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At least 181 records · Page 10

Method for fabricating ceramic filaments and high density tape casting method

An apparatus and method is disclosed for fabricating mats of ceramic material comprising preparing a slurry of ceramic particles in a binder/solvent, charging the slurry into a vessel, forcing the slurry from the vessel into spinneret nozzles, discharging the slurry from the nozzles into the path of airjets to enhance the sinuous character of the slurry exudate and to dry it, collecting the filaments on a moving belt so that the filaments overlap each other thereby forming a mat, curing the binder therein, compressing and sintering the mat to form a sintered mat, and crushing the sintered mat to produce filament shaped fragments. A process is also disclosed for producing a tape of densely packed, bonded ceramic particles comprising forming a slurry of ceramic particles and a binder/solvent, applying the slurry to a rotating internal molding surface, applying a large centrifugal force to the slurry to compress it and force excess binder/solvent from the particles, evaporating solvent and curing the binder thereby forming layers of bonded ceramic particles and cured binder, and separating the binder layer from the layer of particles. Multilayers of ceramic particles are cast in an analogous manner on top of previously formed layers. When all of the desired layers have been cast the tape is fired to produce a sintered tape. For example, a three-layer tape is produced having outer layers of highly compressed filament shaped fragments of strontium doped lanthanum (LSM) particles and a center layer of yttria stabilized zicronia (YSZ) particles.

Collins, Jr., Earl R.↗

Summer Dust Aerosols Detected from CALIPSO Observations over the Tibetan Plateau

Summertime Tibetan dust aerosol plumes are detected from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) satellite. CALIPSO reveals that dust storms occur 4 times more frequently than previously found from Tibetan surface observations because few surface sites were available over remote northwestern Tibet. The Tibetan dust aerosol is characterized by column-averaged depolarization and color ratios around 21% and 0.83, respectively. The dust layers appear most frequently around 4-7 km above mean sea level. The depolarization ratio for about 90% of the dust particles is less than 10% at low altitudes (3-5 km), while only about 50% of the particles have a greater depolarization ratio at higher altitudes (7-10 km) suggesting a separation of larger irregular particles from smaller, near spherical ones during transport. The 4-day back trajectory analyses show that these plumes probably originate from the nearby Taklimakan desert surface and accumulate over the northern slopes of the Tibetan Plateau. These dust outbreaks can affect the radiation balance of the atmosphere of Tibet because they both absorb and reflect solar radiation.

Huang, Jianping↗

The effects of solid rocket motor effluents on selected surfaces and solid particle size, distribution, and composition for simulated shuttle booster separation motors

A series of three tests was conducted using solid rocket propellants to determine the effects a solid rocket plume would have on thermal protective surfaces (TPS). The surfaces tested were those which are baselined for the shuttle vehicle. The propellants used were to simulate the separation solid rocket motors (SSRM) that separate the solid rocket boosters (SRB) from the shuttle launch vehicle. Data cover: (1) the optical effects of the plume environment on spacecraft related surfaces, and (2) the solid particle size, distribution, and composition at TPS sample locations.

Jex, D. W.↗

Observed Enhancement of Reflectivity and Electric Field in Long-Lived Florida Anvils

A study of two long-lived Florida anvils showed that reflectivity greater than 20 dBZ increased in area, thickness and sometimes magnitude at mid-level well downstream of the convective cores. In these same regions electric fields maintained strengths greater than 10 kV m(sup -1) for many tens of minutes and became quite uniform over tens of kilometers. Millimetric aggregates persisted at 9 to 10 km for extended times and distances. Aggregation of ice particles enhanced by strong electric fields might have contributed to reflectivity growth in the early anvil, but is unlikely to explain observations further out in the anvil. The enhanced reflectivity and existence of small, medium and large ice particles far out into the anvil suggest that an updraft was acting, perhaps in weak convective cells formed by instability generated from the evaporation and melting of falling ice particles. We conclude that charge separation must have occurred in these anvils, perhaps at the melting level but also at higher altitudes, in order to maintain fields greater than 10 kV m(sup -1) at 9 to 10 km for extended periods of time over large distances. We speculate that charge separation occurred as a result of ice-ice particle collisions (without supercooled water being present) via either a noninductive or perhaps even an inductive mechanism, given the observed broad ice particle spectra, the strong pre-existing electric fields and the many tens of minutes available for particle interactions. The observations, particularly in the early anvil, show that the charge structure in these anvils was quite complex.

Dye, James E.↗

Observed Enhancement of Reflectivity and Electric Field in Long-Lived Florida Anvils

A study of two long-lived Florida anvils showed that reflectivity >20 dBZ increased in area, thickness and sometimes magnitude at mid-level well downstream of the convective cores. In these same regions electric fields maintained strengths >10 kV m1 for many tens of minutes and became quite uniform over tens of kilometers. Millimetric aggregates persisted at 9 to 10 km for extended times and distances. Aggregation of ice particles enhanced by strong electric fields might have contributed to reflectivity growth in the early anvil, but is unlikely to explain observations further out in the anvil. The enhanced reflectivity and existence of small, medium and large ice particles far out into the anvil suggest that an updraft was acting, perhaps in weak convective cells formed by instability generated from the evaporation and melting of falling ice particles. We conclude that charge separation must have occurred in these anvils, perhaps at the melting level but also at higher altitudes, in order to maintain fields >10 kV m 1 at 9 to 10 km for extended periods of time over large distances. We speculate that charge separation occurred as a result of ice-ice particle collisions (without supercooled water being present) via either a non-inductive or perhaps even an inductive mechanism, given the observed broad ice particle spectra, the strong pre-existing electric fields and the many tens of minutes available for particle interactions. The observations, particularly in the early anvil, show that the charge structure in these anvils was quite complex.

Dye, James E.↗

Interaction of Burning Metal Particles

Physical characteristics of the combustion of metal particle groups have been addressed in this research. The combustion behavior and interaction effects of multiple metal particles has been studied using a microgravity environment, which presents a unique opportunity to create an "aerosol" consisting of relatively large particles, i.e., 50-300 m diameter. Combustion behavior of such an aerosol could be examined using methods adopted from well-developed single particle combustion research. The experiment included fluidizing relatively large (order of 100 m diameter) uniform metal particles under microgravity and igniting such an "aerosol" using a hot wire igniter. The flame propagation and details of individual particle combustion and particle interaction have been studied using a high speed movie and video-imaging with cameras coupled with microscope lenses to resolve individual particles. Interference filters were used to separate characteristic metal and metal oxide radiation bands from the thermal black body radiation. Recorded flame images were digitized and various image processing techniques including flame position tracking, color separation, and pixel by pixel image comparison were employed to understand the processes occurring in the burning aerosol. The development of individual particle flames, merging or separation, and extinguishment as well as induced particle motion have been analyzed to identify the mechanisms governing these processes. Size distribution, morphology, and elemental compositions of combustion products were characterized and used to link the observed in this project aerosol combustion phenomena with the recently expanded mechanism of single metal particle combustion.

Dreizin, Edward L.↗

Efficient Implementation of the Invariant Imbedding T-Matrix Method and the Separation of Variables Method Applied to Large Nonspherical Inhomogeneous Particles

Three terms, ''Waterman's T-matrix method'', ''extended boundary condition method (EBCM)'', and ''null field method'', have been interchangeable in the literature to indicate a method based on surface integral equations to calculate the T-matrix. Unlike the previous method, the invariant imbedding method (IIM) calculates the T-matrix by the use of a volume integral equation. In addition, the standard separation of variables method (SOV) can be applied to compute the T-matrix of a sphere centered at the origin of the coordinate system and having a maximal radius such that the sphere remains inscribed within a nonspherical particle. This study explores the feasibility of a numerical combination of the IIM and the SOV, hereafter referred to as the IIMþSOV method, for computing the single-scattering properties of nonspherical dielectric particles, which are, in general, inhomogeneous. The IIMþSOV method is shown to be capable of solving light-scattering problems for large nonspherical particles where the standard EBCM fails to converge. The IIMþSOV method is flexible and applicable to inhomogeneous particles and aggregated nonspherical particles (overlapped circumscribed spheres) representing a challenge to the standard superposition T-matrix method. The IIMþSOV computational program, developed in this study, is validated against EBCM simulated spheroid and cylinder cases with excellent numerical agreement (up to four decimal places). In addition, solutions for cylinders with large aspect ratios, inhomogeneous particles, and two-particle systems are compared with results from discrete dipole approximation (DDA) computations, and comparisons with the improved geometric-optics method (IGOM) are found to be quite encouraging.

Invariant imbedding method↗

Solid Hydrogen Experiments for Atomic Propellants: Image Analyses

This paper presents the results of detailed analyses of the images from experiments that were conducted on the formation of solid hydrogen particles in liquid helium. Solid particles of hydrogen were frozen in liquid helium, and observed with a video camera. The solid hydrogen particle sizes, their agglomerates, and the total mass of hydrogen particles were estimated. Particle sizes of 1.9 to 8 mm (0.075 to 0.315 in.) were measured. The particle agglomerate sizes and areas were measured, and the total mass of solid hydrogen was computed. A total mass of from 0.22 to 7.9 grams of hydrogen was frozen. Compaction and expansion of the agglomerate implied that the particles remain independent particles, and can be separated and controlled. These experiment image analyses are one of the first steps toward visually characterizing these particles, and allow designers to understand what issues must be addressed in atomic propellant feed system designs for future aerospace vehicles.

Palaszewski, Bryan↗

Remote-Sensing Reflectance and Inherent Optical Properties for Optically Deep Waters: A Revisit

Remote-sensing reflectance (r(rs)) is defined as the ratio of upwelling radiance to downwelling irradiance. Relationships between remote-sensing reflectance and inherent optical properties serve as the basis for ocean-color modeling, as well as for spectral deduction of oceanic constituents through analytical/semi-analytical models of ocean color. A decade ago, a simple and concise formula based on Monte Carlo simulations was developed by relating rrs to a property u, the ratio of backscattering (b(b)) to the sum of absorption (a) and backscattering (u = b(b)/(a+b(b))). This relationship generally ignored the shape differences in phase functions between molecular scattering and particle scattering. In this study, the relationship is updated with separate parameters for molecular and particle scattering, based on the Radiative Transfer Equation through use of Hydrolight numerical solutions. The new approach fits r(rs) better than an earlier traditional formula, for both clear and turbid waters.

Lee, Zhong-Ping↗

Silica-Aerogel Composites Opacified with La(0.7)Sr(0.3)MnO3

As part of an effort to develop improved lightweight thermal-insulation tiles to withstand temperatures up to 1,000 C, silica aerogel/fused-quartz-fiber composite materials containing La0.7Sr0.3MnO3 particles as opacifiers have been investigated as potentially offering thermal conductivities lower than those of the otherwise equivalent silica-aerogel composite materials not containing La(0.7)Sr(0.3)MnO3 particles. The basic idea of incorporating opacifying particles into silica-aerogels composite to reduce infrared radiative contributions to thermal conductivities at high temperatures is not new: it has been reported in a number of previous NASA Tech Briefs articles. What is new here is the selection of La(0.7)Sr(0.3)MnO3 particles as candidate opacifiers that, in comparison with some prior opacifiers (carbon black and metal nanoparticles), are more thermally stable. The preparation of a composite material of the present type includes synthesis of the silica-aerogel component in a sol-gel process. The La(0.7)Sr(0.3)MnO3 particles, made previously in a separate process, are mixed into the sol, which is then cast onto fused-quartz-fiber batting. Then the aerogel-casting solution is poured into the mold, where it permeates the silica fiber felt. After the sol has gelled, the casting is aged and then subjected to supercritical drying to convert the gel to the final aerogel form. The separate process for making the La(0.7)Sr(0.3)MnO3 particles begins with the slow addition of corresponding proportions of La(CH3COOH)3, Mn(CH3COOH)3, and Sr(NO3)2 to a solution of H2O2 in H2O. The solution is then peptized by drop-wise addition of NH4OH to obtain a sol. Next, the sol is dried in an oven at a temperature of 120 C to obtain a glassy solid. The solid is calcined at 700 C to convert it to La(0.7)Sr(0.3)MnO3. Then La(0.7)Sr(0.3)MnO3 particles are made by ball-milling the calcined solid. The effectiveness of La(0.7)Sr(0.3)MnO3 particles as opacifiers and thermal-conductivity reducers depends on the statistical distribution of particle sizes as well as the relative proportions of La(0.7)Sr(0.3)MnO3 and aerogel. For experiments performed thus far, samples of aerogel/fiber composites were formulated to have, variously, silica target density of 0.07 or 0.14 g/cu cm and to contain 30 percent of La(0.7)Sr(0.3)MnO3 in average particle size of 0.3 or 3 microns. The thermal conductivities of the samples containing the 3 micron La(0.7)Sr(0.3)MnO3 particles were found to be lower than those of the samples containing the 0.3 micron La(0.7)Sr(0.3)MnO3 particles. The optimum particle size is believed to be between 1 and 5 microns.

Rhine, Wendell↗

Polymer-Induced Depletion Interaction and Its Effect on Colloidal Sedimentation in Colloid-Polymer Mixtures

In this paper we focus on the polymer-induced depletion attraction and its effect on colloidal sedimentation in colloid-polymer mixtures. We first report a small angle neutron scattering (SANS) study of the depletion effect in a mixture of hard-sphere-like colloid and non-adsorbing polymer. Then we present results of our recent sedimentation measurements in the same colloid-polymer mixture. A key parameter in controlling the sedimentation of heavy colloidal particles is the interparticle potential U(tau), which is the work required to bring two colloidal particles from infinity to a distance tau under a give solvent condition. This potential is known to affect the average settling velocity of the particles and experimentally one needs to have a way to continuously vary U(tau) in order to test the theory. The interaction potential U(tau) can be altered by adding polymer molecules into the colloidal suspension. In a mixture of colloid and non-adsorbing polymer, the potential U(tau) can develop an attractive well because of the depletion effect, in that the polymer chains are expelled from the region between two colloidal particles when their surface separation becomes smaller than the size of the polymer chains. The exclusion of polymer molecules from the space between the colloidal particles leads to an unbalanced osmotic pressure difference pushing the colloidal particles together, which results in an effective attraction between the two colloidal particles. The polymer-induced depletion attraction controls the phase stability of many colloid-polymer mixtures, which are directly of interest to industry.

Tong, Penger↗

The width of electron-photon cascades in air

Results of a Monte-Carlo simulation of electron-photon cascades are presented with particular emphasis on cascade lateral spread. The effects of single and multiple Coulomb scattering are represented by giving the particles suitable displacements in position and angle at each interaction point. Some of the more oblique particle tracks are first divided into a number of steps between interaction points and the scattering procedure is applied to each step separately. To represent the particle defections due the geomagnetic field, a field of 0.3 gauss is supposed present and the appropriate helical path is imposed on each particle between interaction points. The results are in good agreement with the calculations of Nordheim et al., with simulations using the Berger-Seltzer electron photon transport program and with experimental measurements in water.

Allan, H. R.↗

Interaction of Burning Metal Particles

Physical characteristics of the combustion of metal particle groups have been addressed in this research. The combustion behavior and interaction effects of multiple metal particles has been studied using a microgravity environment, which presents a unique opportunity to create an "aerosol" consisting of relatively large particles, i.e., 50-300 micrometer diameter. Combustion behavior of such an aerosol could be examined using methods adopted from well-developed single particle combustion research. The experiment included fluidizing relatively large (order of 100 micrometer diameter) uniform metal particles under microgravity and igniting such an "aerosol" using a hot wire igniter. The flame propagation and details of individual particle combustion and particle interaction have been studied using a high speed movie and video-imaging with cameras coupled with microscope lenses to resolve individual particles. Interference filters were used to separate characteristic metal and metal oxide radiation bands form the thermal black body radiation. Recorded flame images were digitized and employed to understand the processes occurring in the burning aerosol. The development of individual particle flames, merging or separation, and extinguishing as well as induced particle motion have been analyzed to identify the mechanisms governing these processes. Size distribution, morphology, and elemental compositions of combustion products were characterized and used to link the observed in this project aerosol combustion phenomena with the recently expanded mechanism of single metal particle combustion.

Dreizin, Edward L.↗

Direct method for solution of three-dimensional unsteady incompressible Navier-Stokes equations

A three-dimensional, unsteady analysis for the velocity-vorticity formulation of the Navier-Stokes (NS) equations is described. This formulation highlights the natural separation of the spin dynamics of a fluid particle from its translational kinematics. This separation is exploited to produce a single pass direct inversion of the full unsteady NS operator without the need to iterate either the future wall vorticity or the nonlinear vorticity convection terms. The method has uniform second-order accuracy in time and space. As an example, it is applied to the problem of the three-dimensional flow within a shear-driven cubical box. Results are obtained for Re = 100, 400, and 1000 using a preliminary (25, 25, 25) mesh.

Osswald, G. A.↗

Relationship Between the Sub-Micron Fraction (SMF) and Fine-Mode Fraction (FMF) in the Context of AERONET Retrievals

The sub-micron (SM) aerosol optical depth (AOD) is an optical separation based on the fraction of particles below a specified cutoff radius of the particle size distribution (PSD) at a given particle radius. It is fundamentally different from spectrally separated FM (fine-mode) AOD. We present a simple (AOD-normalized) SM fraction versus FM fraction (SMF vs. FMF) linear equation that explains the well-recognized empirical result of SMF generally being greater than the FMF. The AERONET inversion (AERinv) products (combined inputs of spectral AOD and sky radiance) and the spectral deconvolution algorithm (SDA) products (input of AOD spectra) enable, respectively, an empirical SMF vs. FMF comparison at similar (columnar) remote sensing scales across a variety of aerosol types. SMF (AERinv-derived) vs. FMF (SDA-derived) behavior is primarily dependent on the relative truncated portion (ε c ) of the coarse-mode (CM) AOD associated with the cutoff portion of the CM PSD and, to a second order, the cutoff FM PSD and FM AOD (ε f ). The SMF vs. FMF equation largely explains the SMF vs. FMF behavior of the AERinv vs. SDA products as a function of PSD cutoff radius (“inflection point”) across an ensemble of AERONET sites and aerosol types (urban-industrial, biomass burning, dust, maritime and a mixed class of Arctic aerosols). The overarching dynamic was that the linear SMF vs. FMF relation pivots clockwise about the approximate (SMF, FMF) singularity of (1, 1) in a “linearly inverse” fashion (slope and intercept of approximately 1−ε c and ε c ) with increasing cutoff radius. SMF vs. FMF slopes and intercepts derived from AERinv and SDA retrievals confirmed the general domination of ε c over ε f in controlling that dynamic. A more general conclusion is the apparent confirmation that the optical impact of truncating modal (whole) PSD features can be detected by an SMF vs. FMF analysis.

Norman T. O'Neill↗

Metallic particles in the Apollo 14 lunar soil.

The metallographic structures, silicate associations and bulk compositions (Ni, Co, P, S, and Si) were determined by microprobe analysis for 205 metal particles selected by magnetic separation from the less than 1 mm, greater than 125 micron fraction of soil samples 14003,18 and 14163,165. A small number of exotic particles were encountered but almost all the metal could be accommodated within one of four subpopulations, the characteristics and genetic significance of which may be stated as follows: (1) the major proportion has Ni and Co contents corresponding to the range of meteoritic metal; (2) small proportion (about 5%) that not only has meteoritic contents of Ni and Co but also shows still distinguishable indications of meteoritic microstructure; (3) another small population (about 10%) consists of metal excavated from lunar mare basalts by cratering events, and thrown onto the Apollo 14 site; and (4) metallic spheroids (about 5%), analogous to those encountered in the vicinity of the Barringer Meteorite Crater, Arizona.

Goldstein, J. I.↗

Recent progress in the transition radiation detector techniques

A list of some of the major experimental achievements involving charged particles in the relativistic region are presented. With the emphasis mainly directed to the X-ray region, certain modes of application of the transition radiation for the identification and separation of relativistic charged particles are discussed. Some recent developments in detection techniques and improvements in detector performances are presented. Experiments were also carried out to detect the dynamic radiation, but no evidence of such an effect was observed.

Yuan, L. C. L.↗

The Scattering Properties of Natural Terrestrial Snows versus Icy Satellite Surfaces

Our comparisons of the single particle scattering behavior of terrestrial snows and icy satellite regoliths to the laboratory particle scattering measurements of McGuire and Hapke demonstrate that the differences between icy satellite regoliths and their terrestrial counterparts are due to particle structures and textures. Terrestrial snow particle structures define a region in the single particle scattering function parameter space separate from the regions defined by the McGuire and Hapke artificial laboratory particles. The particle structures and textures of the grains composing icy satellites regoliths are not simple or uniform but consist of a variety of particle structure and texture types, some of which may be a combination of the particle types investigated by McGuire and Hapke.

Domingue, Deborah↗