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At least 181 records · Page 10

Linear and nonlinear mechanical properties of a series of epoxy resins

The linear viscoelastic properties have been measured for a series of bisphenol-A-based epoxy resins cured with the diamine DDS. The linear viscoelastic master curves were constructed via time-temperature superposition of frequency dependent G-prime and G-double-prime isotherms. The G-double-prime master curves exhibited two sub-Tg transitions. Superposition of isotherms in the glass-to-rubber transition (i.e., alpha) and the beta transition at -60 C was achieved by simple horizontal shifts in the log frequency axis; however, in the region between alpha and beta, superposition could not be effected by simple horizontal shifts along the log frequency axis. The different temperature dependency of the alpha and beta relaxation mechanisms causes a complex response of G-double-prime in the so called alpha-prime region. A novel numerical procedure has been developed to extract the complete relaxation spectra and its temperature dependence from the G-prime and G-double-prime isothermal data in the alpha-prime region.

Curliss, D. B.↗

Scaling effects of defects in fiber-reinforced composites

Material defects may be introduced willingly or unwillingly during material manufacturing and structural component fabrication stages. Their presence in the material plays a dominant role in determining the material's strength and the associate failure mechanisms. In the sense that the size and the number of defects may increase with the volume of the material, the effect of dimensional scaling may manifest itself in the dependence of material strength on volume. Or, alternatively, there may exist a scaling effect of material defects. In fiber-reinforced composites, manufacturing or fabrication defects may come in several forms: matrix voids, matrix microcracks, fiber misalignment, broken fibers, or interface disbonds, just to mention a few. These are interacting and competing defects in the sense that one type of defect may become dominant under one stress condition and another type of defect may become dominant under a different stress condition. This happens because the fiber reinforcement network, together with the distribution of defects, constitutes the prime microstructure of the composite, and there exist continued interactions between the evolving microstructure and the distribution of defects. In the process, the scaling effects of defects are complicated by this interaction. In this presentation, the scaling effects of defects in fiber-reinforced composites will be briefly discussed with the introduction of the concept of effective defects. It is then shown with the aid of some actual experimental and analysis results that the scaling effects are very much present, but they are regulated by the characteristic dimension of the composite microstructure due to the aforementioned microstructure-defect interaction effect.

Wang, A. S. D.↗

Spatial acquisition of optical sources in the presence of intense interference

The problem of spatially acquiring an optical beacon in the presence of intense optical interference is considered. It is demonstrated that conventional acquisition procedures cannot establish acceptable levels of acquisition probability when competing with strong optical interference without requiring unreasonable amounts of prime power. As a possible solution, it is shown that a more sophisticated acquisition scheme can virtually eliminate the effects of optical interference while requiring only a modest increase in system complexity.

Vilnrotter, V. A.↗

An ab initio calculation of the zero-field splitting parameters of the 3A-double prime state of formaldehyde

The spin dipole-dipole and spin-orbit contributions to the zero-field splitting of the 3A-double prime state of formaldehyde have been evaluated at the excited state experimental geometry. Ab initio CI wave functions were generated from a Dunning double zeta plus polarization bases set using 3A-double prime rhf orbitals. Twelve states of each symmetry were used to evaluate the second-order spin-orbit effect. The resulting values of D and E were 0.19 and 0.03 kayser with the principal magnetic axes rotated 36 deg from the CO bond. The values of alpha and beta relative to the inertial axes were calculated to be 0.03 and 0.01 kayser compared to the experimental values of 0.05 plus or minus 0.01 and 0.02 plus or minus 0.02 kayser.

Davidson, E. R.↗

Advanced pointing systems for space astronomy

It is noted that the requirements on image stability are increasing, often at the same time that instrument external disturbances are increasing. A prime example of this is the pointing of large diameter optics from the Shuttle bay. To achieve cost-effective advanced pointing systems in the face of these problems, a system approach must be followed, one that encompasses a realistic assessment of requirements, the best possible detector technology, and a broad look at space vehicles and pointing systems that are available. By way of example, a rocket instrument for making measurements of the interstellar gas that uses a standard pointing system to achieve a spectral resolution of 2 x 10 to the 5th is described. It is noted that the use of a free-flying instrument avoids the high-frequency components that degrade the instrument resolution.

Delamere, W. A.↗

Facular Limb-darkening Functions for Irradiance Modeling

The limb darkening function of faculae is an important factor in estimating facular contributions to solar irradiance variations. The existing photometric data is reviewed and a synthetic limb darkening function for faculae was generated which was compared with the limb darkening functions currently in use for irradiance modeling. The excess facular flux ranges from 0.017 to 0.0349 of the solar photospheric flux for the various representations. The present limitation appears to be the lack of comprehensive photometric data. The representations are especially varied near the limb, where photometry is most difficult. Synoptic data on calcium plage areas is used as a substitute for facular areas in modeling. Based upon the existing data, the present best value for the effect of faculae on the solar constant is given by delta s/s = 3.9 x 10(-8) A (sub plage prime) for an active region near disk center, where A (sub plage) is the calcium plage area in millionths of a solar hemisphere.

Hirayama, T.↗

The effect of tantalum on the structure/properties of two polycrystalline nickel-base superalloys: B-1900 + Hf MAR-M247

The microstructure, phase compositions, and phase fractions were studied in conventionally cast B-1900 + Hf and both conventionally cast and directionally solidified MAR-M247 as a function of tantalum concentration. The hot tensile and creep rupture properties of the solutionized and aged MAR-M247-type alloys were also determined as a function of tantalum level. The effects of tantalum on the microstructure and phase compositions of B-1900 + Hf and MAR-M247 (conventionally cast and directionally solidified) were found to be very similar. The addition of tantalum to the as cast and heat treated alloys was shown to cause the partial replacement of the Hf in the MC carbides by Ta, although the degree of replacement was decreased by the solutionizing and aging heat treatment. The gamma prime and minor phase fractions (primarily MC type carbides) both increased approximately linearly with tantalum concentration. The gamma prime phase compositions were relatively insensitive to tantalum variations with the exception of the tantalum and/or hafnium levels. Bulk tantalum additions increased the tantalum, chromium, and cobalt levels of the gamma phase in both alloy series. The increase in the concentrations of the latter two elements in the gamma phase was a result of the decrease in the gamma phase fraction with increasing bulk tantalum concentration and constant gamma/gamma prime partitioning ratio. Tantalum additions increased the yield stress and ultimate tensile strength of the directionally solidified MAR-M247 type alloys and had no significant effect on ductility.

Janowski, G. M.↗

Refinement of Promising Coating Compositions for Directionally Cast Eutectics

The successful application of high creep strength, directionally solidified gamma/gamma prime-delta (Ni-19.7Cb-6Cr-2.5Al) eutectic superalloy turbine blades requires the development of suitable coatings for airfoil, root and internal blade surfaces. In order to improve coatings for the gamma/gamma prime-delta alloy, the current investigation had the goals of (1) refining promising coating compositions for directionally solidified eutectics, (2) evaluating the effects of coating/ substrate interactions on the mechanical properties of the alloy, and (3) evaluating diffusion aluminide coatings for internal surfaces. Burner rig cyclic oxidation, furnace cyclic hot corrosion, ductility, and thermal fatigue tests indicated that NiCrAlY+Pt(63 to 127 micron Ni-18Cr-12Al-0.3Y + 6 micron Pt) and NiCrAlY(63 to 127 micron Ni-18Cr-12Al-0.3Y) coatings are capable of protecting high temperature gas path surfaces of eutectic alloy airfoils. Burner rig (Mach 0.37) testing indicated that the useful coating life of the 127 micron thick coatings exceeded 1000 hours at 1366 K (2000 deg F). Isothermal fatigue and furnance hot corrosion tests indicated that 63 micron NiCrAlY, NiCrAlY + Pt and platinum modified diffusion aluminide (Pt + Al) coating systems are capable of protecting the relatively cooler surfaces of the blade root. Finally, a gas phase coating process was evaluated for diffusion aluminizing internal surfaces and cooling holes of air-cooled gamma/gamma prime-delta turbine blades.

Strangman, T. E.↗

Skeletal unloading induces resistance to insulin-like growth factor I

In previous studies with a hindlimb elevation model, we demonstrated that skeletal unloading transiently inhibits bone formation. This effect is limited to the unloaded bones (the normally loaded humerus does not cease growing), suggesting that local factors are of prime importance. IGF-I is one such factor; it is produced in bone and stimulates bone formation. To determine the impact of skeletal unloading on IGF-I production and function, we assessed the mRNA levels of IGF-I and its receptor (IGF-IR) in the proximal tibia and distal femur of growing rats during 2 weeks of hindlimb elevation. The mRNA levels for IGF-I and IGF-IR rose during hindlimb elevation, returning toward control values during recovery. This was accompanied by a 77% increase in IGF-I levels in the bone, peaking at day 10 of unloading. Changes in IGF binding protein levels were not observed. Infusion of IGF-I (200 micrograms/day) during 1 week of hindlimb elevation doubled the increase in bone mass of the control animals but failed to reverse the cessation of bone growth in the hindlimb-elevated animals. We conclude that skeletal unloading induces resistance to IGF-I, which may result secondarily in increased local production of IGF-I.

NASA Center ARC↗

Low-energy electron effects on tensile modulus and infrared transmission properties of a polypyromellitimide film

Infrared (IR) spectroscopy and tensile modulus testing were used to evaluate the importance of experimental procedure on changes in properties of pyromellitic dianhydride-p,p prime-oxydianiline film exposed to electron radiation. The radiation exposures were accelerated, approximate equivalents to the total dose expected for a 30 year mission in geosynchronous Earth orbit. The change in the tensile modulus depends more on the dose rate and the time interval between exposure and testing than on total dose. The IR data vary with both total dose and dose rate. A threshold dose rate exists below which reversible radiation effects on the IR spectra occur. Above the threshold dose rate, irreversible effects occur with the appearance of a new band. Post-irradiation and in situ IR absorption bands are significantly different. It is suggested that the electron radiation induced metastable, excites molecular states.

Ferl, J. E.↗

Satellite contributions to convective scale weather analysis and forecasting

Severe weather phenomena which are amenable to remote sensing by satellite instruments and having resolution fine enough to discern mesoscale features are described. GOES satellites acquire imagery with 1 km resolution in the visible band and 8 km at IR wavelengths. Animation of the images allows tracking the evolution and motions of clouds, which are the prime indicators of convective activity. Sample satellite imagery of sea, lake and river breezes which reveal differential heating processes, the effect of early morning cloud cover, thunderstorm outflow processes, and mesoscale convective systems are provided. Techniques for analyzing the satellite data to predict the onset of severe weather are discussed.

Purdom, James F. W.↗

Creep behavior of tungsten/niobium and tungsten/niobium-1 percent zirconium composites

A study was conducted to determine the feasibility of using tungsten fiber reinforced niobium or niobium-1 percent zirconium matrix composites to meet the anticipated increased temperature and creep resistance requirements imposed by advanced space power systems. The results obtained on the short time tensile properties indicated that W/Nb composites showed significant improvements in high temperature strength and offer significant mass reductions for high temperature space power systems. The prime material requirement for space power systems applications is long time creep resistance. A study was conducted to determine the effect of high temperature exposure on the properties of these composites, with emphasis upon their creep behavior at elevated temperatures.

Petrasek, D. W.↗

Microstructure-property relationships in directionally solidified single-crystal nickel-base superalloys

This paper discusses some of the microstructural features which influence the creep properties of directionally solidified and single-crystal nickel-base superalloys. Gamma prime precipitate size and morphology, gamma-gamma (prime) lattice mismatch, phase instability, alloy composition, and processing variations are among the factors considered. Recent experimental results are reviewed and related to the operative deformation mechanisms and to the corresponding mechanical properties. Special emphasis is placed on the creep behavior of single-crystal superalloys at high temperatures, where directional gamma (prime) coarsening is prominent, and at lower temperatures, where gamma (prime) coarsening rates are significantly reduced. It can be seen that very subtle changes in microstructural features can have profound effects on the subsequent properties of these materials.

Mackay, Rebecca A.↗

A Prognostic Launch Vehicle Probability of Failure Assessment Methodology for Conceptual Systems Predicated on Human Causal Factors

Lessons learned from past failures of launch vehicle developments and operations were used to create a new method to predict the probability of failure of conceptual systems. Existing methods such as Probabilistic Risk Assessments and Human Risk Assessments were considered but found to be too cumbersome for this type of system-wide application for yet-to-be-flown vehicles. The basis for this methodology were historic databases of past failures, where it was determined that various faulty human-interactions were the predominant root causes of failure rather than deficient component reliabilities evaluated through statistical analysis. This methodology contains an expert scoring part which can be used in either a qualitative or a quantitative mode. The method produces two products: a numerical score of the probability of failure and guidance to program management on critical areas in need of increased focus to improve the probability of success. In order to evaluate the effectiveness of this new method, data from a concluded vehicle program (USAF's Titan IV with the Centaur G-Prime upper stage) was used as a test case. The theoretical vs. actual probability of failure was found to be 4.46% vs. 6.67% respectively. Recommendations are made for future applications of this method to ongoing launch vehicle development programs.

Launch Vehicle↗

Prognostic Launch Vehicle Probability of Failure Assessment Methodology for Conceptual Systems Predicated on Human Causal Factors

Lessons learned from past failures of launch vehicle developments and operations were used to create a new method to predict the probability of failure of conceptual systems. Existing methods such as Probabilistic Risk Assessments and Human Risk Assessments were considered but found to be too cumbersome for this type of system-wide application for yet-to-be-flown vehicles. The basis for this methodology were historic databases of past failures, where it was determined that various faulty human-interactions were the predominant root causes of failure rather than deficient component reliabilities evaluated through statistical analysis. This methodology contains an expert scoring part which can be used in either a qualitative or a quantitative mode. The method produces two products: a numerical score of the probability of failure or guidance to program management on critical areas in need of increased focus to improve the probability of success. In order to evaluate the effectiveness of this new method, data from a concluded vehicle program (USAF's Titan IV with the Centaur G-Prime upper stage) was used as a test case. Although the theoretical vs. actual probability of failure was found to be in reasonable agreement (4.46% vs. 6.67% respectively) the underlying sub-root cause scoring had significant disparities attributable to significant organizational changes and acquisitions. Recommendations are made for future applications of this method to ongoing launch vehicle development programs.

Craig H Williams↗

Structure-property effects of tantalum additions to nickel-base superalloys

The characterization of the effect of Ta on the structure of Ni base superalloys, the determination of the effects of Ta (structure) variations on the mechanical, thermal, and oxidation behavior, and the identification of alloying elements which have potential as substitutes for Ta are investigated. Mar M247 type alloys are emphasized; nominal and analyzed compositions of ten alloys under study are given. X-ray and composition analysis are being used to determine the partitioning of alloying elements between gamma, gamma primes, and MC (cubic) as a function of Ta content. The diffusional interactions of the Mar M247-type alloys with as cast beta + gamma alloys are studied to determine the effects of Ta on alloy/coating degradation.

Heckel, R. W.↗

Is there any record of meteorite impact in the Archean rocks of North America

Current speculations on the early impact history of the earth between 4.5 and 3.0 billion years ago range from simple analogies between mare basalts and Archean terrestrial greenstones to casual dismissal. The latter is based on the view that the high rate of convection in the Archean would have obliterated the effects of impact via plate tectonic processes. In the present paper it is suggested that the impact process may have been the prime control on localizing the convection process. The Superior Province and basin-in-basin structure within it may be a record of such localized convection.

Weiblen, P. W.↗

Flare observation during Max 1991 balloon campaigns

A brief overview is presented for some of the large flare properties as observed during the prime SMM flare observation interval, 1980 to 1984. Two of these properties, namely their tendency to occur in groups and the strong effects of the 154 day periodicity, can be used to increase the probability of detecting large flares during the limited observing duration of Max 1991 balloon campaigns provided the solar flare characteristics of the 1991 solar cycle follows that observed in 1980 to 1984.

Forrest, David J.↗