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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Generation and Evolution of High-Mach-Number Laser-Driven Magnetized Collisionless Shocks in the Laboratory

Here, we present the first laboratory generation of high-Mach-number magnetized collisionless shocks created through the interaction of an expanding laser-driven plasma with a magnetized ambient plasma. Time-resolved, two-dimensional imaging of plasma density and magnetic fields shows the formation and evolution of a supercritical shock propagating at magnetosonic Mach number M ms ≈ 12. Particle-in-cell simulations constrained by experimental data further detail the shock formation and separate dynamics of the multi-ion-species ambient plasma. The results show that the shocks form on time scales as fast as one gyroperiod, aided by the efficient coupling of energy, and the generation of a magnetic barrier between the piston and ambient ions. The development of this experimental platform complements present remote sensing and spacecraft observations, and opens the way for controlled laboratory investigations of high-Mach number collisionless shocks, including the mechanisms and efficiency of particle acceleration.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

One dimensional shock initiation of hot isostatically pressed composition B

Twelve one dimensional shock experiments have been carried out on the UK isostatically pressed Composition B (59.5% RDX, 39.5% TNT, 1% wax) comprising of seven sustained pulse experiments and three short shock experiments using the embedded gauge technique at the Los Alamos National Laboratory gas gun facility. The evolution of the reactive growth at and behind the shock front has been measured along with the run to detonation distance. Two low pressure experiments have also been carried out to obtain non-reactive equation of state data. These data have been used to create the Pop plot and Hugoniot states for the UK Comp B. The shock initiation behavior of the UK Comp B has been compared to that of the equivalent US composition. The reactive growth shows a feature that was observed in the US composition in which the wave profiles display a high level of pre-detonation noise. This was hypothesized to be due to a piezoelectric effect in the RDX crystals. The results of these experiments have shown that this effect may be localized in the ε phase at shock pressures in the region of 4.15 GPa and above.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Light transport with weak angular dependence in fog

Random scattering and absorption of light by tiny particles in aerosols, like fog, reduce situational awareness and cause unacceptable down-time for critical systems or operations. Computationally efficient light transport models are desired for computational imaging to improve remote sensing capabilities in degraded optical environments. To this end, we have developed a model based on a weak angular dependence approximation to the Boltzmann or radiative transfer equation that appears to be applicable in both the moderate and highly scattering regimes, thereby covering the applicability domain of both the small angle and diffusion approximations. An analytic solution was derived and validated using experimental data acquired at the Sandia National Laboratory Fog Chamber facility. The evolution of the fog particle density and size distribution were measured and used to determine macroscopic absorption and scattering properties using Mie theory. A three-band (0.532, 1.55, and 9.68 µ m) transmissometer with lock-in amplifiers enabled changes in fog density of over an order of magnitude to be measured due to the increased transmission at higher wavelengths, covering both the moderate and highly scattering regimes. The meteorological optical range parameter is shown to be about 0.6 times the transport mean free path length, suggesting an improved physical interpretation of this parameter.

74 ATOMIC AND MOLECULAR PHYSICS↗

Short video provides broad overview of the Lab’s 80-year history

In celebration of the Lab’s 80th anniversary this month, join National Security Research Center Senior Historian, Alan Carr (NSRCMS), as he provides a six-and-a-half-minute overview of the Lab’s history. The video, co-produced by Brian Clayton (CEA-MP) and Howard Coe (CEA-MP), covers three phases of the Lab’s evolution, from a nuclear weapons laboratory, then a nuclear science laboratory, to its manifestation today as a multidisciplinary laboratory.

99 GENERAL AND MISCELLANEOUS↗

Visualizing Uranium Crystallization from Melt: Experiment-Informed Phase Field Modeling and Machine Learning

The focus of this project was to observe and simulate the solidification of uranium metal at the crystallographic level from its molten state. Melting experiments were conducted at two different scales to observe microstructural evolution using either a laboratory-scale induction furnace (hundreds of grams of metal) or a microscope heating stage (hundreds of milligrams of metal), respectively. Experimental parameters and characterization data were then used to inform a phase field model of gamma-U crystal growth as dendrites with or without secondary phase impurities in the form of uranium carbide particles. Finally, training datasets were generated by the phase field model as inputs to a neural network, developed with the aim of providing a faster, cheaper surrogate model for microstructural simulations within a given parameter space. Progress is reported herein for each of these task areas. Ultimately, 1) an optical microscope heating stage capability has been stood-up for uranium metal solidification studies, 2) a phase field model was advanced to simulate multiple uranium grains growing in the presence of carbide impurity particles and 3) a neural network was constructed and optimized to predict the microstructure features of individually growing uranium crystals.

36 MATERIALS SCIENCE↗

Laboratory Studies of Extraterrestrial Ices and PAHs: Making an Astrobiological Silk Purse Out of An Interstellar Sow's Ear

Tremendous strides have been made in our understanding of interstellar material over the past twenty years thanks to significant, parallel developments in observational astronomy and laboratory astrophysics. Today, the composition of dust in the ISM is reasonably well constrained to cold, micron-sized particles of various refractory materials. Shrouded within the protective confines of cold, opaque molecular clouds--the birthplace of stars and planets--these particles secrete mantles of mixed molecular lees whose major components are also well constrained. Finally, amidst the molecular inventory of these ice mantles are likely to be found polycyclic aromatic hydrocarbons (PAHs), whose telltale infrared signature I is now recognized throughout the Universe. However, of what significance is this scenario to the origin of life in our solar system--or any other? The major components of the icy materials observed in interstellar clouds and in our own solar system are uniformly quite simple. In addition, despite the fact that PAHs likely represent the single largest molecular reservoir of organic carbon in evolving planetary systems, they are not what would be considered "biogenic" molecules. Although interesting from a chemical and astrophysical standpoint, in the absence of a mechanism by which these materials can be transformed into more biochemically significant structures, they are of little Astrobiological significance. In this talk, we will begin with a brief review of the nature and abundance of the "raw" population of PAHs and PAH-related materials in the ISM. From there, we will move on to explore our laboratory simulations of the photochemical evolution of realistic mixed molecular ices under conditions which simulate those encountered in the ISM and in evolving planetary systems. Particular attention will be paid to the surprisingly complex array of organic species that are produced in these ices from such a deceptively simple inventory of starting materials. In addition, we will explore the chemistry of PAHs under these conditions and consider its potential for transforming that rich repository of pre-biotic organic "ore" into materials of greater importance to Astrobiology.

Hudgins, Douglas M.↗

Glass Bubbles Insulation for Liquid Hydrogen Storage Tanks

A full-scale field application of glass bubbles insulation has been demonstrated in a 218,000 L liquid hydrogen storage tank. This work is the evolution of extensive materials testing, laboratory scale testing, and system studies leading to the use of glass bubbles insulation as a cost efficient and high performance alternative in cryogenic storage tanks of any size. The tank utilized is part of a rocket propulsion test complex at the NASA Stennis Space Center and is a 1960's vintage spherical double wall tank with an evacuated annulus. The original perlite that was removed from the annulus was in pristine condition and showed no signs of deterioration or compaction. Test results show a significant reduction in liquid hydrogen boiloff when compared to recent baseline data prior to removal of the perlite insulation. The data also validates the previous laboratory scale testing (1000 L) and full-scale numerical modeling (3,200,000 L) of boiloff in spherical cryogenic storage tanks. The performance of the tank will continue to be monitored during operation of the tank over the coming years.

Glass bubble↗

JWST Observations of the Enigmatic Y Dwarf WISE 1828+2650: I. Limits to a Binary Companion

The Y-dwarf WISE 1828+2650 is one of the coldest known Brown Dwarfs with an effective temperature of ~300 K. Located at a distance of just 10 pc, previous model-based estimates suggest WISE 1828+2650 has a mass of ~5-10 M J , making it a valuable laboratory for understanding the formation, evolution and physical characteristics of gas giant planets. However, previous photometry and spectroscopy have presented a puzzle with the near-impossibility of simultaneously fitting both the short (0.9-2.0 μm) and long wavelength (3-5 μm) data. A potential solution to this problem has been the suggestion that WISE 1828+2650 is a binary system whose composite spectrum might provide a better match to the data. Alternatively, new models being developed to fit JWST/NIRSpec and MIRI spectroscopy might provide new insights. This article describes JWST/NIRCam observations of WISE 1828+2650 in 6 filters to address the binarity question and to provide new photometry to be used in model fitting. We also report Adaptive Optics imaging with the Keck 10 m telescope. We find no evidence for multiplicity for a companion beyond 0.5 AU with either JWST or Keck. Companion articles will present low and high resolution spectra of WISE 1828 obtained with both NIRSpec and MIRI.

Infrared spectroscopy↗

JWST Observations of the Enigmatic Y Dwarf WISE 1828+2650: I. Limits to a Binary Companion

The Y-dwarf WISE 1828+2650 is one of the coldest known brown dwarfs with an effective temperature of∼300K. Located at a distance of just 10 pc, previous model-based estimates suggest WISE1828+2650 has a mass of∼5–10MJ, making it a valuable laboratory for understanding the formation, evolution, and physical characteristics of gas giant planets. However, previous photometry and spectroscopy have presented a puzzle, with the near impossibility of simultaneously fitting both the short-(0.9–2.0μm)and long-wavelength(3–5μm)data. A potential solution to this problem has been the suggestion that WISE 1828+2650 is a binary system whose composite spectrum might provide a better match to the data. Alternatively, new models being developed to fit JWST/NIRSpec, and MIRI spectroscopy might provide new insights. This article describes JWST/NIRCam observations of WISE 1828+2650 in six filters to address the binarity question and to provide new photometry tobe used in model fitting. We also report adaptive optics imaging with the Keck I0 m telescope. We find no evidence for multiplicity for a companion beyond 0.5 au with either JWST or Keck. Companion articles will present low-and high-resolution spectra of WISE 1828 obtained with both NIRSpec and MIRI.

NIRCam↗

Python codes for the paper - "Trade-offs in the latent representation of microstructure evolution"

SAND2024-00946O Python codes used in "Trade-offs in the latent representation of microstructure evolution," a manuscript accepted for publication in Acta Materialia, are part of a repository. The code was developed to perform analysis of microstructure evolution. The repository consists of two main directories: models, which train and test models such as autoencoders and diffusion maps, and analysis, which analyzes microstructures. Source code is used to perform dimensionality reduction of microstructure data for analysis of its evolution in time. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

Dingreville, Remi↗

Propanal, an Interstellar Aldehyde - First Infrared Band Strengths and Other Properties of the Amorphous and Crystalline Forms

Chemical evolution in molecular clouds in the interstellar medium is well established, with the identification of over 200 molecules and molecular ions. Among the classes of interstellar organic compounds found are the aldehydes. However, laboratory work on the aldehydes has scarcely kept pace with astronomical discoveries as little quantitative solid-phase infrared (IR) data has been published on any of the aldehydes, and the same is true for important properties such as density, refractive indices, and vapor pressures. In this paper we examine the IR spectra of solid propanal (HC(O)CH2CH3, propionaldehyde), along with several physical properties, for both the amorphous and crystalline forms of the compound. The quantitative measurements we report, such as infrared intensities and optical constants, will be useful in laboratory investigations of the formation and evolution of propanal-containing ices, will serve as benchmark data for theoretical investigations, and will inform observational studies.

Yukiko Yagi Yarnall↗

Simulations of plasma structure evolution in the high-latitude ionosphere

The Naval Research Laboratory has recently developed a two-dimensional inertial, electrostatic code which has been successfully applied to the development and evolution of ionospheric structure driven by plasma instabilities. This code models the ionosphere and magnetosphere as a set of horizontal two-dimensional layers which are coupled by the vertical magnetic field lines at high latitudes. It is shown that the development of instability-generated structure can be strongly dependent on this coupling. For example, the influence of magnetospheric coupling on the E x B gradient drift instability is to retard the instability's growth and to isotropize density irregularities. The influence of ionospheric coupling on the Kelvin-Helmholtz instability is to retard its growth and to suppress vortex formation. This paper presents the results of numerical simulations of these instabilities and discusses their application to high-latitude ionospheric structure.

Huba, J. D.↗

Investigating the eco‐evolutionary response of microbiomes to environmental change

Abstract Microorganisms are the primary engines of biogeochemical processes and foundational to the provisioning of ecosystem services to human society. Free‐living microbial communities (microbiomes) and their functioning are now known to be highly sensitive to environmental change. Given microorganisms' capacity for rapid evolution, evolutionary processes could play a role in this response. Currently, however, few models of biogeochemical processes explicitly consider how microbial evolution will affect biogeochemical responses to environmental change. Here, we propose a conceptual framework for explicitly integrating evolution into microbiome–functioning relationships. We consider how microbiomes respond simultaneously to environmental change via four interrelated processes that affect overall microbiome functioning (physiological acclimation, demography, dispersal and evolution). Recent evidence in both the laboratory and the field suggests that ecological and evolutionary dynamics occur simultaneously within microbiomes; however, the implications for biogeochemistry under environmental change will depend on the timescales over which these processes contribute to a microbiome's response. Over the long term, evolution may play an increasingly important role for microbially driven biogeochemical responses to environmental change, particularly to conditions without recent historical precedent.

54 ENVIRONMENTAL SCIENCES↗

Mid- and far-infrared spectroscopic studies of the influence of temperature, ultraviolet photolysis and ion irradiation on cosmic-type ices

Infrared (IR) studies of laboratory ices can provide information on the evolution of cosmic-type ices as a function of different simulated space environments involving thermal, ultraviolet (UV), or ion processing. Laboratory radiation experiments can lead to the formation of complex organic molecules. However, because of our lack of knowledge about UV photon and ion fluxes, and exposure lifetimes, it is not certain how well our simulations represent space conditions. Appropriate laboratory experiments are also limited by the absence of knowledge about the composition, density, and temperature of ices in different regions of space. Our current understanding of expected doses due to UV photons and cosmic rays is summarized here, along with an inventory of condensed-phase molecules identified on outer solar system surfaces, comets and interstellar grains. Far-IR spectra of thermally cycled H2O are discussed since these results reflect the dramatic difference between the amorphous and crystalline phases of H2O ice, the most dominant condensed-phase molecule in cosmic ices. A comparison of mid-IR spectra of products in proton-irradiated and UV-photolyzed ices shows that few differences are observed for these two forms of processing for the simple binary mixtures studied to date. IR identification of radiation products and experiments to determine production rates of new molecules in ices during processing are discussed. A new technique for measuring intrinsic IR band strengths of several unstable molecules is presented. An example of our laboratory results applied to Europa observations is included.

Spectrophotometry, Infrared/methods↗

Kinetic simulations comparing quasi-parallel and quasi-perpendicular piston-driven collisionless shock dynamics in magnetized laboratory plasmas

Magnetized collisionless shocks are common in astrophysical systems, and scaled versions can be created in laboratory experiments by utilizing laser-driven piston plasmas to create these shocks in a magnetized background plasma. A key parameter for these experiments is the angle θB between the shock propagation direction and the background magnetic field. We performed quasi-1D piston-driven shock simulations to explore shock formation, evolution, and key observables relevant to laboratory experiments for a range of shock angles between θB=90° to θB=30°. Our results show that the spatial and temporal scales of shock formation for all angles considered are similar when expressed in terms of the perpendicular component of the magnetic field. In a steady state, ion and electron temperatures become more isotropic, and the electron-to-ion temperature ratio is higher for smaller θB. At θB=30°, ion heating parallel to the magnetic field becomes dominant, associated with more ions being reflected at one discontinuity and subsequently trapped by the next discontinuity due to shock reformation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Opportunities to Update the Model of Tank Closure Grout Aging (SRNL-STI-2012-00404) Based on Experimental Results by the Savannah River Ecology Laboratory

The purpose of this report was to review the results of experiments on evolution of tank grout pore fluids performed by the Savannah River Ecology Laboratory (SREL) and reported in Seaman et al. (2020) and highlight opportunities for updating the model of tank grout degradation presented in Denham and Millings (2012). The SREL experimental results validate some assumptions used in the 2012 grout degradation model and provide information useful for updating the model. All experiments on tank grout degradation have limitations because of reaction rates and the enormous disparity between duration of the experiments and the duration of the degradation of the real tank grout system. Given these limitations, the experimental results form the basis for several recommendations for updating the grout degradation model described in this report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

In vitro continuous protein evolution empowered by machine learning and automation

Directed evolution has become one of the most successful and powerful tools for protein engineering. However, the efforts required for designing, constructing, and screening a large library of variants can be laborious, time-consuming, and costly. With the recent advent of machine learning (ML) in the directed evolution of proteins, researchers can now evaluate variants in silico and guide a more efficient directed evolution campaign. Furthermore, recent advancements in laboratory automation have enabled the rapid execution of long, complex experiments for high-throughput data acquisition in both industrial and academic settings, thus providing the means to collect a large quantity of data required to develop ML models for protein engineering. In this perspective, here we propose a closed-loop in vitro continuous protein evolution framework that leverages the best of both worlds, ML and automation, and provide a brief overview of the recent developments in the field.

59 BASIC BIOLOGICAL SCIENCES↗