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Results for “Priming effects”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1987

Kinetic analysis of the template effect in ribooligoguanylate elongation

The paper presents kinetic studies on the reaction of elongation of the 3-prime-5-prime-linked ribooligoguanylates with guanosine 5-prime-phospho-2-methylimidazolide (2-MelmpG) in the presence or absence of a complementary template, the polycytidylic acid. In the absence of poly(C), the reaction leads to three isomeric oligomers that are elongated by one monomer unit: the 3-prime-5-prime linked, the 2-prime-5-prime linked, and the pyrophosphate, formed in a ratio of 1:2:5. In the presence of the template, the reaction is 20-fold faster and yields products (n + 1), (n + 2), (n + 3), etc., as long as 2-MelmpG is available. The formation of the natural, 3-prime-5-prime-linked isomer, is enhanced selectively by 140-fold at 37 C, and its relative yield increases with decreasing temperature.

Kanavarioti, Anastassia↗
DOE OSTI2021

Dual arginine recognition of LRRK2 phosphorylated Rab GTPases

Parkinson’s-disease-associated LRRK2 is a multidomain Ser/Thr kinase that phosphorylates a subset of Rab GTPases to control their effector functions. Rab GTPases are the prime regulators of membrane trafficking in eukaryotic cells. Rabs exert their biological effects by recruitment of effector proteins to subcellular compartments via their Rab-binding domain (RBD). Effectors are modular and typically contain additional domains that regulate various aspects of vesicle formation, trafficking, fusion, and organelle dynamics. The RBD of effectors is typically an α-helical coiled coil that recognizes the GTP conformation of the switch 1 and switch 2 motifs of Rabs. LRRK2 phosphorylates Rab8a at T72 (pT72) of its switch 2 α-helix. This post-translational modification enables recruitment of RILPL2, an effector that regulates ciliogenesis in model cell lines. A newly identified RBD motif of RILPL2, termed the X-cap, has been shown to recognize the phosphate via direct interactions between an arginine residue (R132) and pT72 of Rab8a. Here, we show that a second distal arginine (R130) is also essential for phospho-Rab binding by RILPL2. Through structural, biophysical, and cellular studies, we find that R130 stabilizes the primary R132:pT72 salt bridge through favorable enthalpic contributions to the binding affinity. These findings may have implications for the mechanism by which LRRK2 activation leads to assembly of phospho-Rab complexes and subsequent control of their membrane trafficking functions in cells.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1980

Greenhouse models of Venus' high surface temperature, as constrained by Pioneer Venus measurements

Recent measurements conducted from the Pioneer Venus probes and orbiter have provided a significantly improved definition of the solar net flux profile, the gaseous composition, temperature structure, and cloud properties of Venus' lower atmosphere. Using these data, we have carried out a series of one-dimensional radiative-convective equilibrium calculations to determine the viability of the greenhouse model of Venus' high surface temperature and to assess the chief contributors to the greenhouse effect. New sources of infrared opacity include the permitted transitions of SO2, CO, and HCl as well as opacity due to several pressure-induced transitions of CO2. We find that the observed surface temperature and lapse rate structure of the lower atmosphere can be reproduced quite closely with a greenhouse model that contains the water vapor abundance reported by the Venera spectrophotometer experiment. Thus the greenhouse effect can account for essentially all of Venus' high surface temperature. The prime sources of infrared opacity are, in order of importance, CO2, H2O, cloud particles, and SO2, with CO and HCl playing very minor roles.

Pollack, J. B.↗
NASA NTRS1983

Variable speed drive

A variable speed drive wherein a first embodiment is comprised of a pivotally mounted prime mover coupled to a rotary fluid output device, such as a fan or pump, through a variable and fixed pulley drive arrangement is described. The pivotal position of the prime mover and accordingly the pitch diameter of variable pulley means is controlled in accordance with fluid motor means coupled to the prime mover. This is actuated in response to a fluid feedback control signal derived from a sensed output of the rotary fluid output device. The pivotal motion of the prime mover imparts an arcuate motion to the variable pulley means which effects a speed variation of the rotary fluid output device in accordance with the variation of the pitch diameter ratio of opposing variable and fixed pulley means.

Obler, H. D.↗
NASA NTRS1985

Effect of bond coat creep and oxidation on TBC integrity

The potential of thermal barrier coatings (TBCs) on high-pressure turbine (HPT) nozzles and blades is limited at present by the inability to quantitatively predict TBC life for these components. The goal is to isolate the major TBC failure mechanisms, which is part of the larger program aimed at developing TBC life prediction models. Based on the results of experiments to isolate TBC failure mechanisms, the effects of bond coat oxidation and bond coat creep on TBC integrity is discussed. In bond coat oxidation experiments, Rene prime 80 specimens coated with a NiCrAlY/ZrO2-8 percent Y2O3 TBC received isothermal pre-exposures at 2000 F in static argon, static air, or received no pre-exposure. The effects of oxidation due to the pre-exposures were determined by thermal cycle tests in both static air and static argon at 2000 F. To study the effect of bond coat creep on TBS behavior, four bond coats with different creep properties were evaluated by thermal cycle tests in air at 2000 F. The test results, the relative importance of these two failure mechanisms, and how their effects may be quantified will also be discussed.

Duderstadt, E. C.↗
NASA NTRS1991

Use of scaled external correlation, a double many-body expansion, and variational transition state theory to calibrate a potential energy surface for FH2

New ab initio results and a double many-body expansion formalism have been used to parameterize a new FH2 potential energy surface with improved properties near the saddle point and in the region of long-range attraction. The functional form of the new surface includes dispersion forces by a double many-body expansion. Stationary point properties for the new surface are calculated along with the product-valley barrier maxima of vibrationally adiabatic potential curves for F + H2 - HF(nu-prime = 3) + H, F + HD - HF(nu-prime = 3) + D, and F + D2 - DF(nu-prime = 4) + D. The new surface should prove useful for studying the effect on dynamics of a low, early barrier with a wide, flat bend potential.

Lynch, Gillian C.↗
NASA NTRS2019

Omni-gravity Hydroponics for Space Exploration

As part of the NASA Plant Water Management technology demonstration experiments, a capillary fluidics hydroponic system that can function in a variety of gravity environments has been developed and tested for crop production in space. A passive liquid delivery method is employed that drastically reduces the number of contaminable moving parts providing a high reliability solution requiring minimal resources for operation. The terrestrial, lunar, and Martian environments are managed in a ‘gravity-dominated mode,’ while the low-gravity transit and orbit environments are managed in a ‘capillary fluidics mode,’ where the role of gravity is replaced by the equally passive effects of surface tension, conduit shape, and wettability. The unique considerations for priming, germination, aeration, nutrient supply, root accommodation, layout, crew interaction, etc. are highlighted. Design guides for system function are provided along with high Technology Readiness Level demonstrations of the system during terrestrial and drop tower tests. Long duration tests are planned on short schedule aboard the International Space Station in 2019.

gravity↗
NASA NTRS1990

Ductility enhancement from interface dislocation sources in a directionally solidified beta + gamma + gamma-prime Ni-Fe-Al composite alloy

A directionally solidified beta + gamma + gamma-prime Ni-Fe-Al in situ composite alloy of composition Ni50Fe30Al20 has been used to investigate the effect of a plastically soft second phase on the mechanical behavior of a B2 ordered intermetallic alloy. This material exhibits extensive plasticity during compressive deformation at room temperature and fails in shear with extensive gamma + gamma-prime lamellar or rod pullout. The material also exhibits about 10 percent tensile elongation to fracture at room temperature, with final fracture that includes substantial necking of the gamma + gamma-prime lamellae or rods. Observation of slip lines and dislocation substructures discloses that the normally brittle beta matrix undergoes extensive plasticity in order to deform compatibly with the more ductile gamma phase. The plasticity of the beta matrix is accomplished by the generation of glissile dislocations into the beta matrix from the beta/gamma interface region and is enhanced because of a favorable beta-gamma orientation relationship for slip transfer. Ductility enhancement from interface-generated mobile dislocations generated from beta-gamma interfaces is compared to that observed in film-coated beta-NiAl single crystals and FeAl polycrystals.

Larsen, M.↗
DOE OSTI2025

Non-dimensional performance and safety parameters for heat pipes

The use of heat pipes in safety-critical systems such as nuclear microreactors dictates the development of generalized, practical, scalable performance and safety parameters. Traditional dimensional metrics, while informative, lack the universality required for comparative analysis across varying designs and operating regimes. Here, this work introduces a comprehensive set of non-dimensional parameters to characterize heat pipe performance and safety, including capillary performance, effective thermal conductivity, response time, exergetic efficiency, allowable temperature gradients, allowable rate of temperature change, priming coefficients, and factor of safety. A reference heat pipe design representative of microreactor applications was analyzed via the developed parameters using both traditional analytical models and Sockeye simulations under transient and steady-state conditions. Sodium, potassium, and water were evaluated as working fluids to demonstrate the applicability of the framework across a broad temperature range. The proposed non-dimensional parameters effectively captured key thermal-hydraulic behaviors and safety concerns, as was demonstrated via Sockeye simulations. This framework supports the development of design optimization strategies, operational protocols, and safety assurance practices for advanced reactor systems and other high-reliability applications.

42 - ENGINEERING↗
NASA NTRS1984

Morphological changes of gamma prime precipitates in nickel-base superalloy single crystals

Changes in the morphology of the gamma prime precipitate were examined during tensile creep at temperatures between 927 and 1038 C in 001-oriented single crystals of a Ni-Al-Mo-Ta superalloy. In this alloy, which has a large negative misfit of -0.80%, the gamma prime particles link together during creep to form platelets, or rafts, which are aligned with their broad faces perpendicular to the applied tensile axis. The dimensions of the gamma and gamma prime phases were measured as directional coarsening developed in an attempt to trace the changing morphology under various stress levels. In addition, the effects of initial microstructure, as well as slight compositional variations, were related to raft development and creep properties. The results showed that directional coarsening of gamma prime began during primary creep, and under certain conditions, continued to develop after the onset of steady-state creep. The length of the rafts increased linearly with time up to a plateau region. The thickness of the rafts, however, remained equal to the initial gamma prime size at least up through the onset of tertiary creep; this is a clear indication of the stability of the finely-spaced gamma-gamma prime lamellar structure. It was found that the single crystals with the finest gamma prime size exhibited the longest creep lives, because the resultant rafted structure had a larger number of gamma-gamma prime interfaces per unit volume of material.

Mackay, R. A.↗
DOE OSTI2022

Evaluating the effectiveness of a camera-based detection system to support informed curtailment and minimize eagle fatalities at wind energy facilities

The American Wind Wildlife Institute (AWWI – now Renewable Energy Wildlife Institute, REWI) – was appointed prime awardee of DOE award number DE-EE0007880 to lead a team of scientists, wind developers, and technology manufacturers in a collaborative evaluation of the effectiveness of a technology intended to help reduce eagle collisions with wind turbines. IdentiFlight, developed by Renewable Energy Systems (RES) in collaboration with Boulder Imaging, is an autonomous aerial monitoring and detection system. REWI partnered with ecological consultants, Western Ecosystems Technology, Inc. (WEST), to independently evaluate the performance of IdentiFlight reducing eagle collision risk under a suite of environmental conditions relative to the performance of a Biomonitor (human observer-based) Program. The project objectives were to 1) evaluate how IdentiFlight compared to biomonitors in detecting and identifying eagles under a suite of environmental conditions and 2) use the observation data to model how IdentiFlight and biomonitors reduced the eagle fatality prediction through informed curtailment. Field testing was to take place at two geographically distinct wind farms over two field seasons at each wind farm with a study design appropriate for meta-analyses across sites and years.

17 WIND ENERGY↗
DOE OSTI2021

Evolution of {delta}ferrite in a CF3 cast stainless steel upon neutron irradiation to 3, 5, 10, 20, and 40 dpa

The microstructural evolution of delta ferrite in a CF3 cast stainless steel irradiated to 3, 5, 10, 20, and 40 dpa with two dose rates was studied with atom probe tomography (APT) and transmission electron mi-croscopy. Spinodal decomposition and G-phase precipitates induced by neutron irradiation and thermal aging were quantified systematically. The neutron irradiation significantly enhances the spinodal decom-position in delta ferrite as both the spinodal wavelength (i.e. a characteristic repeat distance) and am-plitude (i.e. magnitude of elemental concentration fluctuation) increase after irradiation. The wavelength only varies slightly when the dose increases from 5 to 40 dpa, while the amplitude increases dramatically from 10 to 20 dpa and starts to saturate before 20 dpa. The dose rate and irradiation temperature also have a notable effect on the spinodal wavelength and amplitude. The study shows that higher dose rate promotes a larger wavelength at given irradiation doses. Regarding the G-phase precipitates, a slightly lower irradiation temperature would result in a smaller mean size of G-phase precipitates, while a lower irradiation dose rate would lead to a larger G-phase precipitates at a given temperature and dose. Over-all, the spinodal decomposition and G-phase precipitates in the delta ferrite continue to evolve with the increasing dose beyond 10 dpa. This study confirms that the formation of G-phase precipitates at the in-terdomain region between alpha and alpha-prime is facilitated by the Si and Mo atoms rejected from Fe rich alpha phase and the Ni and Mn atoms rejected from Cr rich alpha-prime phase. Neutron irradiation plays a dominant role in the ferrite instability, and the effect of prior thermal aging at 400 degrees C for 10,000 hours is negligible as the dose is 3 dpa and above.

duplex stainless steel↗
DOE OSTI2025

Stemflow Hydrodynamics

Stemflow hydrodynamics is the study of water movement along the exterior surface area of plants. Its primary goal is to describe water velocity and water depth along the stem surface area. Its significance in enriching the rhizosphere with water and nutrients is not in dispute. Yet, the hydrodynamics of stemflow have been entirely overlooked. This review seeks to fill this knowledge gap by drawing from thin film theories to seek outcomes at the tree scale. The depth‐averaged conservation equations of water and solute mass are derived at a point. These equations are then supplemented with the conservation of momentum that is required to describe water velocities or relations between water velocities and water depth. Relevant forces pertinent to momentum conservation are covered and include body forces (gravitational effects), surface forces (wall friction), line forces (surface tension), and inertial effects. The inclusion of surface tension opens new vistas into the richness and complexity of stemflow hydrodynamics. Flow instabilities such as fingering, pinching of water columns into droplets, accumulation of water within fissures due to surface tension and their sudden release are prime examples that link observed spatial patterns of stemflow fronts and morphological characteristics of the bark. Aggregating these effects at the tree‐ and storm‐ scales are featured using published experiments. The review discusses outstanding challenges pertaining to stemflow hydrodynamics, the use of dynamic similarity and 3D printing to enable the interplay between field studies and controlled laboratory experiments.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1978

Role of back stress in the creep behavior of particle strengthened alloys

Recent developments in the interpolation of high-temperature steady-state creep results have introduced the concept that the stress dependence of the creep rate should be in terms of the effective stress referred to as the applied stress minus a back stress. This paper reports on back stresses taken from data on a gamma-prime-strengthened wrought nickel-base superalloy, an oxide dispersion-strengthened ODS nickel-base solid solution alloy, and an ODS nickel-base superalloy. The effect of air versus vacuum environments and the effect of dynamic changes in the strengthening microstructures on the magnitude of the back stress are assessed. The role of modulus normalization and the back stress correction in determining the true creep activation energy are examined. It is shown that the high values of the apparent stress exponent 'n' of the steady-state creep equation can be easily explained through a relationship between n, the true stress exponent of steady-state creep, and the stress which when subtracted from the applied stress results in the effective driving stress acting on the mobile dislocations during creep.

Purushothaman, S.↗
DOE OSTI2020

Evaluation of simulated soil carbon dynamics in Arctic-Boreal ecosystems

Given the magnitude of soil carbon stocks in northern ecosystems, and the vulnerability of these stocks to climate warming, land surface models must accurately represent soil carbon dynamics in these regions. We evaluate soil carbon stocks and turnover rates, and the relationship between soil carbon loss with soil temperature and moisture, from an ensemble of eleven global land surface models. We focus on the region of NASA's Arctic-Boreal vulnerability experiment (ABoVE) in North America to inform data collection and model development efforts. Models exhibit an order of magnitude difference in estimates of current total soil carbon stocks, generally under- or overestimating the size of current soil carbon stocks by greater than 50 PgC. We find that a model's soil carbon stock at steady-state in 1901 is the prime driver of its soil carbon stock a hundred years later—overwhelming the effect of environmental forcing factors like climate. The greatest divergence between modeled and observed soil carbon stocks is in regions dominated by peat and permafrost soils, suggesting that models are failing to capture the frozen soil carbon dynamics of permafrost regions. Using a set of functional benchmarks to test the simulated relationship of soil respiration to both soil temperature and moisture, we find that although models capture the observed shape of the soil moisture response of respiration, almost half of the models examined show temperature sensitivities, or Q10 values, that are half of observed. Significantly, models that perform better against observational constraints of respiration or carbon stock size do not necessarily perform well in terms of their functional response to key climatic factors like changing temperature. This suggests that models may be arriving at the right result, but for the wrong reason. The results of this work can help to bridge the gap between data and models by both pointing to the need to constrain initial carbon pool sizes, as well as highlighting the importance of incorporating functional benchmarks into ongoing, mechanistic modeling activities such as those included in ABoVE.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1973

Wheat classification exercise, using 11 June 1973, ERTS MSS data for Fayette County, Illinois (for CITARS task)

The prime emphasis was on classification of pixels in field centers, away from boundary effects. Results were encouraging in both training and test field centers for wheat and other major types of vegetation present. However, the location of fields was found to be a serious problem and it was even more difficult to select field-center pixels for fields of sizes less than 20 acres (or even larger, depending upon field shape) for use in the field-center analysis. The majority of fields in the segment are less than 20 acres in size. ERTS-1 data were received on 12 September 1973. Ground truth information and aerial photography were received on 9 and 15 September. The data were analyzed and processed digitally using the ERIM multispectral software system.

Malila, W. A.↗
NASA NTRS1988

Molten salt corrosion of SiC and Si3N4

Industrial systems such as heat engines and heat exchangers involve harsh environments. The structural materials are subjected to high temperatures as well as corrosive gases and condensed phases. Past experience with metal alloys has shown that these condensed phases can be particularly corrosive and are often the limiting factor in the operation of these systems. In a heat engine the most common condensed corrodent is Na2SO4 whereas in a heat exchanger an oxide slag may be present. The primary emphasis is on Na2SO4 induced corrosion, however, similarities and differences to oxide slag are also discussed. The extensive research on corrosion of metal alloys has led to understanding and controlling corrosion for these materials. Currently silicon based ceramics are prime candidates for the applications discussed. Therefore it is important to understand the effects of condensed phase deposits on this emerging class of high temperature materials. Both the thermodynamic and strength of the ceramic is also examined. Finally some control strategies for corrosion of silicon based ceramics are explored.

Jacobson, Nathan S.↗
NASA NTRS1991

Soft X Ray Telescope (SXT) focus error analysis

The analysis performed on the soft x-ray telescope (SXT) to determine the correct thickness of the spacer to position the CCD camera at the best focus of the telescope and to determine the maximum uncertainty in this focus position due to a number of metrology and experimental errors, and thermal, and humidity effects is presented. This type of analysis has been performed by the SXT prime contractor, Lockheed Palo Alto Research Lab (LPARL). The SXT project office at MSFC formed an independent team of experts to review the LPARL work, and verify the analysis performed by them. Based on the recommendation of this team, the project office will make a decision if an end to end focus test is required for the SXT prior to launch. The metrology and experimental data, and the spreadsheets provided by LPARL are used at the basis of the analysis presented. The data entries in these spreadsheets have been verified as far as feasible, and the format of the spreadsheets has been improved to make these easier to understand. The results obtained from this analysis are very close to the results obtained by LPARL. However, due to the lack of organized documentation the analysis uncovered a few areas of possibly erroneous metrology data, which may affect the results obtained by this analytical approach.

Ahmad, Anees↗