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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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180 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Carbon Dioxide Pressure and Catalyst Quantity Dependencies in Artificial Photosynthesis of Hydrocarbon Chains on Nanostructured Co/CoO Surfaces

In this study, we investigated the influence of pressure and the quantity of Co/CoO catalyst on an artificial photosynthesis process that converts CO 2 and H 2 O into hydrocarbons (C n H 2n+2 , where n ≤ 18). The adsorption of CO 2 and H 2 O on Co/CoO surfaces proved to be pivotal in this photo-catalytic reaction. Photoexcited carbon dioxide and water molecules ((CO 2 )* and (H 2 O)*) generated by illuminating the catalyst surface led to the formation of alkene hydrocarbon molecules with carbon numbers following an approximate Poisson distribution. The optimal pressure was found to be 0.40 MPa. Pressure less than 0.40 MPa resulted in low CO 2 adsorption, impeding excitation for photosynthesis. At greater pressure, oil/wax accumulation on Co/CoO surfaces hindered CO 2 adsorption, limiting further photosynthesis reactions. The average number of carbon atoms in the hydrocarbons and hydrocarbon yield were correlated. The amount of Co/CoO was also found to affect the hydrocarbon yield. Our study contributes to the understanding of Co/CoO-catalyzed photosynthesis and suggests that an open-flow system could potentially enhance the productivity of long-chain hydrocarbons.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Recent Progress of High Performance Thermosets Based on Norbornene Functional Benzoxazine Resins

With the growing demand for high performance polymeric materials in industry, several types of thermosets such as bismaleimides, advanced epoxy resins, cyanate esters, and phenolic resins have been widely investigated to improve the performance of thermosetting products. Among them, benzoxazine resins have received wide attention due to their extraordinarily rich molecular design flexibility, which can customize our needs and adapt increasing requirements. To further improve the properties of polybenzoxiazines, researchers have found that the introduction of a norbornene functional group into the benzoxazine moiety can effectively improve the comprehensive performance of polybenzoxazine thermosets. This article focused on reviewing the recent development of high-performance thermosets based on norbornene functional benzoxazine thermosetting resins.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Multi-Size Proppant Pumping Schedule of Hydraulic Fracturing: Application to a MP-PIC Model of Unconventional Reservoir for Enhanced Gas Production

Slickwater hydraulic fracturing is becoming a prevalent approach to economically recovering shale hydrocarbon. It is very important to understand the proppant’s transport behavior during slickwater hydraulic fracturing treatment for effective creation of a desired propped fracture geometry. The currently available models are either oversimplified or have been performed at limited length scales to avoid high computational requirements. Another limitation is that the currently available hydraulic fracturing simulators are developed using only single-sized proppant particles. Motivated by this, in this work, a computationally efficient, three-dimensional, multiphase particle-in-cell (MP-PIC) model was employed to simulate the multi-size proppant transport in a field-scale geometry using the Eulerian–Lagrangian framework. Instead of tracking each particle, groups of particles (called parcels) are tracked, which allows one to simulate the proppant transport in field-scale geometries at an affordable computational cost. Then, we found from our sensitivity study that pumping schedules significantly affect propped fracture surface area and average fracture conductivity, thereby influencing shale gas production. Motivated by these results, we propose an optimization framework using the MP-PIC model to design the multi-size proppant pumping schedule that maximizes shale gas production from unconventional reservoirs for given fracturing resources.

42 ENGINEERING↗
DOE OSTI2023

Beyond n-dopants for organic semiconductors: use of bibenzo[ d ]imidazoles in UV-promoted dehalogenation reactions of organic halides

2,2’-Bis(4-dimethylaminophenyl)- and 2,2'-dicyclohexyl-1,1',3,3'-tetramethyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[ d ]imidazole ((N-DMBI) 2 and (Cyc-DMBI) 2 ) are quite strong reductants with effective potentials of ca. −2 V vs ferrocenium/ferrocene, yet are relatively stable to air due to the coupling of redox and bond-breaking processes. Here, we examine their use in accomplishing electron transfer-induced bond-cleavage reactions, specifically dehalogenations. The dimers reduce halides that have reduction potentials less cathodic than ca. −2 V vs ferrocenium/ferrocene, especially under UV photoexcitation (using a 365 nm LED). In the case of benzyl halides, the products are bibenzyl derivatives, whereas aryl halides are reduced to the corresponding arenes. The potentials of the halides that can be reduced in this way, quantum-chemical calculations, and steady-state and transient absorption spectroscopy suggest that UV irradiation accelerates the reactions via cleavage of the dimers to the corresponding radical monomers.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Global nitrogen and sulfur deposition mapping using a measurement–model fusion approach

Abstract. Global reactive nitrogen (N) deposition has more than tripled since 1860 and is expected to remain high due to food production and fossil fuel consumption. Global sulfur emissions have been decreasing worldwide over the last 30 years, but many regions are still experiencing unhealthily high levels of deposition. We update the 2010 global deposition budget for reactive nitrogen and sulfur components with new regional wet deposition measurements from Asia, improving the ensemble results of 11 global chemistry transport models from the second phase of the United Nations Economic Commission for Europe's Task Force on Hemispheric Transport of Air Pollution (HTAP II). The observationally adjusted global N deposition budget is 114.5 Tg N, representing a minor increase of 1 % from the model-only derived values, and the adjusted global sulfur deposition budget is 88.9 Tg S, representing a 6.5 % increase from the modeled values, using an interpolation distance of 2.5∘. Regionally, deposition adjustments can be up to ∼ 73 % for nitrogen and 112 % for sulfur. Our study demonstrates that a global measurement–model fusion approach can improve N and S deposition model estimates at a regional scale, with sufficient availability of observations; however, in large parts of the world, alternative approaches need to be explored. The analysis presented here represents a step forward toward the World Meteorological Organization's goal of global fusion products for accurately mapping harmful air pollution deposition.

Rubin, Hannah J. (ORCID:0000000182226924)↗
DOE OSTI2020

Generation and analysis of chemical compound libraries

Various samples are generated on a substrate. The samples each includes or consists of one or more analytes. In some instances, the samples are generated through the use of gels or through vapor deposition techniques. The samples are used in an instrument for screening large numbers of analytes by locating the samples between a working electrode and a counter electrode assembly. The instrument also includes one or more light sources for illuminating each of the samples. The instrument is configured to measure the photocurrent formed through a sample as a result of the illumination of the sample.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Collaborative RFID reader using code divisional multiple access (CDMA) and methods for same

The present disclosure provides collaborative radiofrequency identification (RFID) readers that employ code division multiple access (CDMA) encoding to simultaneously broadcast to and read responses from tags in an overlapping reading zone with improved data synchronization and read yield rates. In some embodiments, a harmonic backscattering scheme is used to enable the system to have a much higher signal-to-noise ratio (SNR) and sensitivity, while the reader CDMA protocol can be integrated with an initial TDMA polling process or alternative tag CDMA scheme.

Kan, Edwin C.↗
DOE OSTI2022

System and method for ultra-high-resolution ranging using RFID

A radio-frequency method for range finding includes modulating a reference signal having an intermediate frequency to a downlink signal having a carrier frequency using a clock signal. The downlink signal is transmitted to a tag using a transceiver. An uplink signal backscattered from the tag is received and demodulated using the clock signal. The uplink signal has a frequency that is a harmonic of the carrier frequency. A distance between the tag and the transceiver is calculated based on a phase of the demodulated uplink signal. A system for range finding includes a transceiver and a processor. The transceiver modulates a reference signal to a downlink signal and transmits the downlink signal. The transceiver receives and demodulates an uplink signal. The processor is configured to receive the demodulated uplink signal and calculate a distance between the tag and the transceiver using a phase of the demodulated uplink signal.

Hui, Xiaonan↗
DOE OSTI2023

Methods and systems for electromagnetic near-field coherent sensing

The present disclosure may be embodied as methods and/or systems for non-contact measuring of an on-body and/or inside-body motion of an individual. A sensing signal is provided within a near-field coupling range of a motion to be measured. In this way, a measurement signal may be generated as the sensing signal modulated by the motion. The sensing signal may be an ID-modulated signal. In some embodiments, the sensing signal is a backscattered RFID link provided a wireless tag. A downlink signal may be provided to power the wireless tag. The sensing signal may be a harmonic of the downlink signal. The measurement signal is detected. The motion is measured based on the measurement signal. The measurement signal may be detected as far-field radiation after transmission through a source of the motion. The measurement signal may be detected as reflected from a source of the motion as antenna reflection.

Hui, Xiaonan↗
DOE OSTI2024

System and method for ultra-high-resolution ranging using RFID

A radio-frequency method for range finding includes modulating a reference signal having an intermediate frequency to a downlink signal having a carrier frequency using a clock signal. The downlink signal is transmitted to a tag using a transceiver. An uplink signal backscattered front the tag is received and demodulated using the clock signal. The uplink signal has a frequency that is a harmonic of the carrier frequency. A distance between the tag and the transceiver is calculated based on a phase of the demodulated uplink signal. A system for range finding includes a transceiver and a processor. The transceiver modulates a reference signal to downlink signal and transmits the downlink signal. The transceiver receives and demodulates an uplink signal. The processor is configured to receive the demodulated uplink signal and calculate a distance between the tag and the transceiver using a phase of the demodulated uplink signal.

Hui, Xiaonan↗
DOE OSTI2024

Collaborative RFID reader using code divisional multiple access (CDMA) and methods for same

The present disclosure provides collaborative radiofrequency identification (RFID) readers that employ code division multiple access (CDMA) encoding to simultaneously broadcast to and read responses from tags in an overlapping reading zone with improved data synchronization and read yield rates. In some embodiments, a harmonic backscattering scheme is used to enable the system to have a much higher signal-to-noise ratio (SNR) and sensitivity, while the reader CDMA protocol can be integrated with an initial TDMA polling process or alternative tag CDMA scheme.

Kan, Edwin C.↗