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At least 181 records · Page 10

Circularly Polarized Light-Induced Microwave Conductivity Measurement: Rapid Screening Technique of Electronic Conductivity in Chiral Molecular Materials

Here, we developed circularly polarized light-time-resolved microwave conductivity (CPL-TRMC) for investigation of the CPL-dependent photoinduced charge carrier dynamics in chiral materials with chiroptical properties. Chiral R- or S-perylenediimide (PDI) molecular thin films were paired with handedness-sorted (6,5) and (11,-5) single-walled carbon nanotube (SWCNT) films to compose a donor (D)-acceptor (A) system for the spin-dependent charge separation process, and the D-A system was examined through linear and circular polarization-dependent steady-state and time-resolved measurements. The R-PDI-(6,5) film exhibited strong enhancement in circular dichroism (CD) and revealed a reversed transient conductivity signal, relative to the polarity of CD in CPL-TRMC measurement upon excitation of the E 11 state, which is interpreted as arising from a spin-dependent initial charge separation process. Through linear polarization-dependent flash photolysis TRMC and circular polarization-resolved femtosecond transient absorption, we could deduce that sub-picosecond intertubular charge separation upon E 11 excitation in SWCNT was responsible for the spin-dependent photoconductivity transients observed in CPL-TRMC measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Reduction of weather effects in the calculation of sea ice concentration from microwave radiances

A technique is presented which improves existing methods of calculating sea ice concentrations from microwave radiances by reducing weather-related effects over open ocean areas and in the vicinity of marginal sea ice zones. Winds, atmospheric water vapor, cloud liquid water, and rain increase the microwave emission over these regions and thus result in erroneous values of computed sea ice concentration. The method described is based on the microwave spectral properties of sea ice and ice-free ocean and utilizes ratios of the polarized radiances at the 0.81-cm (37 GHz) and 1.7-cm (18 GHz) wavelengths. Following a discussion of the physical basis for this technique, examples are provided which demonstrate its utility. While the technique was developed for use with the Nimbus 7 scanning multichannel microwave radiometer data, it is applicable also to data from other microwave radiometers operating in a similar wavelength range.

Gloersen, P.↗

Microwave-Mediated Extraction of Critical Metals from LED E-Waste

This study introduces a microwave-assisted technique for extracting critical minerals from LED electronic waste. The process begins with microwave irradiation, which thermally decomposes the LED’s plastic lens into a brittle, charred residue. During this stage, the LED chip undergoes deflagration—being rapidly ejected from the reflective cavity and becoming embedded within the decomposed lens material. Consequently, the chip is encapsulated in the resulting charred residue. This composite, consisting of the charred lens and the LED chip, can be easily separated from the metallic pins (Fe, Ni, Ag), which remain almost undamaged. Subsequent calcination of the charred material in air exposes the materials making up the LED chip, which contain critical metals (e.g., Ga, As, In, Y, Au). These metals are then extracted through a two-step acid leaching process involving aqua regia followed by hot concentrated hydrochloric acid, yielding them in potentially recoverable forms. The synergistic effect of microwave irradiation and acid treatment achieves an average extraction efficiency of 96% for critical metals. Notably, this approach enables complete and loss-free recovery of the LED chip, offering a practical and efficient solution for LED e-waste recycling.

Bourlinos, Athanasios B.↗

System definition of SEASAT-A, an ocean observation satellite

SEASAT will be an earth-satellite system designed to monitor and observe ocean dynamics in order to provide data for real-time use and predictive purposes. SEASAT-A will be a prototype satellite which will provide experience for system development and some operational demonstration capability. The SEASAT-A will use passive and active visible, infrared, and microwave sensing techniques. The payload will include a scanning radiometer (SR) and a scanning multichannel microwave radiometer (SMMR), which are passive sensors, a short-pulse altimeter, a scatterometer, and a synthetic aperture radar, which are active. The major functional elements considered in the definition-phase studies are the sensors, data handling, communications, attitude control, power, orbit adjust, thermal control, structures, and mechanical design. An existing satellite bus, with sensors and sensor modules to be developed, is to be used on SEASAT-A.

Rose, J. R.↗

Soil moisture measurements with microwave, radiometers

One technique of measuring moisture content that appears promising is that of microwave radiometry. In the microwave region of the spectrum, the emissivity of water is approximately 0.4, whereas that of dry soil is approximately 0.9. Therefore, the emissivity of the soil can range from about 0.6 to 0.9 as the soil changes from a wet to a dry condition. Recent ground base measurements have demonstrated emissivity changes of this magnitude. To test the use of this approach for remote sensing of soil moisture, flights were made over agricultural test sites in the vicinity of Phoenix, Ariz., during late February 1971. On the same day, soil moisture measurements were made on the ground for 200 fields. On board the aircraft were six microwave radiometers, ranging in wavelength from 21 cm to 8 mm. The results of one of these radiometers are presented.

Schmugge, T. J.↗

Containerless synthesis of ceramic materials using microwave heating

It was demonstrated that microwave heating technique may be employed for the synthesis of a number of multicomponent ceramic oxide-based materials, e.g., YBa2Cu3O7 and CuFe2O4. A characteristic, and potentially extremely useful, feature of such synthesis is that they occur in significantly less time than that required using conventional furnace-based techniques. However, the information obtained to date is necessarily rather empirical, and systematic investigations of the use of microwave heating for the synthesis of ceramic materials are required. The synthesis of ceramic materials at high temperatures are often affected by unwanted, deleterious reactions of the reactants and/or products with the reaction container. Consequently, it is of interest to investigate the high temperature synthesis of ceramic materials using microwave heating in a containerless environment.

Dunn, B.↗

The Upper Atmosphere Research Satellite microwave limb sounder instrument

The microwave limb sounder (MLS) on the Upper Atmosphere Research Satellite (UARS) is the first satellite experiment using limb sounding techniques at microwave frequencies. Primary measurement objectives are stratospheric ClO, O3, H2O, temperature, and pressure. Measurements are of thermal emission: all are performed simultaneously and continuously and are not degraded by ice clouds or volcanic aerosols. The instrument has a 1.6-m mechanically scanning antenna system and contains heterodyne radiometers in spectral bands centred near 63, 183, and 205 GHz. The radiometers operate at ambient temperature and use Schottky-diode mixers with local oscillators derived from phase-locked Gunn oscillators. Frequency tripling by varactor multipliers generates the 183- and 205-GHz local oscillators, and quasi-optical techniques inject these into the mixers. Six 15-channel filter banks spectrally resolve stratospheric thermal emission lines and produce an output spectrum every 2 s. Thermal stability is sufficient for 'total power' measurements which do not require fast chopping. Radiometric calibration, consisting of measurements of cold space and an internal target, is performed every 65-s limb scan. Instrument in-orbit performance has been excellent, and all objectives are being met.

Barath, F. T.↗

Sensor Calibration and Ocean Products for TRMM Microwave Radiometer

During the three years of finding, we have carefully corrected for two sensor/platform problems, developed a physically based retrieval algorithm to calculate SST, wind speed, water vapor, cloud liquid water and rain rates, validated these variables, and demonstrated that satellite microwave radiometers can provide very accurate SST retrievals through clouds. Prior to this, there was doubt by some scientists that the technique of microwave SST retrieval from satellites is a viable option. We think we have put these concerns to rest, and look forward to making microwave SSTs a standard component of the Earth science data sets. Our TMI SSTs were featured on several network news broadcasts and were reported in Science magazine. Additionally, we have developed a SST algorithm for VIRS to facilitate IR/MW inter-comparisons and completed research into diurnal cycles and air-sea interactions.

Wentz, Frank J.↗

Sensor Calibration and Ocean Products for TRMM Microwave Radiometer

During the three years of fundin& we have carefully corrected for two sensor/platform problems, developed a physically based retrieval algorithm to calculate SST, wind speed, water vapor, cloud liquid water and rain rates, validated these variables, and demonstrated that satellite microwave radiometers can provide very accurate SST retrievals through clouds. Prior to this, there was doubt by some scientists that the technique of microwave SST retrieval from satellites is a viable option. We think we have put these concerns to rest, and look forward to making microwave SSTs a standard component of the Earth science data sets. Our TMI SSTs were featured on several network news broadcasts and were reported in Science magazine. Additionally, we have developed a SST algorithm for VIRS to facilitate IR/MW inter-comparisons and completed research into diurnal cycles and air-sea interactions.

Lawrence, Richard J.↗

Optimal spatial sampling techniques for ground truth data in microwave remote sensing of soil moisture

The paper examines optimal sampling techniques for obtaining accurate spatial averages of soil moisture, at various depths and for cell sizes in the range 2.5-40 acres, with a minimum number of samples. Both simple random sampling and stratified sampling procedures are used to reach a set of recommended sample sizes for each depth and for each cell size. Major conclusions from statistical sampling test results are that (1) the number of samples required decreases with increasing depth; (2) when the total number of samples cannot be prespecified or the moisture in only one single layer is of interest, then a simple random sample procedure should be used which is based on the observed mean and SD for data from a single field; (3) when the total number of samples can be prespecified and the objective is to measure the soil moisture profile with depth, then stratified random sampling based on optimal allocation should be used; and (4) decreasing the sensor resolution cell size leads to fairly large decreases in samples sizes with stratified sampling procedures, whereas only a moderate decrease is obtained in simple random sampling procedures.

Rao, R. G. S.↗

On the determination of atmospheric path length by passive microwave radiometer

Microwave radiometer techniques were evaluated for use in atmospheric path length correction of Pacific Plate Motion Experiment interferometer measurements. It is shown that passive microwave radiometry allows precise measurement of the brightness temperature of the sky. It is also noted that the technological requirements of radiometers are very different from the requirements of radio astronomy. The technology was used in the construction of radiometers which are sufficient for use in the path length correction problem. A simulation study shows that, when combined with surface meteorology data, passive microwave radiometer data would allow a determination of the path length correction to better than 2 cm at the zenith. By a careful choice of frequencies, a dual frequency system would allow a measurement of the path length correction to better than 4 cm at zenith angles as great as 60 deg. Because of the wide range of weather conditions to be expected for the PPME sites (which include Alaska, Hawaii and Massachusetts), it will probably be necessary to use a separate correction algorithm for each site.

Webster, W. J., Jr.↗

Fabrication of ultra-low-noise amplifier

Three construction techniques reduce noise temperature of microwave parametric amplifier. Techniques include electroformed idler cavity, screw-tuned idler, and low-loss matching section.

Kraemer, E.↗

Optical technology for microwave applications IV; Proceedings of the Meeting, Orlando, FL, Mar. 28, 29, 1989

Among the topics discussed at the meeting are high-speed laser and electrooptical technologies, detectors and detector arrays, microwave delay lines, and photon-microwave interactions. In addition, optical link applications are discussed, along with electronic warfare receivers and acoustooptical signal processing. Emphasis is placed on laser diode technology, direct modulation of laser diodes, external electrooptical laser modulation techniques, and microwave fiber-optic delay lines. Attention is given to such optical link applications as multigigahertz links as well as to signal processing for phased-array antennas and channelized microwave receiver technologies.

Yao, Shi-Kay↗

Passive microwave radiometric observations of the atmosphere

Passive microwave sensing techniques can be used to obtain the temperature of the atmosphere, and to infer liquid water, water vapor and other molecular species over ocean or above the troposphere. The use of satellite-borne passive microwave radiometers is discussed along with the future use of the instrument on Nimbus-G and on the space shuttle.

Cassel, A. L.↗