitting

We study spatially resolved properties (on spatial scales of ~1–2 kpc out to at least 3 effective radii) of the stars, dust, and gas in 10 nearby spiral galaxies. The properties of the stellar population and dust are derived by fitting the spatially resolved spectral energy distribution (SED) with more than 20 photometric bands ranging from far-ultraviolet to far-infrared. Our newly developed software piXedfit performs point-spread function matching of images, pixel binning, and models the stellar light, dust attenuation, dust emission, and emission from a dusty torus heated by an active galactic nucleus simultaneously through the energy-balance approach. With this self-consistent analysis, we present the spatially resolved version of the IRX–βrelation, finding that it is consistent with the relationship from the integrated photometry. We show that the old stellar populations contribute to the dust heating, which causes an overestimation of the star formation rate (SFR) derived from the total ultraviolet and infrared luminosities on kiloparsec scales. With archival high-resolution maps of atomic and molecular gas, we study the radial variation of the properties of the stellar populations (including stellar mass, age, metallicity, and SFR), dust (including dust mass, dust temperature, and abundance of polycyclic aromatic hydrocarbon), and gas, as well as dust-to-stellar mass and dust-to-gas mass ratios. We observe a depletion of the molecular gas mass fraction in the central region of the majority of the galaxies, suggesting that the lack of available fuel is an important factor in suppressing the specific SFR at the center.

79 ASTRONOMY AND ASTROPHYSICS↗

The Water Balance Representation in Urban‐PLUMBER Land Surface Models

Abstract Urban Land Surface Models (ULSMs) simulate energy and water exchanges between the urban surface and atmosphere. However, earlier systematic ULSM comparison projects assessed the energy balance but ignored the water balance, which is coupled to the energy balance. Here, we analyze the water balance representation in 19 ULSMs participating in the Urban‐PLUMBER project using results for 20 sites spread across a range of climates and urban form characteristics. As observations for most water fluxes are unavailable, we examine the water balance closure, flux timing, and magnitude with a score derived from seven indicators expecting better scoring models to capture the latent heat flux more accurately. We find that the water budget is only closed in 57% of the model‐site combinations assuming closure when annual total incoming fluxes (precipitation and irrigation) fluxes are within 3% of the outgoing (all other) fluxes. Results show the timing is better captured than magnitude. No ULSM has passed all water balance indicators for any site. Models passing more indicators do not capture the latent heat flux more accurately refuting our hypothesis. While output reporting inconsistencies may have negatively affected model performance, our results indicate models could be improved by explicitly verifying water balance closure and revising runoff parameterizations. By expanding ULSM evaluation to the water balance and related to latent heat flux performance, we demonstrate the benefits of evaluating processes with direct feedback mechanisms to the processes of interest.

Jongen, H. J.↗

Two-fluid model of rf current condensation in magnetic islands

The stabilization of tearing modes with rf waves is subject to a nonlinear effect, termed rf current condensation, that has the potential to greatly enhance and localize current driven within magnetic islands. Here we extend previous investigations of this effect with a two fluid model that captures the balance of diffusive and thermal equilibration processes within the island. We show that the effective power and resulting strength of the condensation effect can be greatly enhanced by avoiding collisional heat loss to the ions. The relative impact of collisions on the overall power balance within the island depends on the ratio of the characteristic diffusion timescale and the electron–ion equilibration time, rather than the latter alone. Although relative heat loss to ions increases with island size, the heating efficiency does as well. In particular, we show that the latter safely dominates for large deposition profiles, as is typically the case for lower hybrid current drive. This supports the possibility of passive stabilization of neoclassical tearing modes without the precise aiming of the rf waves required for electron cyclotron current drive stabilization.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Optimal operations of a nuclear-based integrated energy system: A mixed integer program approach

A nuclear-based integrated energy system (IES), consisting of multiple carbon-free energy generation and conversion technologies to meet heterogeneous end-use demands, offers a promising approach to decarbonizing the U.S. economy. Operating such an IES is challenging due to its complexity and the diverse end-use demands, such as heating and electricity. This paper aims to address the optimal operation of an IES composed of a small modular reactor (SMR), a steam manifold, a balance of plant (BOP), a high-temperature steam electrolysis (HTSE) system, a district heating (DH) network, and electrical grids. We formulate the system’s operation as a mixed integer linear programming (MILP) problem to maximize net revenues from sales of electricity and hydrogen. To evaluate the efficacy of the proposed model, we conduct a 24-hour simulation considering day-ahead (DA) electricity prices from CAISO and a varying DH demand profile with hourly resolution. The simulation results show that our model effectively optimizes the operation by selling electricity during on-peak periods and purchasing electricity for hydrogen production during off-peak periods, while satisfying operating constraints within the IES.

08 HYDROGEN↗

PERFORMANCE ANALYSIS OF AN ENGINEERING SCALE HYDROTHERMAL LIQUEFACTION SYSTEM

This work evaluates the Modular Hydrothermal Liquefaction System (MHTLS), an engineering-scale, integrated continuous HTL plant operated at the Pacific Northwest National Laboratory (PNNL), for converting realistic wet wastes into energy-dense biocrudes. The production campaigns discussed here processed algae, sewage sludges, lignocellulosic blends, Industrial food waste, and engineered food-waste slurries at 350?°C and around 200?bar, with nominal feed rates of ~12?L?h?¹. We report biocrude yields and composition, establish mass and elemental (C, N) balances, and quantify energy performance via heater duties, heat-exchanger behavior, and system-level efficiencies. Biocrudes contained 76–80?wt?% C (dry, ash-free) with HHVs of 38-41?MJ?kg?¹, substantially higher than feed materials HHVs of 16.6–26.1?MJ?kg?¹ and approaching petroleum fuels. Dry, ash-free biocrude yields of 32–53?wt?% corresponded to 43–71?wt?% carbon yields, with 18–40?wt?% of feed carbon routed to the aqueous phase. Thermal efficiencies were 50-65%, and total energy efficiencies, including reactor heat input, were 35-55%. A counter-current tube-in-tube heat exchanger delivered U values of 200–450?W?m?²?K?¹, with fouling-induced declines impacting heat recovery and heater duty. The analysis highlights three priorities for the process intensification of HTL: robust, fouling-resistant heat recovery, hydrodynamically suitable reactor and heat-exchanger designs, simplified and predictable solids management, and biocrude-water separation.

Biocrude production↗

Crystalline versus Glassy Nature of Iron Phosphate Waste Forms Subjected to Different Slow Cooling Curves

This report provides experimental details and associated results on the elemental distributions (compositions), crystalline/amorphous phase distributions, and microstructures for iron phosphate reference materials (DPF5-336) made with different cooling curves and starting from different temperatures (i.e., 1050°C and 1200°C). The primary goal of this work was to evaluate the properties of the DPF5- 336 reference material after it was melted and cooled at different rates to simulate the cooling profile of different types of canisters. Crystal fractions across the SCC#2, SCC#3, and SCC#5 samples were all similar ranging in crystal content of 35.66–41.14 mass% with amorphous fractions being the balance (64.34–58.86 mass%, respectively). This shows that the heat treatment profile did not seems to greatly affect either the total crystal content or the phase distributions. The quenched sample was almost completely amorphous (99.55 mass%) with very small peaks identified as Li 3 Fe 2 (PO 4 ) 3 whereas the SCC-treated materials showed peaks for what appear to be ten separate phases present in various concentrations. Another goal of these experiments was to see how the phase distribution affected chemical durability of these waste forms, but that information is being collected at Argonne National Laboratory and will be published in a separate report

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

An Overview of Non-LWR Vessel Cooling Systems for Passive Decay Heat Removal (Technical Letter Final Report)

The following report provides a technical review of various reactor vessel cooling system (VCS) concepts under consideration for decay heat removal (DHR) in non-light water advanced reactor designs. This review focuses on ex-vessel designs, including the Reactor Cavity Cooling System (RCCS), the Reactor Vessel Auxiliary Cooling System (RVACS), and hybrid iterations, using both air and water cooling to achieve their heat removal function. Based on a literature review of publicly available sources published between 1979 and 2021, a technical summary is presented detailing existing and planned VCS design options, their applicability to specific reactor type, and review of authored research and development studies. Following an assessment of the availability of data and modeling tools, an evaluation was performed analyzing their likely performance during normal, degraded, and accident conditions, including reliability, stability, and longevity. With renewed consideration of air-based DHR systems by some US vendors, there is a need to fully understand the complexities inherent to natural circulation systems, and more importantly, how they may influence safety-related heat removal functions and system performance. For DHR systems that rely on air-based mode of cooling, this entails quantification of the impacts of low flow conditions during start-up, relative elevations of inlet and outlet ducts for below-grade installations, effects of the use of multiple parallel chimneys for redundancy, and impact of weather conditions at the plant site. For systems relying on water-based mode cooling, reliance on limited coolant inventory in an event of pipe break or extended duration accident scenarios, sensitivities related to stability of boiling flow and heat transfer conditions, and quantification of full-scale structural vibrations on balance of plant structures are among the complicating factors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

High-fidelity multiphysics load following and accidental transient modeling of microreactors using NEAMS tools: Application of NEAMS codes to perform multiphysics modeling analyses of micro-reactor concepts

The feasibility of modeling microreactors using high-fidelity models with the Nuclear Energy Advanced Modeling and Simulation (NEAMS) tools is investigated in this report. Three overarching questions guided this research: can NEAMS tools readily be applied for high-fidelity multiphysics modeling of different types of transients in microreactor designs; how accurate are the results obtained; and are improvements needed in accuracy or user experience of NEAMS tools, especially considering newly developed capabilities? This work builds upon FY-2022 work, and two microreactor concepts considering heat pipe (HP-MR) and gas-cooled (GC-MR) technologies were further analyzed using high-fidelity multiphysics simulations. The NEAMS tools considered and coupled within the MultiApp environment are Griffin for neutronics, BISON for thermo-mechanics, Sockeye for heat pipe modeling (in HP-MR), SAM for 1D Fluid – 3D solid modeling of coolant channels and system modeling of balance of plant components (in GC-MR), and the SWIFT code for hydrogen redistribution in hydride moderator. The Heat Pipe MicroReactor (HP-MR) concept was further analyzed in FY-2023 to demonstrate the stochastic TRISO failure modeling capability in BISON to check operational limits of the TRISO fuel. A new full-core Gas-Cooled MicroReactor (GC-MR) model was developed based on the initial assembly-model used in Y-2022 and used for steady-state and accidental depressurization transient simulations. Accuracy of the simulations performed was assessed through 1) verification analyses completed on the different physics with code-to-code comparison, and 2) validation of the multiphysics simulations based on modeling of the Kilopower Reactor Using Stirling Technology (KRUSTY) experiment. In FY-2023, the mesh and model of KRUSTY was updated to closely match publicly available data, and the neutronic model was verified and validated against experimental control rod worth measurements. The multiphysics model of KRUSTY was developed and used for steady-state analysis and for modeling reactivity insertion transient. The calculated power increase and stabilization agrees well with experimental data following adjustment in fuel thermal expansion coefficient. As an important component of this project, the ANL team gathered experience with a wide range of NEAMS tools: the MOOSE Mesh System, Griffin, BISON, SWIFT, Sockeye, SAM, Workbench, and the MOOSE MultiApp System, and provided assessment of new capabilities. Noteworthy are the user assessment of the “vapor-only” flow model in Sockeye and development of a multiphysics startup transient in HP-MR unit cell for use as tutorial in Sockeye. The full-core GC-MR model was used for assessment of SAM for balance of plant modeling and for demonstrating the SWIFT code capability for hydrogen redistribution modeling in multiphysics transient analyses. In this process, several bugs/issues were identified and reported to developers. Finally, the assembly GC-MR model developed in FY-2022 coupling Griffin, BISON and SAM through flow blockage and rod ejection transients was published to the National Reactor Innovation Center (NRIC) Virtual Test Bed (VTB). The Heat Pipe MicroReactor (HP-MR) concept high-fidelity multiphysics coupling of Griffin/BISON/Sockeye in load-following and heat pipe failure transients was also published on the VTB. Those submissions are enabling thorough review of these models as well as wide distribution to industry, regulator, and university users. In this analysis, several new research questions were uncovered, and follow-up analyses are recommended to further improve some models, consider additional transients, and continue development of VTB models.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Strong influence of convective heat transfer efficiency on the cooling benefits of green roof irrigation

Abstract By enhancing evapotranspiration (ET), green roofs provide cooling benefits for the urban environment and are recognized as a promising heat mitigation strategy. The evaporative cooling effects of green roofs strongly depend on the soil moisture conditions and thus irrigation may be needed to sustain the cooling benefits. It has been shown that the magnitude of cooling benefits offered by green roof irrigation varies spatially, but its controlling factors remain elusive. In this study, we combine a surface energy balance (SEB) model with global simulations generated by an improved Earth System Model to illustrate the key factors controlling the cooling benefits of green roof irrigation. We employ a simple irrigation scheme, which is only active when there is no ice in soil layers and when the soil moisture is below field capacity. As a result, most of the irrigation water leaves the green roof system via ET. We find that the magnitude and also the spatial variability of the cooling benefits of green roof irrigation are controlled by the irrigation amount, and a surface energy redistribution factor that encodes the efficiencies of different SEB components in transferring heat. Further analysis indicates that the enhancement of latent heat flux due to irrigation is largely balanced by the reduction of sensible heat flux on green roofs. Therefore, the amount of irrigation needed per unit decrease of green roof surface temperature is mainly controlled by the convective heat transfer efficiency. A lower convective heat transfer efficiency (e.g. under a lower wind speed) helps reduce the amount of irrigation needed per unit decrease of green roof surface temperature. This study highlights the importance of SEB in constraining the cooling benefits of green roof irrigation and provides valuable guidance for urban planners and policy makers in terms of heat mitigation and sustainable water management.

Wang, Linying (ORCID:0000000308769220)↗

CROCUS Urban Fluxes of CO₂, H₂O, and Turbulence at University of Illinois Chicago

As of May 12, 2026 this dataset is currently being versioned to include data up to April 2026. Once the versioning process is complete, new data files will be available for access. The dataset metadata will also be updated to reflect the data availability of the new data being versioned. This dataset was collected at the UIC Plant Research Laboratory in Chicago, Illinois, as part of the Community Research on Climate and Urban Science (CROCUS) Urban Integrated Field Laboratory (UIFL) project, led by Argonne National Laboratory. The site provides continuous atmospheric flux measurements, focusing on CO₂, H₂O, and heat and momentum transport in an urban setting. The data is processed at 30 minutes interval using the Eddy Covariance method and includes quality control and diagnostic data generated by EddyPro software. The data is stored in the netCDF files following CF conventions. The UIC Plant Research Laboratory is located near major highways and urban infrastructure, including buildings and parking areas. The surrounding landscape consists of a mix of turf, plants, trees, and impervious surfaces such as concrete and asphalt, making it ideal for studying urban at for studies on urban sustainability, air quality, and the effects of urbanization on atmospheric processes on urban climate dynamics, air quality, and surface-atmosphere exchanges within the city of Chicago. This dataset is funded by the U.S. Department of Energy’s Office of Science, Biological and Environmental Research (BER) program.

54 ENVIRONMENTAL SCIENCES↗

Stabilizing the Grid and Reducing Utility Bills Through Price-Responsive Controls for Heat Pump Water Heaters

The electricity grid is facing increasing challenges in cost-effectively balancing supply and demand. These challenges are exacerbated by increased penetration of photovoltaics, which causes mid-day overproduction, and electrification of gas appliances, which increases peak-period electricity demand. Decarbonization requires shifting building loads from fossil-intensive high-cost times to renewable-intensive low-cost times while maintaining quality of service to occupants. Utilities and ISO’s are investigating new ways of incentivizing this load shifting. One promising method is the use of Highly Dynamic Prices (HDPs). HDPs feature continuously changing prices that reflect real-time grid generation and distribution costs and capacity constraints, and thus incentivize consumers to shift their loads. California’s CPUC CalFUSE proposal and Hawaii’s recent changes demonstrate that electricity tariffs are moving towards this model. For this to work however, loads must have the capability to respond to these prices. Heat pump water heaters (HPWHs) are an ideal device for this purpose because their storage tanks decouple delivery of domestic hot water from electricity consumption. The storage enables control strategies that consume midday solar power to increase the energy stored in the tank, then provide evening peak domestic hot water services using the stored energy. Berkeley Lab's CalFlexHub project is pioneering price-driven load flexibility by developing and deploying cost-minimizing controls for many flexible loads - including HPWHs - in response to HDP. Control development is based on simulations using the Flexible Heat Pump Water Heater Performance Predictor which captures the control decisions of the on-board controller in a residential, integrated HPWH . The price-responsive controls a) shift load in ways that consume additional midday solar power to help stabilize the grid and reduce overall emissions, b) ensure that occupants receive equal or better hot water delivery service, and c) minimize the operating cost for each home in the fleet. On the grid level, the resulting shift will reduce utility operating costs and emissions, and can avoid expensive system capacity expansions. The control approach is customized to each home based on typical hot water consumption patterns. HPWH controllers, whether on the device or remotely, will receive a schedule of CTA-2045-B signals or set temperature adjustments customized to the current HDP price schedule and home. Simulation results for a fleet of 148 HPWHs on a summer day in Berkeley, California show cost savings of 29% and high price electricity consumption reductions of 80%, while maintaining full quality of service.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Fracture of PC and PMMA cylinders in the Taylor tests

The present paper analyzes failure observed in polymer rods collided with a steel anvil under the Taylor cylinder impact experiments. The experimental and numerical analysis demonstrates that association of the failure patterns with the loading mode depends on the rod material. Two materials are considered in the paper, specifically, polymethylmethacrylate (PMMA) and polycarbonate (PC). Damage in PMMA rods at the Taylor tests is shown to be dominated by the shear load resulting in plastic deformation. In contrast, the major mechanism of damage in PC rods is governed by omni-directional (pressure) mode of load. Analysis of the damage in sections of the rods associated with the glass transition is also addressed in the present theoretical study. Failure in these polymers follows the traditional fracture wave mechanism for brittle glass-type materials due to load in the corresponding mode. Numerical analysis employs a two-phase model with improved inter-phase thermal balance accounting for the inter-phase mass, momentum, and heat exchanges during the glass phase transition, while damage being accumulated in time. In conclusion, the simulation results demonstrate a good correlation with the experimental results.

36 MATERIALS SCIENCE↗

Design of inertial fusion implosions reaching the burning plasma regime

One of the last remaining milestones in fusion research before reaching ignition is creating a burning plasma state, where alpha particles from deuterium-tritium (DT) fusion reactions redeposit their energy as the dominant source of heating in the plasma. The indirect-drive inertial confinement fusion approach at the National Ignition Facility (NIF) uses a laser-generated radiation cavity (hohlraum) to spherically implode DT fuel to high temperatures and densities in a central ”hot spot”. Here, we deliver more energy to the hot spot than ever before, while maintaining the extreme pressures required for inertial confinement, by increasing the size of the implosion compared to previous experiments. We develop more efficient hohlraums, to drive these larger implosions within NIF’s current laser energy and power capability and control symmetry by moving energy between laser beams and by changing the shape of the hohlraum. These designs resulted in record fusion powers of 1.5 petawatts, greater than the input power of the laser, and 170 kJ of fusion energy. Radiation hydrodynamics simulations show alpha particle heating as the dominant term in the hot spot energy balance, e.g. a burning plasma state. This work is expected to motivate future studies of burning plasmas and improve predictive capability by providing a benchmark for modeling used to understand the proximity to ignition.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Evaluation of the energy balance of chemical looping combustion of solid fuels using CuO-based oxygen carriers

Chemical looping combustion (CLC) can inherently capture the CO2 generated during thermal energy production. When using CuO-based oxygen carriers, the reactions in both the fuel reactor (FR) and air reactor (AR) are exothermic, facilitating autothermal operation. To prevent the oxygen carrier from becoming agglomerated while ensuring a sufficient oxygen release rate, it is necessary to predict the FR temperature and remove an appropriate amount of heat from the AR when burning high-rank fuels. Here in this work, the energy balance of a CuO-based CLC system firing various solid fuels (biomass, coal, and petroleum coke) was investigated by establishing a thermodynamic model using FactSage. The energy distribution characteristics of the FR were quantified based on a virtual five-step thermodynamic sequence. The effects of fuel properties, oxygen carrier properties, and operating conditions on the energy balance were evaluated systematically. The results indicate that the temperature difference between the FR and AR is not very sensitive to the heating value of the fuel, while the CuO loading of the oxygen carrier, the heat capacity of the support material, and the flow rate of the fluidizing gas have significant impact. The insights obtained in this work will help improve the design and heat management of CLC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗