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NASA NTRS2011

A Search for Optically Faint GEO Debris

Existing optical surveys for debris at geosynchronous orbit (GEO) have been conducted with meter class telescopes, which have detection limits in the range of 18th-19th magnitude. We report on a new search for optically faint debris at GEO using the 6.5-m Magellan 1 telescope Walter Baade at Las Campanas Observatory in Chile. Our goal is to go as faint as possible and characterize the brightness distribution of debris fainter than R = 20th magnitude, corresponding to a size smaller than 10 cm assuming an albedo of 0.175. We wish to compare the inferred size distribution for GEO debris with that for LEO debris. We describe results obtained during 9.4 hours of observing time during 25-27 March 2011. We used the IMACS f/2 instrument, which has a mosaic of 8 CCDs, and a field of view of 30 arc-minutes in diameter. This is the widest field of view of any instrument on either Magellan telescope. All observations were obtained through a Sloan r filter. The limiting magnitude for 5 second exposures is estimated to be fainter than 22. With this small field of view and the limited observing time, our objective was to search for optically faint objects from the Titan 3C Transtage (1968-081) fragmentation in 1992. Eight debris pieces and the parent rocket body are in the Space Surveillance Network public catalog. We successfully tracked two cataloged pieces of Titan debris (SSN # 25001 and 33519) with the 6.5-m telescope, followed by a survey for objects on similar orbits but with a spread in mean anomaly. To detect bright objects over a wider field of view (1.6x1.6 degrees), we observed the same field centers at the same time through a similar filter with the 0.6-m MODEST (Michigan Orbital DEbris Survey Telescope), located 100 km to the south of Magellan at Cerro Tololo Inter-American Observatory, Chile. We will describe our experiences using Magellan, a telescope never used previously for orbital debris research, and our initial results.

Seitzer, Patrick↗
NASA NTRS2011

Simultaneous Planck, Swift, and Fermi Observations of X-Ray and gamma-Ray Selected Blazars

We present simultaneous Planck, Swift, Fermi, and ground-based data for 105 blazars belonging to three samples with flux limits in the soft X-ray, hard X-ray, and -ray bands, and we compare our results to those of a companion paper presenting simultaneous Planck and multi-frequency observations of 104 radio-loud northern active galactic nuclei selected at radio frequencies. While we confirm several previous results, our unique data set has allowed us to demonstrate that the selection method strongly influences the results, producing biases that cannot be ignored. Almost all the BL Lac objects have been detected by Fermi Large Area Telescope (LAT), whereas 30 to 40% of the flat-spectrum radio quasars (FSRQs) in the radio, soft X-ray, and hard X-ray selected samples are still below the gamma ray detection limit even after integrating 27 months of Fermi-LAT data. The radio to sub-millimetre spectral slope of blazars is quite flat, with [alpha] approximately 0 up to about 70 GHz, above which it steepens to [alpha] approximately -0.65. BL Lacs have significantly flatter spectra than FSRQs at higher frequencies. The distribution of the rest-frame synchrotron peak frequency (v(sup IC) (sub (PEAK)), ranges from 10(sup 21) to 10(sup 22) HZ. The distribution of the rest-frame synchrotron peak frequency (v(sup s)(sub peak)) in the spectral energy distribution (SED) of FSRQs is the same in all the blazar samples with (v(sup s)(sub peak) = 10(sup 13:1 plus or minus 0.1) Hz, while the mean inverse-Compton peak frequency,(v(sup IC)(sub peak) ranges from 10(sup 21) to 10(sup 22) Hz. The distributions of v(sup S)(sub peak) and of v(sup IC)(sub peak) of BL Lacs are much broader and are shifted to higher energies than those of FSRQs; their shapes strongly depend on the selection method. The Compton dominance of blazars ranges from less than 0.2 to nearly 100, with only FSRQs reaching values larger than about 3. Its distribution is broad and depends strongly on the selection method, with gamma-ray selected blazars peaking at approximately 7 or more, and radio-selected blazars at values close to 1, thus implying that the common assumption that the blazar power budget is largely dominated by high-energy emission is a selection effect. A comparison of our multi-frequency data with theoretical predictions shows that simple homogeneous SSC models cannot explain the simultaneous SEDs of most of the gamma-ray detected blazars in all samples. The SED of the blazars that were not detected by Fermi-LAT may instead be consistent with SSC emission. Our data challenge the correlation between bolometric luminosity and v(sup S)(sub peak) predicted by the blazar sequence.

Giommi, P.↗
NASA NTRS2004

Atmospheric Trace Gas Abundances and Stable Isotope Ratios via IR-LIF

We propose to develop new technologies with support provided by PIDDP that will enable the in situ measurements of abundances and stable isotope ratios in important radiatively and biogenically active gases such as carbon dioxide, carbon monoxide, water, methane, nitrous oxide, and hydrogen sulfide to very high precision (0.1 per mil or better for the isotopic ratios, for example). Such measurements, impossible at present, could provide pivotal new constraints on the global (bio)geochemical budgets of these critical species, and could also be used to examine the dynamics of atmospheric transport on Mars, Titan, and other solar system bodies. We believe the combination of solid state light sources with imaging of the IR laser induced fluorescence (IR-LIF) via newly available detector arrays will make such in situ measurements possible for the first time. Even under ambient terrestrial conditions, the LIF yield from vibrational excitation of species such as water and carbon dioxide should produce emission measures well in excess of ten billion photons/sec from samples volumes of order 1 c.c. These count rates can, in principle, yield detection limits into the sub-ppt range that are required for the in situ isotopic study of atmospheric trace gases. While promising, such technologies are relatively immature, but developing rapidly, and there are a great many uncertainties regarding their applicability to in situ IR-LIF planetary studies. We therefore feel PIDDP support will be critical to developing these new tools, and propose a three-year program to combine microchip near-IR lasers with low background detection axes and state-of-the-art HgCdTe detectors developed for astronomical spectroscopy to investigate the sensitivity of IR-LIF under realistic planetary conditions, to optimize the optical pumping and filtering schemes for important species, and to apply the spectrometer to the non-destructive measurement of stable isotopes in a variety of test samples. These studies form the necessary precursors to the development of compact, lightweight stable isotope/trace gas sensors for future planetary missions.

Blake, Geoffrey A.↗
NASA NTRS1989

The measurement of trace elements in interplanetary dust and cometary particles by ultra-high sensitivity INAA

Today the major elemental composition of interplanetary dust particles (IDPs) is routinely determined in many laboratories. These and mineralogical studies have revealed the presence of at least two major types of IDPs, chondritic and refractory. Preliminary results of a successful attempt to determine abundances of a large suite of trace elements from both chondritic and refractory IDPs are reported. The analytical procedure can be used in the grain-by-grain analysis of returned cometary samples. Chondritic and refractory IDPs are characterized by standard scanning electron microscopy and energy dispersive x ray spectroscopy (SEM-EDX) techniques. With this system, detection limits for many elements are well below picogram levels, and some approach femtogram levels. This technique is non-destructive, although some sample handling is required, so particles can be analyzed by other techniques after instrument neutron activation analysis (INAA) is completed. Data is presently being reduced from the analyses of 7 IDPs. These are U2015E10, U2015F1, W7029-A2, W7029-A3, W7013A8, LACl (all chondritic) and 705 (refractory). So far, 17 different major and trace elements were detected and measured in these particles, including rare earths and some very volatile elements (Br and Zn).

Zolensky, M. E.↗
NASA NTRS2001

Beagle 2: The Next Exobiology Mission to Mars

Beagle 2 is a 60 kg probe (with a 30 kg lander) developed in the United Kingdom for inclusion on the European Space Agency's 2003 Mars Express. Beagle 2 will deliver to the Martian surface a payload which consists of a high percentage of science instruments to landed spacecraft mass. Beagle 2 will be launched in June, 2003 with Mars Express on a Soyuz-Fregat rocket from the Baikonur Cosmodrome in Kazakhstan. Beagle 2 will land on Mars on December 26, 2003 in the Isidis Planitia basin (approximately 10 degrees N and 275 degrees W), a large sedimentary basin that overlies the boundary between ancient highlands and northern plains. Isidis Planitia, the third largest basin on Mars, which is possibly filled with sediment deposited at the bottom of long-standing lakes or seas, offers an ideal environment for preserving traces of life. Beagle 2 was developed to search for organic material and other volatiles on and below the surface of Mars in addition to the study of the inorganic chemistry and mineralogy. Beagle 2 will utilize a mechanical mole and grinder to obtain samples from below the surface, under rocks and inside rocks. A pair of stereo cameras will image the landing site along with a microscope for examination of surface and rock samples. Analyses will include both rock and soil samples at various wavelengths, X-ray spectrometer and Mossbauer spectrometer as well as a search for organics and other light element species (e.g. carbonates and water) and measurement of their isotopic compositions. Beagle 2 has as its focus the goal of establishing whether evidence for life existed in the past on Mars at the Isidis Planitia site or at least establishing if the conditions were ever suitable. Carbonates and organic components were first recognized as existing on Mars when they were found in the Martian meteorite Nakhla. Romanek et al showed the carbonates in ALH84001 were formed at low temperatures. McKay et al noted possible evidence of early life on Mars within the ALH84001 meteorite. Thomas-Keprta et al showed the magnetite biomarkers in ALH84001's carbonates are indistinguishable from those formed by magnetotactic bacteria found on Earth. Gibson et al showed there was significant evidence for liquid water and biogenic products present on Mars across a 3.9 billion year period. A mechanical arm (PAW) operates from the lander and is used for science operations along with sample acquisition. Instruments attached to the PAW include: stereo cameras, Mossbauer instrument, X-ray fluorescence instrument, microscope, environmental sensors, rock corer/grinder, a spoon, mirror, brushes, a mole attachment for acquisition of subsurface to depths of 1 to 2 meters and an illumination device. Each camera has 14 filters which have been optimized for mineralogy composition, dust and water vapor detection. The microscope's camera is designed for viewing the size and shape of dust particles, rock surfaces, microfossils, and characteristics of the samples prior to introduction into the gas analysis package (GAP). The camera has a resolution of 4 microns/pixel, features four color capability (red, green, blue and UV (ultraviolet) fluoresence), a depth of focus of 40 micrometers and translation stage of +3 millimeters. The heart of the Beagle 2's life detection package is the gas analysis package (GAP), which consists of a mass spectrometer with collectors at fixed masses for precise isotopic ratio measurements and voltage scanning for spectral analysis. Primary aim of the GAP is to search for the presence of bulk constituents, individual species, and isotopic fractionations for both extinct and extent life along with studying the low-temperature geochemistry of the hydrogen, carbon, nitrogen and oxygen components on Mars from both the surface and atmosphere. GAP is a magnetic sector mass spectrometer with the range of 1 to 140 amu which can be operated in both the static and dynamic modes. A triple Faraday collector array will be used for C, N and O ratios along with a double Faraday array for H/D. Pulse counting electron multiplier will be utilized for noble gases and selected organics. Anticipated detection limits are at the picomole level for operation in the static mode of operation and high precision isotopic measurements will be made in the dynamic mode. Sample processing and preparation system consists of reaction vessels along with references. Sample ovens capable of being heated are attached to the manifold for sample combustion. Surface, subsurface materials and interior rock specimens will be combusted in pure oxygen gas at various temperature intervals to release organic matter and volatiles. Combustion process will permit detection of all forms and all atoms of carbon present in the samples. A chemical processing system is capable of a variety of conversion reactions. Gases are manipulated either by cryogenic or chemical reactions and passed through the gas handling portion of the vacuum system. There are two modes of operation: quantitative analysis and precise isotopic measurements. Additional information is contained in the original extended abstract.

Gibson, Everett K., Jr.↗
NASA NTRS2016

The Sample at Mars Analysis (SAM) Detections of CO2 and CO in Sedimentary Material from Gale Crater, Mars: Implications for the Presence of Organic Carbon and Microbial Habitability on Mars

Sedimentary rock samples heated to 860 C in the SAM instrument evolved CO2 and CO indicating the presence of organic-carbon(C) in Gale Crater materials. Martian or exogenous (meteoritic, interplanetary dust) CO2 and CO could be derived from combustion of simple organics (less than 300 C), complex refractory organics/amorphous carbon (300-600 C), and/or magmatic carbon (greater than 600 C) as result of thermal decomposition of Gale Crater perchlorates, and sulfates present that produce O2. Oxidized organic compounds could also evolve CO2 and CO over broad temperature range (150 to 800 C) and such organics are expected on Mars via exogenous sources. Alternatively, organic-C could also have been oxidized to carboxylic acids [e.g, mellitic acid (RCOOH), acetate (CH3CO2(-)), and oxalates ((2)C2O4(-))] by oxidative radiolytic weathering, or other oxidation processes. The presence of oxidized organics is consistent with the limited detection of reduced organic-C phases by the SAM-gas chromatography. Organic-C content as determined by CO2 and CO contents could range between 800 and 2400 ppm C indicating that substantial organic-C component is present in Gale Crater. There are contributions from SAM background however, even in worse case scenarios, this would only account for as much as half of the detected CO2 and CO. Nevertheless, if organic-C levels were assumed to have existed in a reduced form on ancient Mars and this was bioavailable C, then less than 1% of C in Gale Crater sediments could have supported an exclusively heterotrophic microbial population of 1 x 10(exp 5) cells/g sediment (assumes 9 x 10(exp -7) microgram/cell and 0.5 micrograms C/microgram cell). While other essential nutrients (e.g., S and P) could be limiting, organic-C contents, may have been sufficient to support limited heterotrophic microbial populations on ancient Mars.

Sutter, Brad↗
NASA NTRS2016

The Sample at Mars Analysis (SAM) Detections of CO2 and CO in Sedimentary Material from Gale Crater, Mars: Implications for the Presence of Organic Carbon and Microbial Habitability on Mars

Sedimentary rock samples heated to 860 degrees Centigrade in the SAM (Sample at Mars) instrument evolved CO2 and CO indicating the presence of organic-carbon(C) in Gale Crater materials. Martian or exogenous (meteoritic, interplanetary dust) CO2 and CO could be derived from combustion of simple organics (less than 300 degrees Centigrade), complex refractory organics/amorphous carbon (300-600 degrees Centigrade), and/or magmatic carbon (greater than 600 degrees Centigrade) as result of thermal decomposition of Gale Crater perchlorates, and sulfates present that produce O2. Oxidized organic compounds could also evolve CO2 and CO over broad temperature range (150 to 800 degrees Centigrade) and such organics are expected on Mars via exogenous sources. Alternatively, organic-C could also have been oxidized to carboxylic acids [e.g, mellitic acid (RCOOH), acetate (CH3CO2-), and oxalates (C2O42-)] by oxidative radiolytic weathering, or other oxidation processes. The presence of oxidized organics is consistent with the limited detection of reduced organic-C phases by the SAM-gas chromatography. Organic-C content as determined by CO2 and CO contents could range between 800 and 2400 parts per million C indicating that substantial organic-C component is present in Gale Crater. There are contributions from SAM background however, even in worst-case scenarios, this would only account for as much as half of the detected CO2 and CO. Nevertheless, if organic-C levels were assumed to have existed in a reduced form on ancient Mars and this was bioavailable C, then less than 1 percent of C in Gale Crater sediments could have supported an exclusively heterotrophic microbial population of 1 by 10 (sup 5) cells per gram sediment (assumes 9 by 10 (sup -7) microgram per cell and 0.5 micrograms C per microgram cell). While other essential nutrients (e.g., S and P) could be limiting, organic-C contents, may have been sufficient to support limited heterotrophic microbial populations on ancient Mars.

Sutter, Brad↗
NASA NTRS2009

Finding ExoEarths: The Problem of Exozodical Dust

Dust coming from asteroids and comets will strongly affect direct imaging and characterization of terrestrial planets in the Habitable Zones of nearby stars. Such dust in the Solar System is called the zodiacal dust. Higher levels of similar dust are seen around many nearby stars, confined in disks called debris disks. Future high-contrast images of an Earth-like exoplanet (or "exoEarth") will very likely be background-limited by light scattered of both local Solar System zodiacal dust and circumstellar dust in the extrasolar system (exozodiacal dust). Clumps in the exozodiacal dust, which are expected in planet-hosting systems,, may also be a source of confusion. Here we discuss the problems associated with direct observations of an Earth-like planet in the presence of unknown levels of exozodiacal dust. Basic formulae showing the effect of zodiacal and exozodiacal dust on exoEarth direct imaging will be presented, and performance estimates for some future mission concepts summarized. Current detection limits for debris dust and future prospects for sensitive exozodiacal dust observations will also be discussed. Finally, we highlight a few additional problems relating to exozodiacal dust that have yet to be solved.

Roberge, Aki↗
NASA NTRS1979

Launch vehicle effluent measurements during the September 5, 1977, Titan 3 launch at Air Force eastern test range

Airborne effluent measurements and cloud physical behavior data are presented. The monitoring program included airborne effluent measurements in situ in the launch cloud, visible and infrared photography of cloud growth and physical behavior, and limited surface collection of rain samples. Effluent measurements included concentrations of HCl, Cl2, NO, nitric oxide, and particles as a function of time in the exhaust cloud. In situ particle mass concentration and number density were measured as a function of time and size in the range of 0.05 micron m to 30 micron m diameter. Measurement results were similar to those of previous launch monitorings. Maximum HCl and nitric oxide concentrations of Cl2 were maximum about 2 minutes after launch and by 10 to 15 minutes had decayed to less than 10 ppb (detection limit). Particle measurements showed most of the particles present to be below about 3-micron m diameter. Postlaunch analyses of collected particle samples showed significant amounts of Al (some cases Cl) from about 3-micron m to 0.04-micron m diameter.

Wornom, D. E.↗
NASA NTRSDate not supplied

High Sensitive and Low Power Nanosensors for Space and Terrestrial Applications

Nanotechnology offers the ability to work at the molecular level, atom by atom, to create large structures with fundamentally new molecular organization. It is essentially concerned with materials, devices, and systems whose structures and components exhibit novel and significantly improved physical, chemical and biological properties, phenomena, and process control due to their nanoscale size. A nanosensor technology has been developed at NASA Ames using nanostructure, single walled carbon nanotubes (SWNTs). The nanosensors have achieved low detection limit of chemicals in the concentration range of ppm to ppb. Due to large surface area, low surface energy barrier and high thermal and mechanical stability, nanostructured chemical sensors offer higher sensitivity, lower power consumption and a more robust solution than most state-of-the-art systems making them attractive for space and terrestrial applications. An example of a sensor module, the first space flown nano device, will be introduced in this presentation. Such sensors have drawn attention from space community for global weather monitoring, space exploration, life search in the universe, and launch pad fuel leak detection and in-flight cabin air and life support system monitoring, and engine operation monitoring. Additionally, the wireless capability of such sensors can be leveraged to network mobile and fixed-base detection and warning systems for civilian population centers, military bases and battlefields, as well as other high-value or high-risk assets and areas in industry.

Jing Li↗
NASA NTRS2006

Chemical Characterization and Thermal Stressing Studies of Perfluorohexane Fluids for Space-Based Applications

Perfluorohexane (PFH), C6F14, is a perfluorocarbon fluid. Several PFH fluids with different isomer concentrations were evaluated for use in an upcoming NASA space experiment. Samples tested included two commercially obtained high-purity n-perfluorohexane (n-PFH) fluids and a technical grade mixture of C6F14 branched and linear isomers (FC-72(TradeMark)). These fluids were evaluated for exact chemical composition, impurity purity and high temperature degradation behavior (pyrolysis). Our investigation involved simulated thermal stressing studies of PFH fluids under conditions likely to occur in the event of an atmospheric breach within the International Space Station (ISS) and subsequent exposure of the vapors to the high temperature and catalyst present in its Trace Contaminant Control Subsystem (TCCS). Exposure to temperatures in the temperature range of 200-450 C in an inert or oxidizing atmosphere, with and without the presence of catalyst was investigated. The most aggressive conditions studied were exposure of PFH vapors to 450 C in air and in the presence of TCCS (palladium) catalyst. Gas chromatography-mass spectrometry (GC-MS) and gas chromatography (GC) analyses were conducted on the perfluorohexane samples before and after pyrolysis. The FC-72 and n-PFH samples showed no significant degradation following pyrolysis even under the most aggressive study conditions. Some trace level impurities associated with the PFH samples such as linear perfluorocarbon monohydrides or monoiodides were destroyed by pyrolysis at the upper limit. Other trace level impurities such as olefinic or cycloolefinic perfluorocarbons were converted into oxidation products by pyrolysis. The purity of PFH following pyrolysis actually increased slightly as a consequence since these trace contaminants were effectively scrubbed from the samples. However, since the initial concentrations of the thermally-impacted impurities were so low, the net effect was trivial. A potential byproduct of exposure of perfluorohexane fluids to high temperatures is the production of perfluoroisobutene (PFiB), which is extremely toxic. An ultra-high sensitivity PFiB-specific analysis based on GC-MS with negative ion chemical ionization (NICI) detection was used to evaluate the samples following thermal stressing. The perfluorohexanes examined here under conditions reflective of the ISS TCCS environment showed no signs of PFiB production with an analytical detection limit of 10 part per billion (ppb v/v).

Arnold, William A.↗
NASA NTRS2010

Demonstration of on Sky Contrast Improvement Using the Modified Gerchberg-Saxton Algorithm at the Palomar Observatory

We have successfully demonstrated significant improvements in the high contrast detection limit of the Well-Corrected Subaperture (WCS) using the Autonomous Phase Retrieval Calibration (APRC) software package developed at the Jet Propulsion Laboratory (JPL) for the Palomar adaptive optics instrument (PALAO). APRC utilizes the Modified Gerchberg-Saxton (MGS) wavefront sensing algorithm, also developed at JPL. The WCS delivers such excellent correction of the atmosphere that non-common path (NCP) wavefront errors not sensed by PALAO but present at the coronagraphic image plane begin to factor heavily as a limit to contrast. We have implemented the APRC program to reduce these NCP wavefront errors from 110 nm to 35 nm (rms) in the lab, and we have extended these exceptional results to targets on the sky for the first time, leading to a significant suppression of speckle noise. Consequently we now report a contrast level of very nearly 1x10(exp -4) at separations of 2 lambda/D before the data is post processed. We describe here the major components of our instrument, the work done to improve the NCP wavefront errors, and the ensuing excellent on sky results, including the detection of the three exoplanets orbiting the star HR8799.

mgs↗
NASA NTRS1985

An upper limit for the absorption cross section of the oxygen C 3 Delta u - a 1 Delta g transition

Frederick and Cicerone (1985) have proposed that photodissociation of O2 (a 1 Delta g) by the process O2 (a 1 Delta g) + h-nu + O2 (C 3 Delta u) to O(3 P) + O(3 P) may be a major source of odd oxygen in the upper stratosphere and mesosphere. They argued that, since the process is forbidden only by change in the spin multiplicity, it might have been a cross section intermediate between a fully allowed and a strictly forbidden transition, i.e., 10 to the -20th to 10 to the -19th sq cm near 250 nm. In order to test this proposal, absorption by O2 (a 1 Delta g) has been measured in the 190-290 nm wavelength region. No absorption above the detection limit could be observed for O2 (a 1 Delta g) concentrations of (4-7) x 10 to the 15th/cu cm. An upper limit of 8 x 10 to the -22 sq cm was calculated for the cross section.

Simonaitis, R.↗
NASA NTRS2010

In Situ and Lidar Observations of Tropopause Subvisible Cirrus Clouds During TC4

During the Tropical Composition, Clouds, and Climate Coupling (TC4) experiment in July-August 2007, the NASA WB-57F and ER-2 aircraft made coordinated flights through a tropopause subvisible cirrus (SVC) layer off the Pacific Coast of Central America. The ER-2 aircraft was equipped with a remote sensing payload that included the cloud physics lidar (CPL). The WB-57F payload included cloud microphysical and trace gas measurements, and the aircraft made four vertical profiles through the SVC layer shortly after the ER-2 flew over. The in situ and remotely sensed data are used to quantify the meteorological and microphysical properties of the SVC layer, and these data are compared to the limited set of SVC measurements that have previously been made. It is found that the layer encountered was particularly tenuous, with optical depths (tau) between about 10(exp -4) and 10(exp -3). From the in situ and other meteorological data, radiative heating rate perturbations of approx.0.05-0.1 K/day are calculated. These heating rates are smaller than previous estimates for tropopause SVC, consistent with the smaller tau in the present study. Coverage statistics based on CPL data from other TC4 flights indicate that this cloud was not an outlier among the sampled population. SVC with properties similar to the one presented here are below the detection limit of space \based lidars such as CALIPSO, and a comparison with the TC4 statistics suggests that a majority (>50%) of tropopause SVC (with tau < 0.01) could be unaccounted for in studies using CALIPSO data.

Davis, Sean↗
NASA NTRS2013

Coordinated Analyses of Antarctic Sediments as Mars Analog Materials Using Reflectance Spectroscopy and Current Flight-Like Instruments for CheMin, SAM and MOMA

Coordinated analyses of mineralogy and chemistry of sediments from the Antarctic Dry Valleys illustrate how data obtained using flight-ready technology of current NASA and ESA missions can be combined for greater understanding of the samples. Mineralogy was measured by X-ray diffraction (XRD) and visible/ near-infrared (VNIR) reflectance spectroscopy. Chemical analyses utilized a quadrupole mass spectrometer (QMS) to perform pyrolysis-evolved gas analysis (EGA) and gas chromatography-mass spectrometry (GC/MS) both with and without derivatization, as well as laser desorption-mass spectrometry (LD/MS) techniques. These analyses are designed to demonstrate some of the capabilities of near-term landed Mars missions, to provide ground truthing of VNIR reflectance data acquired from orbit by the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) on MRO and to provide detection limits for surface- operated instruments: the Chemistry and Mineralogy (CheMin) and Sample Analysis at Mars (SAM) instrument suites onboard Mars Science Laboratory (MSL) and the Mars Organic Molecule Analyzer (MOMA) onboard ExoMars-2018. The new data from this study are compared with previous analyses of the sediments performed with other techniques. Tremolite was found in the oxic region samples for the first time using the CheMin-like XRD instrument. The NIR spectral features of tremolite are consistent with those observed in these samples. Although the tremolite bands are weak in spectra of these samples, spectral features near 2.32 and 2.39 micrometers could be detected by CRISM if tremolite is present on the martian surface. Allophane was found to be a good match to weak NIR features at 1.37-1.41, 1.92, and 2.19 micrometers in spectra of the oxic region sediments and is a common component of immature volcanic soils. Biogenic methane was found to be associated with calcite in the oxic region samples by the SAM/EGA instrument and a phosphoric acid derivative was found in the anoxic region sample using the SAM/MTBSTFA technique.

Mars↗
NASA NTRS1994

The luminosity function at the end of the main sequence: Results of a deep, large-area, CCD survey for cool dwarfs

The luminosity function at the end of the main sequence is determined from V, R, and I data taken by the charge coupled devices (CCD)/Transit Instrument, a dedicated telescope surveying an 8.25 min wide strip of sky centered at delta = +28 deg, thus sampling Galactic latitudes of +90 deg down to -35 deg. A selection of 133 objects chosen via R - I and V - I colors has been observed spectroscopically at the 4.5 m Multiple Mirror Telescope to assess contributions by giants and subdwarfs and to verify that the reddest targets are objects of extremely late spectral class. Eighteen dwarfs of type M6 or later have been discovered, with the latest being of type M8.5. Data used for the determination of the luminosity function cover 27.3 sq. deg down to a completeness limit of R = 19.0. This luminosity function, computed at V, I, and bolometric magnitudes, shows an increase at the lowest luminosities, corresponding to spectral types later than M6- an effect suggested in earlier work by Reid & Gilmore and Legget & Hawkins. When the luminosity function is segregated into north Galactic and south Galactic portions, it is found that the upturn at faint magnitudes exists only in the southern sample. In fact, no dwarfs with M(sub I) is greater than or equal to 12.0 are found within the limiting volume of the 19.4 sq deg northern sample, in stark contrast to the smaller 7.9 sq deg area at southerly latitudes where seven such dwarfs are found. This fact, combined with the fact that the Sun is located approximately 10-40 pc north of the midplane, suggests that the latest dwarfs are part of a young population with a scale height much smaller than the 350 pc value generally adopted for other M dwarfs. These objects comprise a young population either because the lower metallicities prevelant at earlier epochs inhibited the formation of late M dwarfs or because the older counterparts of this population have cooled beyond current detection limits. The latter scenario would hold if these late-type M dwarfs are substellar. The luminosity function data together with an empirical derivation of the mass-luminosity relation (from Henry & McCarthy) are used to compute a mass function independent of theory. This mass function increases toward the end of the main sequence, but the observed density of M dwarfs is still insufficient to account for the missing mass. If the increases seen in the luminosity and mass functions are indicative of a large, unseen, substellar population, brown dwarfs may yet add significantly to the mass of the Galaxy.

Kirkpatrick, J. Davy↗
NASA NTRSDate not supplied

Statistical Classification of Biosignature Information using Multiple Instrument Observations

The accurate identification of biosignatures (indications of life) from data taken from remote or in situ planetary exploration is one of the most important challenges in astrobiology, the interdisciplinary field examining habitability and the potential for extraterrestrial life. This study employs machine learning algorithms to optimize the identification of biosignatures, with an emphasis on those which are agnostic to a specific biochemical basis. We exploit the wealth of terrestrial data available from biogenic and abiogenic systems to enhance efficient feature prioritization. Our dataset, pulled from public databases and laboratory recorded measurements, includes elemental abundance, isotopic fractionation, and VNIR/Raman spectra The data curation process included standardization for detection limits and ranges. Subsequent feature extraction yielded detailed inputs for machine learning, including combinations of elemental content, isotopic ratios, and parameters of spectral peaks and troughs. Feature significance was evaluated across diverse machine learning methodologies, such as k-nearest neighbors, logistic regression, Random Forest, support vector machines, and Gaussian Naïve Bayes, along with a combined voting classifier. We utilized Receiver Operating Characteristic Area Under the Curve (ROC AUC) across 2,000 50% test-train splits as a robust metric of model performance. Results revealed a promising ROC AUC of 0.853 for the combined voting classifier. Removing elemental abundance data notably reduced model accuracy (13% decrease in AUC), highlighting its critical role in biosignature detection. Several other individual data features exhibited significance within their respective data types, offering additional granularity. This research fortifies the relevance of machine learning to astrobiology, potentially enhancing life detection missions by allowing algorithmic prioritization of high-interest samples for further investigation. Future work will refine data standardization, expand the dataset to include more terrestrial systems, and incorporate convolutional neural networks for spectral feature extraction. The potential for public data sharing is also under exploration, reinforcing our commitment to collective scientific advancement.

Statistical↗
NASA NTRS1994

Measurement of atmospheric OH by titration of near-IR fluorescent dyes

Recent research has shown that certain polymethine dyes can be detected at ultratrace levels (greater than or equal to 6x10(exp -14) M) in solution by fluorimetry. These detection limits are possible because of the inherent sensitivity of fluorescence techniques, because the dyes fluoresce in the near infrared region where background interference is negligible, and because powerful infrared diode lasers are now available to improve the signal to noise ratio. Other work has shown that the hydroxyl radical destroys the ability of polymethine dyes to fluoresce. These observations form the basis for a new hydroxyl radical detector that is essentially a fluorometric titrator. Theoretically, the detector should show an acceptable sensitivity and response time. Assuming that the atmospheric HO concentration is about 10(exp -11) moles m(exp -3) (i.e. 10(exp 6) molecules cm(exp -3)), then 10 L of air 'titrated' with 20 mL of 10(exp -11) M dye solution (an easily detected concentration) should result in a drop in the fluorescent signal of 50 percent - a readily detectable change. At a flow rate of 3 L min(exp -1) the sampling time would be 3 minutes. The biggest potential problem is selectivity: other oxidants may also cause the fluorescence signal to be lost. The chemistry of polymethine dyes has not been studied in detail and so no quantitative data are available. However, a survey of the literature suggests that in general HO should react up to six orders of magnitude faster than HO2 and other radicals such as RO2 and RO. It should also react much more rapidly than H2O2 and O3. Thus it may be possible to discriminate kinetically against potential interfering substances. It was shown in the laboratory that 10(exp -4) M H2O2 has little effect on the absorption spectrum of the dye IR125 over a period of hours but that the band at 780 nm is slowly lost in water over a period of days even under argon in the dark. By contrast, DMSO solutions of IR125 are stable.

Betterton, Eric A.↗