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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10

Giotto Ion Mass Spectrometer Measurements at Comet P/Grigg-Skjellerup

The Giotto Ion Mass Spectrometer High Intensity Spectrometer (IMS-HIS) measured fluxes of ions from about 260,000 km before (10:08:37 UT spacecraft time) to about 86,000 km after (17:01:33 UT spacecraft time) closest approach to comet P/Grigg- Skjellerup during the encounter on July 10, 1992. Although the HIS sensor was not designed to measure protons, the unusual flyby geometry at Grigg-Skjellerup allowed the sensor to detect these ions. Considerable temporal structure appears in the data, well- correlated with the data of other instruments onboard, especially those of the magnetometer. In particular, the proton count rate correlates with the direction of the magnetic field.

Rosenbauer, H.↗

Condensation cyclization reactions of electron deficient aromatics. 4: Tricyclic nitropropene nitronates from the reaction of phloroglucinol and cycloalkanones with sym-trinitrobenzene

Interesting similarities have been shown between the reactions of sym-trinitrobenzene with cycloalkanones, and with phloroglucinol. Previously unsuspected common intermediates have been shown to intervene. The structurally similar products in each case are tricyclic nitropropene nitronates. Protonation of these yields the corresponding nitronic acids in certain instances.

Strauss, M. J.↗

Energetic protons accelerated at corotating shocks - Pioneer 10 and 11 observations from 1 to 6 AU

Vector helium magnetometer and proton telescope data are used to examine the relationship between low energy proton increases and corotating interaction regions (CIRs). A general correlation is noted between the maximum CIR field intensity and the maximum proton count rate. The minimum proton flux, located between the two proton maxima, appears to be correlated with the maximum field strength of the CIR. The evidence presented strongly supports shock acceleration as the primary source of the 1-MeV protons. A schematic figure incorporating many of the features deduced in the present study is given to illustrate the relationship between energetic protons, forward and reverse shocks, and the interplanetary magnetic field structure. The predictions of various theories and mechanisms for interplanetary nucleon acceleration are discussed in light of the experimental results presented.

Tsurutani, B. T.↗

Radiation measurements in low Earth orbit: U.S. and Russian results

The radiation environment in low-Earth orbital flights is complex. It is strongly influenced by altitude, orbital inclination, time within a given solar cycle, flight duration, and shielding configuration. At any specified shielded location, both primary and secondary particles generated by nuclear interactions of primary particles with spacecraft structure are present. In addition, there are atmospheric secondary albedo protons and neutrons. No single detector can adequately measure this complex radiation field, and measurements of very high linear energy transfer target fragmentation products are particularly difficult. Crew radiation exposure have exclusively been measured using passive thermoluminescent detectors (TLDs). The cosmonaut exposures on the Mir station, uncorrected for the TLD inefficiency and neutron contribution, have varied from a low of 2.43 cGy to a high of 8.70 cGy. These correspond to dose rates of 144 microGy d(-1) to 468 microGy d(-1). These are consistent with rates observed by the D2 ion-chamber. Using the rates measured by the D1 chamber, dose rates under 4 cm of water vary from about 60 microGy d-1 to about 350 microGy d(-1). There is variation of about a factor of two between the dose rates at various locations in the same module. There is also a variation of dose rates of about a factor two between various modules. The highest astronaut dose for a Shuttle flight (STS-82) was 3.205 cGy with a dose rate of 3,221 microGy d(-1). Neutron contribution could be 36 +/- 15% of the astronaut charged particle dose equivalent. East-West asymmetry of dose rate is significant for spacecrafts that fly in an fixed altitude, such as the International Space Station.

NASA Center JSC↗

Liquid Phase Deposition of Single-Phase Alpha-Copper-Indium-Diselenide

The success of exploratory missions in outer space often depends on a highly efficient renewable energy supply, as provided by solar cells. Since future missions will demand large aggregates of solar cells, and space flight is expensive, the solar cells must furthermore be available at low costs and have a long lifetime and high resistance against structural damage introduced by irradiation with high energy electrons and protons. The photovoltaic materials that are presently available only partly fulfill all these requirements. Therefore, we propose to explore a new method for fabricating thin-films for cost-efficient solar cells with very high specific power,high irradiation resistance and long lifetime based on the alpha-phase of the Cu-In-Se system "alpha-CIS."

Hepp, Aloysius F.↗

Helium vs. Proton Induced Displacement Damage in Electronic Materials

In this project, the specific effects of displacement damage due to the passage of protons and helium nuclei on some typical electronic materials will be evaluated and contrasted. As the electronic material absorbs the energetic proton and helium momentum, degradation of performance occurs, eventually leading to overall failure. Helium nuclei traveling at the same speed as protons are expected to impart more to the material displacement damage; due to the larger mass, and thus momentum, of helium nuclei compared to protons. Damage due to displacement of atoms in their crystalline structure can change the physical properties and hence performance of the electronic materials.

Ringo, Sawnese↗

A Deterministic Electron, Photon, Proton and Heavy Ion Radiation Transport Suite for the Study of the Jovian System

A deterministic suite of radiation transport codes, developed at NASA Langley Research Center (LaRC), which describe the transport of electrons, photons, protons, and heavy ions in condensed media is used to simulate exposures from spectral distributions typical of electrons, protons and carbon-oxygen-sulfur (C-O-S) trapped heavy ions in the Jovian radiation environment. The particle transport suite consists of a coupled electron and photon deterministic transport algorithm (CEPTRN) and a coupled light particle and heavy ion deterministic transport algorithm (HZETRN). The primary purpose for the development of the transport suite is to provide a means for the spacecraft design community to rapidly perform numerous repetitive calculations essential for electron, proton and heavy ion radiation exposure assessments in complex space structures. In this paper, the radiation environment of the Galilean satellite Europa is used as a representative boundary condition to show the capabilities of the transport suite. While the transport suite can directly access the output electron spectra of the Jovian environment as generated by the Jet Propulsion Laboratory (JPL) Galileo Interim Radiation Electron (GIRE) model of 2003; for the sake of relevance to the upcoming Europa Jupiter System Mission (EJSM), the 105 days at Europa mission fluence energy spectra provided by JPL is used to produce the corresponding dose-depth curve in silicon behind an aluminum shield of 100 mils ( 0.7 g/sq cm). The transport suite can also accept ray-traced thickness files from a computer-aided design (CAD) package and calculate the total ionizing dose (TID) at a specific target point. In that regard, using a low-fidelity CAD model of the Galileo probe, the transport suite was verified by comparing with Monte Carlo (MC) simulations for orbits JOI--J35 of the Galileo extended mission (1996-2001). For the upcoming EJSM mission with a potential launch date of 2020, the transport suite is used to compute the traditional aluminum-silicon dose-depth calculation as a standard shield-target combination output, as well as the shielding response of high charge (Z) shields such as tantalum (Ta). Finally, a shield optimization algorithm is used to guide the instrument designer with the choice of graded-Z shield analysis.

Norman, Ryan B.↗

Effects of proton irradiation on luminescence and carrier dynamics of self-assembled III-V quatum dots

The effects of proton irradiation (1.5 MeV) on photoluminescence intensities and carrier dynamics were compared between III-V quantum dots and similar quantum well structures. A significant enhancement in radiation tolerance is seen with three-dimensional quantum confinement. Measurements were carried out in different quantum dot (QD) structures, varying in material (InGaAs/GaAs and InAlAs/AlGaAs), QD surface density (4x10^8 to 3x10'^10 cm^-2), and substrate orientation [(100) and (311) B]. Similar trends were observed for all QD samples. A slight increase in PL emission after low to intermediate proton doses, are also observed in InGaAs/GaAs (100) QD structures. The latter is explained in terms of more efficient carrier transfer from the wetting layer via radiation-induced defects.

nanotechnology DLTS optical properties pn diodes q↗

EFFECT OF SPACE ENVIRONMENT ON PHOTOVOLTAIC CELLS

A series of theoretical calculations have been performed concerning inelastic nuclear interactions between incident high energy protons and silicon. The results of these calculations, summarized here, indicate that, above incident proton energies of about 20 Mev, the primary defect production mechanism is inelastic nuclear interactions. Additional evidence is presented which indicates that the defect structures produced by these inelastic nuclear interactions are significantly more complicated than those produced by electron and lower energy proton induced elastic nuclear interactions. Based on these phenomena, it is shown that high energy proton experimental damage data on silicon photovoltaic devices obtained at low illumination intensities cannot be applied directly to spacecraft photovoltaic power supply systems designed to operate at the illumination levels existing in space.

SILICON↗

Energetic charged particles in Saturn's magnetosphere - Voyager 1 results

Voyager 1 provided the first look at Saturn's magnetotail and magnetosphere during relatively quiet interplanetary conditions. This report discusses the energetic particle populations of the outer magnetosphere of Saturn and absorption features associated with Titan and Rhea, and compares these observations with Pioneer 11 data of a year earlier. The trapped proton fluxes had soft spectra, represented by power laws in kinetic energy with an exponent of 7 in the outer magnetosphere and 9 in the magnetotail. Structure associated with the magnetotail was observed as close as 10 Saturn radii on the outbound trajectory. The proton and electron fluxes in the outer magnetosphere and in the magnetotail were variable and appeared to respond to changes in interplanetary conditions. Protons with energies greater than or approximately equal to 2 MeV had free access to the magnetosphere from interplanetary space and were not stably trapped outside about 7.5 Saturn radii.

Vogt, R. E.↗

Proton exchange membrane fuel cells for space and electric vehicle applications: From basic research to technology development

The proton exchange membrane fuel cell (PEMFC) is one of the most promising electrochemical power sources for space and electric vehicle applications. The wide spectrum of R&D activities on PEMFC's, carried out in our Center from 1988 to date, is as follows (1) Electrode Kinetic and Electrocatalysis of Oxygen Reduction; (2) Optimization of Structures of Electrodes and of Membrane and Electrode Assemblies; (3) Selection and Evaluation of Advanced Proton Conducting Membranes and of Operating Conditions to Attain High Energy Efficiency; (4) Modeling Analysis of Fuel Cell Performance and of Thermal and Water Management; and (5) Engineering Design and Development of Multicell Stacks. The accomplishments on these tasks may be summarized as follows: (1) A microelectrode technique was developed to determine the electrode kinetic parameters for the fuel cell reactions and mass transport parameters for the H2 and O2 reactants in the proton conducting membrane. (2) High energy efficiencies and high power densities were demonstrated in PEMFCs with low platinum loading electrodes (0.4 mg/cm(exp 2) or less), advanced membranes and optimized structures of membrane and electrode assemblies, as well as operating conditions. (3) The modeling analyses revealed methods to minimize mass transport limitations, particularly with air as the cathodic reactant; and for efficient thermal and water management. (4) Work is in progress to develop multi-kilowatt stacks with the electrodes containing low platinum loadings.

Srinivasan, Supramaniam↗

Energetics of the protonation of CO - Implications for the observation of HOC(+) in dense interstellar clouds

A number of molecular species on the H3CO(+) energy hypersurface is examined. Ab initio molecular orbital theory is used to determine the structures and relative energetics of the two isomers of HCO(+) and HOC(+) together with the affinity of CO for protonation at either end. The proton affinities of H2 and H2CO are also examined. The calculations are performed using large basis sets and include the effects of electron correlation. The calculated vibrational frequencies are used to correct for zero point energy differences. The results show that the proton affinities of H2 and CO to form HOC(+) are within 1 kcal of each other. The calculations demonstrate that there is no thermodynamic driving force to form HOC(+) in collisions of H3(+) with CO, and that the formation of HCO(+) in such collisions is very exoergic. A plausible mechanism is suggested to explain the differences observed between the laboratory and the interstellar medium.

Dixon, D.↗

PEM regenerative fuel cells

This paper will update the progress in developing electrocatalyst systems and electrode structures primarily for the positive electrode of single-unit solid polymer proton exchange membrane (PEM) regenerative fuel cells. The work was done with DuPont Nafion 117 in complete fuel cells (40 sq cm electrodes). The cells were operated alternately in fuel cell mode and electrolysis mode at 80 C. In fuel cell mode, humidified hydrogen and oxygen were supplied at 207 kPa (30 psi); in electrolysis mode, water was pumped over the positive electrode and the gases were evolved at ambient pressure. Cycling data will be presented for Pt-Ir catalysts and limited bifunctional data will be presented for Pt, Ir, Ru, Rh, and Na(x)Pt3O4 catalysts as well as for electrode structure variations.

Swette, Larry L.↗

The variation of protons, alpha particles, and the magnetic field across the bow shock of Comet Halley

Data from the Ion Mass Spectrometer and the magnetometer on the Giotto spacecraft are used to examine the structure of the inbound crossing of the Comet Halley bow shock on March 13, 1986. It is found that the velocity decrease, the field strength increase, and the heating of picked up cometary protons occurred over a broad region corresponding to several heavy-ion gyroradii. The solar-wind protons and alphas, on the other hand, were compressed and heated at a narrow structure on the leading edge of the broad shock region.

Neugebauer, M.↗

Periodic Solar Wind Structures Observed in Measurements of Elemental and Ionic Composition in situ at L1

Mesoscale periodic structures observed in solar wind plasma serve as an important diagnostic tool for constraining the processes that govern the formation of the solar wind. These structures have been observed in situ and in remote data as fluctuations in proton and electron density. However, only two events of this type have been reported regarding the elemental and ionic composition. Composition measurements are especially important in gaining an understanding of the origin of the solar wind as the composition is frozen into the plasma at the Sun and does not evolve as it advects through the heliosphere. Here, we present the analysis of four events containing mesoscale periodic solar wind structure during which the Iron and Magnesium number density data, measured by the Solar Wind Ion Composition Spectrometer (SWICS)on board the Advanced Composition Explorer spacecraft, are validated at statistically significant count levels. We use a spectral analysis method specifically designed to extract periodic signals from astrophysical time series and apply it to the SWICS 12-minute native resolution dataset. We find variations in the relative abundance of elements with low first ionization potential, mass dependencies, and charge state during time intervals in which mesoscale periodic structures are observed. These variations are linked to temporal or spatial variations in solar source regions and put constraints on the solar wind formation mechanisms that produce them. Techniques presented here are relevant for future, higher-resolution studies of data from new instruments such as Solar Orbiter’s Heavy Ion Sensor.

Irena Gershkovich↗

A macroscopic profile of the typical quasi-perpendicular bow shock - Isee 1 and 2

A macroscopic examination of field and particle properties of the bow shock recorded on November 5, 1977, identified earlier as stable features by comparison of Isee 1 and 2 data, is presented. Attention is given to the extent to which the shock was in a typical state, and multidiagnostic observations are combined to define the shock profile. It is found that the shock profile offered several unanticipated structural features, which include a variable directional profile of the reflected proton group passing through the front, an electrostatic boundary effect associated with the reflected protons upstream, and an oscillatory buildup of proton thermalization behind the overshoot portion of the shock signature.

Greenstadt, E. W.↗