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At least 181 records · Page 10

A model of the origin of the Jovian ring

Assuming that the micron-sized particles making up the bright Jovian ring are fragments of erosive collisions between micrometeoroid projectiles and large parent bodies, a physical model of the ring is calculated. This leads to a well-defined size distribution for the ejecta, whose optical properties can be compared with observation. The (most likely silicate) ejecta material maximum diameter is estimated to be 0.1 micron, and most likely the result of Io volcanic activity. The impact model's determination of ejecta size distribution in turn determines the structure of the ring, with the largest ejecta forming the bright ring, medium-sized ejecta forming a disk that extends to the Jovian atmosphere, and small ejecta forming a faint halo whose structure is dominated by electromagnetic forces.

Gruen, E.↗

Carbon-rich Chondritic Clast PV1 from the Plainview H-chondrite Regolith Formation from H3 Chondrite Material by Possible Cometary Impact

Chondritic clast PV1 from the Plainview H-chondrite regolith breccia is a subrounded, 5-mm diameter unequilibrated chondritic fragment that contains 13 wt% C occurring mainly within irregularly shaped 30-400-micron-size opaque patches. The clast formed from H3 chondrite material as indicated by the mean apparent chondrule diameter (310 micron vs. approximately 300 micron in H3 chondrites), the mean Mg-normalized refractory lithophile abundance ratio (1.00 +/- 0.09 XH), the previously determined 0-isotopic composition (Delta O-17 = 0.66% vs. 0.68 +/- 0.04%0 in H3 chondrites and 0.73 +/- 0.09% in H4-6 chondrites), the heterogeneous olivine compositions in grain cores (with a minimum range of Fal-19), and the presence of glass in some chondrules. Although the clast lacks the fine-grained, ferroan silicate matrix material present in type 3 ordinary chondrites, PV1 contains objects that appear to be recrystallized clumps of matrix material. Similarly, the apparent dearth of radial pyroxene and cryptocrystalline chondrules in PV1 is accounted for by the presence of some recrystallized fragments of these chondrule textural types. All of the chondrules in PV1 are interfused indicating that temperatures must have briefly reached approximately 1100C (the approximate solidus temperature of H-chondrite silicate). The most likely source of this heating was by an impact. Some metal was lost during impact heating as indicated by the moderately low abundance of metallic Fe-Ni in PV1 (approximately 14 wt%) compared to that in mean H chondrites (approximately 18 wt%). The carbon enrichment of the clast may have resulted from a second impact event, one involving a cometary projectile, possibly a Jupiter-family comet. As the clast cooled, it experienced hydrothermal alteration at low water/rock ratios as evidenced by the thick rims of ferroan olivine around low-FeO olivine cores. The C-rich chondritic clast was later incorporated into the H-chondrite parent-body regolith and extensively fractured and faulted.

Rubin, Alan E.↗

Measurements and predictions of a liquid spray from an air-assist nozzle

Droplet size and gas velocity were measured in a water spray using a two-component Phase/Doppler Particle Analyzer. A complete set of measurements was obtained at axial locations from 5 to 50 cm downstream of the nozzle. The nozzle used was a simple axisymmetric air-assist nozzle. The sprays produced, using the atomizer, were extremely fine. Sauter mean diameters were less than 20 microns at all locations. Measurements were obtained for droplets ranging from 1 to 50 microns. The gas phase was seeded with micron sized droplets, and droplets having diameters of 1.4 microns and less were used to represent gas-phase properties. Measurements were compared with predictions from a multi-phase computer model. Initial conditions for the model were taken from measurements at 5 cm downstream. Predictions for both the gas phase and the droplets showed relatively good agreement with the measurements.

Bulzan, Daniel L.↗

Measurements and predictions of a liquid spray from an air-assist nozzle

Droplet size and gas velocity were measured in a water spray using a two-component Phase/Doppler Particle Analyzer. A complete set of measurements was obtained at axial locations from 5 to 50 cm downstream of the nozzle. The nozzle used was a simple axisymmetric air-assist nozzle. The sprays produced, using the atomizer, were extremely fine. Sauter mean diameters were less than 20 microns at all locations. Measurements were obtained for droplets ranging from 1 to 50 microns. The gas phase was seeded with micron sized droplets, and droplets having diameters of 1.4 microns and less were used to represent gas-phase properties. Measurements were compared with predictions from a multi-phase computer model. Initial conditions for the model were taken from measurements at 5 cm downstream. Predictions for both the gas phase and the droplets showed relatively good agreement with the measurements.

Bulzan, Daniel L.↗

Nanoscale Mg–B via Surfactant Ball Milling of MgB 2 : Morphology, Composition, and Improved Hydrogen Storage Properties

Metal borides have attracted the attention of researchers due to their useful physical properties and unique ability to form high hydrogen-capacity metal borohydrides. We demonstrate improved hydrogen storage properties of a nanoscale Mg–B material made by surfactant ball milling MgB 2 in a mixture of heptane, oleic acid, and oleylamine. Transmission electron microscopy data show that Mg–B nanoplatelets are produced with sizes ranging from 5 to 50 nm, which agglomerate upon ethanol washing to produce an agglomerated nanoscale Mg–B material of micron-sized particles with some surfactant still remaining. X-ray diffraction measurements reveal a two-component material where 32% of the solid is a strained crystalline solid maintaining the hexagonal structure with the remainder being amorphous. Fourier transform infrared shows that the oleate binds in a “bridge-bonding” fashion preferentially to magnesium rather than boron, which is confirmed by density functional theory calculations. The Mg–B nanoscale material is deficient in boron relative to bulk MgB 2 with a Mg–B ratio of ~1:0.75. The nanoscale MgB 0.75 material has a disrupted B–B ring network as indicated by X-ray absorption measurements. Hydrogenation experiments at 700 bar and 280 °C show that it partially hydrogenates at temperatures 100 °C below the threshold for bulk MgB 2 hydrogenation. In addition, upon heating to 200 °C, the H–H bond-breaking ability increases ~10-fold according to hydrogen–deuterium exchange experiments due to desorption of oleate at the surface. This behavior would make the nanoscale Mg–B material useful as an additive where rapid H–H bond breaking is needed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Three Paradigms of Lunar Regolith Evolution

Integration of diverse datasets on the Moon may render some paradigms of lunar science either better-defended or vulnerable. We will consider three paradigms commonly used for understanding the processes of lunar regolith evolution in light of new and accumulated data. Our premise is that all data-sets should converge to a single interpretation if a concept or model is to be accepted as a paradigm. If a convergence is lacking, the paradigm needs fresh scrutiny. SteadyState: Lunar regolith evolution is currently understood in terms of comminution, agglutination, and replenishment as described by McKay and coworkers). Briefly, the model envisages continued micrometeoritic bombardment to comminute exposed soil particles to finer sizes while continued agglutination consumes finer sizes to produce larger constructional particles. Eventually, a balance between these two opposing processes achieves a steady state; soils at steady state maintain their mean grain size (M(sub z)). Episodic higher-energy impacts excavate fresh coarse material from below the soil cover, disturb the steady state, and restart the process to achieve a new steady state. It follows that the thickness of the regolith at any site would control the frequency of replenishment; indeed, the thickness of the regolith at Apollo landing sites was predicted by McKay et al. from the average M(sub z) of local soils. However, replenishment may come also from disintegrating boulders and cobbles at the lunar surface, and rates of comminution and agglutination may depend on the properties of target material. Regression between M(sub z) and I(sub s)/Fe(sup 0) (a measure of maturity or total surface exposure) of Apollo soils at different sites shows the following relations and estimated M(sub z) at a high maturity of I(sub s)/Fe(sup 0)= 100. It is possible that Apollo 12 and 15 sites have the thickest regolith and the Apollo 16 site has the thinnest. It is also possible that Apollo 12 and 15 basalts are comminuted faster than Apollo 16 highland rocks and Apollo 14 and 17 soils are products of mixed parentage. If a soil becomes continually finer as it matures until agglutination catches up, and if comminution is differential-dependent on the physical properties of the constituents, then the composition of the bulk soil has to match the composition of some "fulcrum" grain size fraction, say X Grain size fractions >X and <X will complement each other; their mass balance is the bulk soil. It appears that the 10-20-micron size fraction may be the fulcrum. In general, trace-element chemistry and IR reflectance spectra of this size fraction are closest to that of the bulk soil, regardless of maturity that is surprising. Disaggregated products of regolith breccias may also show similar relationships. If the 10-20 gm is the fulcrum (i.e., X as above) for many soil properties (e.g., major element composition, FMR, solar-wind-implanted elements), then this may be the ultimate mean grain size of lunar soils at steady state. However, different properties of soils may find steady states at different grain size fractions. The steady state of solar-wind-implanted elements, on the other hand, will climb up the grain-size scale as agglutinates transfer surface-correlated components into volume correlated components until a saturation level is reached or the rates of replenishment and implantation become equal. The same will be the case with vapor-deposited reduced metals as they too are incorporated inside constructional particles. Properties that are directly affected by soil-maturation processes will thus have different pathways of achieving steady states. Maturity, i.e., cumulative surface exposure, of lunar soils is best quantified by the amount of nanophase superparamagnetic Fe(sup 0) (np-Fe(sup 0)) normalized to Fe content (=I(sub s)/Fe(sup 0). The majority consensus (paradigm?) for the production of np-Fe(sup 0) is associated with the production of agglutinates. Because large doses of solar-wind H are implanted in all lunar soils upon exposure, any melting (e.g., during agglutinate production) triggers a chemical reduction of Fe-bearing minerals resulting in np-Fe(sup 0) production. The quantity of np-Fe(sup 0) is thus dependent on melting events, (i.e., exposure), and limited by the Fe content of the soil. All freshly produced np-Fe(sup 0) resides in agglutinitic glass, as new TEM images show. Apparently, the correction procedure developed by Lucey et al. to estimate the Fe content of the lunar surface from IR-reflectance spectra depends on accepting the above. However, the process of producing np-Fe(sup 0) may be physical rather than chemical. All np-Fe(sup 0) could be deposits from a vapor produced by micrometeoritic impact on lunar soils. If metal-O bonds in target phases are broken, O being "most volatile" will escape leaving an O-deficient vapor to facilitate the production of np-Fe(sup 0). If so, the quantity of np-Fe(sup 0) is dependent on the vaporizing events, (i.e., exposure), and limited by the efficiency of breaking metal-O bonds and the escape of 0. To the extent that strengths of metal-O bonds are dependent on the local crystal field, production of np-Fe(sup 0) may be limited by the mineral composition of target soils and not by their total Fe content. According to this model, vapor-deposited np-Fe(sup 0) should be found at any retentive sites on lunar soil grains. Indeed, TEM images show np-Fe(sup 0) on plagioclase and ilmenite. Incorporation of such pre-irradiated np-Fe(sup 0)-bearing grains into agglutinates may account for eventual increased emplacement of np-Fe(sup 0) in agglutinates. Such a paradigm shift in understanding the origin of np-Fe(sup 0) will raise questions ranging from the unquestionable use of Is/FeO as the universal maturity parameter of lunar soils to global elemental maps of the Moon from remote-sensing data. Additional information is contained in the original.

Basu, A.↗

Size distributions in two porous chondritic micrometeorites

Quantitative size measurements of granular units (GUs), and nm-sized minerals in these units, in two porous chondritic micrometeorites are investigated. The matrix of these micrometeorites consist of loosely packed, 0.1 micron-sized, GUs. These objects were a major component of the solar nebula dust that accreted into protoplanets. The matrix in micrometeorite W7010*A2 has a fractal dimension with a small coefficient that supports efficient sticking of carbon-rich GUs during accretion. The fractal nature of the matrix provides a way to calculate the density using the aggregate size. The resulting very low density for porous chondritic micrometeorites is 0.08-0.14 g/cu cm, which supports the view that they are the solid debris from unconsolidated solar system bodies. Chondritic GUs contain ultrafine olivines, pyroxenes, and sulfides, embedded in hydrocarbons and amorphous carbons. Nanocrystals in the micrometeorites W7010*A2 and U2015*B show log normal size distributions. The high incidence of disk-shaped grains, a changeover from disk-shaped to euhedral grains, the unevolved nature of the size distributions, and multiple populations for grains less than 127 nm in size, are consistent with continuous postaccretion nucleation and growth in amorphous GUs, including coarsening via Ostwald ripening.

Rietmeijer, Frans J. M.↗

Options for improving rigidized ceramic heatshields

Studies regarding capabilities, tensile strength, and dimensional stability of fibrous ceramics, used in current thermal protection systems and those required for future NASA advanced transfer vehicles, are presented. It is shown that the use of smaller diameter (2-4 micron) aluminoborosilicate fibers (instead of conventional 11-micron size) in the FRCI composites improves the homogeneity and tensile strength of high-silica composite. Substitution of the smaller aluminoborosilicate fibers by 2-4-micron alumina fibers in the AETB composites improves the dimensional stability, at the expense of a substantial increase in the thermal expansion coefficient, with a potential decrease in tensile strength.

Leiser, D. B.↗

C-14 in lunar soil - Temperature-release and grain-size dependence

C-14 is released from surface soils by heatings between 600 and 1000 C. The amounts of 600-1000-C C-14 obtained increase inversely with grain diameter for the 10-30 and 74-125-micron size fractions. The inverse relation shows that the 600-1000-C C-14 is located on the surface of grains and probably is of solar-wind origin. The amount released at these temperatures gives 0.002 C-14 ions per sq cm/sec for the implantation rate and corresponds to a C-14/H ratio of the order of 4 hundred-billionths for the solar wind. This result from the grain-size dependence is in accord with C-14 depth-variation studies. The C-14 released above melting temperatures can be attributed to spallation production.

Fireman, E. L.↗

Mesoscale simulations of High Burnup Fuel Fragmentation: Applying phase-field modeling to understand high burnup fuel fragmentation during loss of coolant accident conditions

During a loss-of-coolant accident (LOCA) in a nuclear power plant, a rapid increase in temperature is experienced in the fuel. In commercial light water reactors (LWRs), the high burnup structure (HBS) forms in regions of the UO 2 fuel where local burnup is high, characterized by smaller grain sizes and large, overpressurized bubbles. During a LOCA transient, fuel in the HBS region is susceptible to fine fragmentation, where the fuel breaks up into micron-size fragments (sometimes referred to as pulverization). To better understand the mechanisms behind this phenomenon, mesoscale computational modeling using the Idaho National Laboratory code Marmot has been employed to simulate the process of HBS formation and response to a LOCA transient. The process of complete and partial HBS formation was demonstrated in prototypical LWR conditions. The simulated HBS microstructures from these simulations were passed to a phase-field model of fracture. To provide a more direct comparison with experiments, a set of experiments conducted by Studsvik on fine fragmentation/pulverization during LOCA conditions was simulated using the BISON fuel performance code. The temperature profiles from the BISON simulations were passed to a phase-field model to determine the gas bubble pressure as a function of time. These pressure histories were used in a phase-field model of fracture to determine under what conditions and in which types of bubbles fine fragmentation was likely to occur.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Petrographic and ferromagnetic resonance studies of the Apollo 15 deep drill core

Detailed petrographic grain size, and ferromagnetic resonance studies were performed on a representative suite of samples from the Apollo 15 deep drill core. Petrographic analyses of the 90-150 micron size fraction show a subtle upward increase in the ratio of mare to highland components. The agglutinate content at the FMR intensity normalized to FeO show that the soils in the core are generally immature to submature. The most striking feature shown by the maturity indices is a systematic decrease in maturity from the lunar surface to a depth of about 40 cm. Although other mechanisms are possible, the downward decrease in maturity can be attributed to in situ reworking over a time span of 400 m.y. at a 50% probability.

Heiken, G. H.↗

Lunar regolith fines - A source of hydrogen

The theoretical evaluation of the lunar regolith fines as a primary source of hydrogen reveals that a minimum order of magnitude increase in hydrogen content is possible in beneficiated fines because both particle size and particle shape play a significant role in the relationship of volume percent of surface coating to grain size. The lunar regolith fines meet the basic requirement for beneficiation because a major portion (minimum two-thirds) of the hydrogen occurs in the less than 20-micron-size fraction, a relatively small part of the fines. Beneficiation should be accomplished by a combination of vibratory screening followed by cyclone and/or possibly electrostatic separation. Early exploitation of the lunar regolith fines for hydrogen probably will be limited to hydrogen obtained as a by-product or co-product from the mining and processing for other elements or materials because a minimum of about 13,600 tons to about 19,600 tons of 100 ppm hydrogen-bearing lunar regolith fines will have to be processed with about 3,100 tons to about 4,500 tons, respectively, of concentrate heated to supply 1 ton of hydrogen, yielding a recovery of about 74 percent to about 51 percent respectively, of the hydrogen.

Carter, J. L.↗

All-Optical Micro Motors Based on Moving Gratings in Photosensitive Media

This research effort was a feasibility study of the concept of an all-optical micro motor with a rotor driven by a traveling wave. The wave was a result of a photo induced surface deformation of a photosensitive material produced by a traveling holographic grating. Two phases modulated coherent optical beams were used to generate the grating in two types of photosensitive materials. The materials that were studied were photorefractive crystals and thin polymer films. Theoretical studies were performed on lithium niobate giving predictions of deformations of the order of nanometers. The experimental deformation size was also on the order of nanometers. The deformations were deep enough to provide conditions for the implementation of the all-optical motor using lithium niobate. We also were able to align micron-size dielectric particles along the holographic gratings by means of the periodic electric forces generated by the grating. These forces can also move the particles along the surface if the grating is moving. We then turned our attention on thin films and obtained a deformation visible on the order of 100 microns. An experimental breadboard demonstration of a prototype was done in the summer of 2001 at Glenn Research Center (GRC). The demonstration included the movement of clocks mechanical workings by an optically driven motor based on a polymer film. The application of this technology can be adapted to government as well as industrial uses. One such project is to make a chemical sensor for the detection of hazardous chemicals. The thin polymer film is highly suited for this purpose since a marker dye could be easily placed on the film in order to detect chemical compounds. This system could be a self-regulating chemical monitoring system used on launches of the space shuttle or locations where hazardous chemicals are present. The project provided support for two black minority graduate students targeting MS and PhD degrees in Applied Optics.

Adamovsky, Gregory↗

Photoemission of Single Dust Grains for Heliospheric Conditions

Initial results of an experiment to measure the photoemission of single dust grains as a function of far ultraviolet wavelengths are presented. Coulombic forces dominate the interaction of the dust grains in the heliosphere. Knowledge of the charge state of dust grains, whether in a dusty plasma (Debye length < intergrain distance) or in the diffuse interplanetary region, is key to understanding their interaction with the solar wind and other solar system constituents. The charge state of heliospheric grains is primarily determined by primary electron and ion collisions, secondary electron emission and photoemission due to ultraviolet sunlight. We have established a unique experimental technique to measure the photoemission of individual micron-sized dust grains in vacuum. This technique resolves difficulties associated with statistical measurements of dust grain ensembles and non-static dust beams. The photoemission yield of Aluminum Oxide 3-micron grains For wavelengths from 120-300 nm with a spectral resolution of 1 nm FWHM is reported. Results are compared to interplanetary conditions.

Spann, James F., Jr.↗

Laboratory Measurements of Charging of Apollo 17 Lunar Dust Grains by Low Energy Electrons

It is well recognized that the charging properties of individual micron/sub-micron size dust grains by various processes are expected to be substantially different from the currently available measurements made on bulk materials. Solar UV radiation and the solar wind plasma charge micron size dust grains on the lunar surface with virtually no atmosphere. The electrostatically charged dust grains are believed to be levitated and transported long distances over the lunar terminator from the day to the night side. The current models do not fully explain the lunar dust phenomena and laboratory measurements are needed to experimentally determine the charging properties of lunar dust grains. An experimental facility has been developed in the Dusty Plasma Laboratory at NASA Marshall Space Flight Center MSFC for investigating the charging properties of individual micron/sub-micron size positively or negatively charged dust grains by levitating them in an electrodynamic balance in simulated space environments. In this paper, we present laboratory measurements on charging of Apollo 17 individual lunar dust grains by low energy electron beams in the 5-100 eV energy range. The measurements are made by levitating Apollo 17 dust grains of 0.2 to 10 micrometer diameters, in an electrodynamic balance and exposing them to mono-energetic electron beams. The charging rates and the equilibrium potentials produced by direct electron impact and by secondary electron emission processes are discussed.

Abbas, Mian M.↗

Smyer H-Chondrite Impact-Melt Breccia and Evidence for Sulfur Vaporization

Smyer is an H-chondrite impact-melt breccia containing approx.20 vol% 0.5- to 13-mm-thick silicate-rich melt veins surrounding unmelted subrounded chondritic clasts up to 7 cm in maximum dimension. At the interface between some of the melt veins and chondritic clasts, there are troilite-rich regions consisting of unmelted. crushed 0.2- to 140-micron-size angular silicate grains and chondrule fragments surrounded by troilite and transected by thin troilite veins. Troilite fills every available fracture in the silicates. including some as thin as 0.1 microns. Little metallic Fe-Ni is present in these regions: the FeS/Fe modal ratio ranges from -25: 1 to approx.500: 1, far higher than the eutectic weight ratio of 7.5: 1. The texture of these regions indicates that the sulfide formed from a fluid of very low viscosity. The moderately high viscosity (0.2 poise) and large surface tension of liquid FeS, its inability to wet silicate grain surfaces at low oxygen fugacities. and the supereutectic FeS/Fe ratios in the troilite-rich regions indicate that the fluid was a vapor. It seems likely that during the shock event that melted Smyer, many silicates adjacent to the melt veins were crushed. Upon release of shock pressure. some of the troilite evaporated and dissociated. Molecules of S2 were transported and condensed into fractures and around tiny silicate grains: there, they combined with Fe from small adjacent metallic Fe-Ni grains to form troilite. The Ni content at the edges of some of these metal grains increased significantly; Co from these Ni-rich grains diffused into nearby kamacite. Impact-induced S volatilization may have played a major role in depleting the surface of 433 Eros (and other chondritic asteroids) in S.

Rubin, Alan E.↗

Charged dust in the outer planetary magnetospheres. III - Satellite impact geometries

Interplanetary dust grains entering the Jovian plasmasphere become charged, and those in a certain size range get magneto-gravitationally trapped in the corotating plasmasphere. The trajectories of such dust grains intersect the orbits of one or more of the Galilean satellites. Orbital calculations of micron sized dust grains show that they impact the outermost satellite Callisto predominantly on its leading face, while they impact the inner three - Io, Europa and Ganymede - predominantly on the trailing face. These results are offered as an explanation of the observed brightness asymmetry between the leading and trailing faces of the outer three Galilean satellites. The albedo of Io is likely to be determined by its volcanism.

Hill, J. R.↗

Transport dynamics calculated under the full Mie scattering theory for micron and submicron lunar ejecta in selenocentric, cislunar, and geocentric space

In 1967, Lunar Explorer 35 was launched from the earth and placed into a stable orbit around the moon. The data from the dust particle experiment on this spacecraft were essentially continuous over a 5-yr period from the time of insertion in lunar orbit. Analysis of this data has been interpreted to show that micron-sized lunar ejecta leave the moon and traverse through selenocentric and cislunar space and obtain either interplanetary/heliocentric orbits or intercept the earth's magnetosphere and move into geocentric orbits. Extensive studies of the orbital trajectories of lunar particles in this size range have now been conducted that include a calculation of the solar radiation force using the full Mie scattering theory. A significant flux of particles with radii less than 0.1 micron are found to intercept the earth's magnetopause surface. This flux is shown to be strongly dependent upon both the particle's density and its index of refraction.

Hyde, T. W.↗