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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Advanced sorbents for modular oxygen production for REMS gasifiers

Under a DOE funded effort, Thermosolv LLC has been developing a sorbent-based oxygen production technology for gasification and oxy-combustion applications. The sorbents utilize oxygen-storage properties of certain perovskites to (1) selectively adsorb oxygen at moderate temperature from compressed air and (2) release the adsorbed oxygen into a vacuum or a sweep gas such as CO2 and/or steam. Through cyclic operations of multiple sorbent beds such a process can be made continuous. Pressure drop across the sorbent bed and other similar design considerations dictate that the sorbent be in the form of a high surface-area-to-volume pellet and yet still possess sufficient crush strength and integrity. Process efficiency is determined by the sorption and desorption kinetics and sorbent capacity. Typical process involves cycle times in the order of 100 seconds, a time too short to fully utilize the full volume of the sorbent and the sorption capacity of the sorbent pellets. As a part of this project, Thermosolv LLC undertook the development of oxygen sorbents as a high-surface area supported sorbent on a light-weight inert support to (1) reduce the cost, (2) increase the productivity, and (3) reduce the overall weight of the reactor. Using a previously developed perovskite (LSCF 1991) with its well-characterized performance, composite sorbent pellets each consisting of an inert core coated by a thin layer of the functional perovskite material were produced. Several low-density, inexpensive inert solids supports in the 1/8”-1/4” size were selected to keep the pressure drop across the sorbent bed in the acceptable range. A number of commercial technologies including spray coating, dip coating, incipient impregnation of porous substrate followed by thermal annealing at various temperatures and duration were employed and tested to produce robust composite supported sorbent pellets. A sense of optimum coating thickness was developed by testing sorbent pellets of various increasing diameter pellets. LSCF-1991extrudates ranging in size from 1/32” to 3/16” were tested in a TGA and in a fixed-bed pressure swing test set-up for sorption/desorption cycles of interest. The data show that for the operational conditions of interest the coating thickness for a supported sorbent pellet needs to be approximately 1/32” (about 0.8 mm). Subsequent work thereby concentrated on developing composite pellets of various substrates, shapes and sizes with coating layer of about this size range. Candidate support materials were chosen based on cost, inertness, mechanical strength, thermal expansion and chemical stability with sorbent material, and in a size range to give an acceptable pressure drop in fixed-bad reactor configurations. Coating application methods used for application of the sorbent onto the support included precipitation, spray coating and dip coating from sorbent slurries and sol gels. For all coated supports where we could successfully apply a uniform coating of desired thickness with an acceptable handling performance in terms of exfoliation, TGA-based cyclic sorption/desorption testing was performed to determine cycling capacity of oxygen. Among nearly twenty different support materials tested, best adhesion performance was obtained from stainless saddle supports. In the bench-scale fixed-bad tests stainless steel saddle support composite pellets with a coating thickness in the 0.6 mm or so range, the composite sorbent pellet performance approached up to 95% of that of the 2 mm parent material pellets. In a parallel approach to reducing the cost of the sorbent, alternate sorbent formulations replacing/reducing the amount of cobalt in the LSCF family were also investigated. Successful formulations that could match the performance of LSCF 1991 were identified based on TGA cyclic tests as LSCF 1919 and LSF 1910. In the range of operational envelop of cycle times and other relevant process operating conditions, the reduced Co formulations showed comparable performance in the bench-scale fixed-bad cyclic operations. As a part of this project, we also attempted substitution of La and Sr with Ca and Ba, and Co with Mn, Ni and Cu with little success, but the overall project goal of reducing sorbent cost in terms of raw material and manufacturing expenses was successful.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2023

An Infinite Domain 3D Poisson Solver Based on the Barnes-Hut Algorithm

We present a domain decomposition method for the solution of the 3D Poisson equation with infinite domain boundary conditions. The method is based on an application of the Barnes-Hut tree particle scheme adapted to gridded data. Long range interactions are computed using the first two terms in the Cartesian multipole expansion of Green’s function convoluted with the charge while short range computations are performed using Hockney’s domain doubling algorithm. A standard domain decomposition strategy requires O(N 2 ) applications of Hockney’s algorithm, where N is the number of subdomains that intersect that charge support, while in the present approach only O(Nlog 2 N) such computations suffice. The discretization scheme employed is a sixth order Mehrstellen approximation of the 3D Laplace opera tor. The method exhibits satisfactory accuracy at a substantially reduced computational cost compared to the full domain decomposition Hockney’s algorithm.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2026

Skewness-dependent moments of the pion GPD from nonlocal quark-bilinear correlators

We present lattice QCD calculations of the odd Mellin moments of pion valence-quark generalized parton distribution up to fifth order ⟨𝑥 4 ⟩ and for the skewness range [−0.33, 0] using operator product expansion of bilocal quark-bilinear operators. The calculations are performed on an ensemble with lattice spacing 𝑎 = 0.04 fm and valence pion mass 300 MeV, employing boosted pion states with momenta up to 2.428 GeV and momentum transfers reaching 2.748 GeV 2 . We employ ratio-scheme renormalization and next-to-leading logarithmic resummed perturbative matching. At zero skewness, our results are consistent with previous lattice studies. By combining matrix elements at multiple values of skewness and momentum transfer, skewness-dependent moments are obtained through simultaneous polynomiality-constrained fits.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Capacitive response of biological membranes

We present a minimal model to analyze the capacitive response of a biological membrane subjected to a step voltage via blocking electrodes. Through a perturbative analysis of the underlying electrolyte transport equations, we show that the leading-order relaxation of the transmembrane potential is governed by a capacitive timescale, τ_{C}=λ_{D}L/D(2+Γδ^{M}/L/4+Γδ^{M}/λ_{D}), where λ_{D} is the Debye screening length, L is the electrolyte width, Γ is the ratio of the permittivity of the electrolyte to the membrane, δ^{M} is the membrane thickness, and D is the ionic diffusivity. This timescale is considerably shorter than the traditional RC timescale λ_{D}L/D for a bare electrolyte due to the membrane's low permittivity and finite thickness. Beyond the linear regime, however, salt diffusion in the bulk electrolyte drives a secondary, nonlinear relaxation process of the transmembrane potential over a longer timescale τ_{L}=L^{2}/4π^{2}D. A simple equivalent-circuit model accurately captures the linear behavior, and the perturbation expansion remains applicable across the entire range of observed physiological transmembrane potentials. Together, these findings underscore the importance of the faster capacitive timescale and nonlinear effects on the bulk diffusion timescale in determining transmembrane potential dynamics for a range of biological systems.

Farhadi, Jafar↗
DOE OSTI2020

The crystal structure of TlMgCl 3 from 290 K to 725 K

The title compound, thallium magnesium trichloride, has been identified as a scintillator with both moderate gamma-stopping power and moderate light yield. Knowledge of its crystal structure is needed for further development. This work determines the crystal structure of TlMgCl 3 to be hexa­gonal P6 3 /mmc (No. 194) and isostructural with RbMgCl 3 , contrary to previously reported data. This structure was obtained by single-crystal X-ray diffraction and was further confirmed by neutron diffraction measurements. Extending neutron diffraction measurements to high temperature, the data show that TlMgCl 3 maintains this crystal structure from 290 K up through 725 K, approaching the melting point of 770 K. Anisotropic thermal expansion coefficients increase over this temperature range, from 31 to 38 × 10 –6 K –1 along the a axis and from 19 to 34 × 10 –6 K –1 along the c axis.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Expansion of the Direct Feed High-Level Waste Glass Composition in the High Al Range

Baseline glass compositions have been developed and demonstrated for successful immobilization of Hanford high-level waste (HLW) prepared through a pretreatment process. Recent enhanced waste glass formulations have shown promise to increase the waste loading of pretreated sludge compositions from a broader range of HLW feeds. This project proposes to increase the loading of minimally pretreated Hanford HLW in glass by expanding the existing database and glass property-composition models. Estimated direct-feed high level waste (DFHLW) compositions were generated by the Hanford Tank Operations Contractor and used by Pacific Northwest National Laboratory to determine target glass compositions. Gaps in existing data were identified including one high-priority gap in the high Al compositional region. This report summarizes the data collected during the characterization of the DFHLW High Al Glass Matrix. These glasses were intentionally designed with high aluminum concentrations (15 to 30 wt%) and a high likelihood of nepheline formation, which is known to negatively affect glass durability. Some glasses were expected to either fail or approach property constraints to fill data gaps in poorly understood regions of the compositional space due to lack of data. Out of the 50 glasses tested, 14 glasses formed nepheline, while the model predicted nepheline formation in 20 glasses. All quenched glasses met the product consistency test durability constraint; however, 8 glasses failed this constraint after undergoing the canister centerline cooling treatment. Additionally, 17 glasses did not meet the viscosity constraints, 4 failed the EC constraints, and 2 exceeded the allowable T2% for spinel crystal formation. All glasses satisfied the SO 3 solubility limit. The resulting dataset provides valuable information to improve model accuracy and reduce prediction uncertainty. These insights will ultimately support the development of more robust glass formulation strategies, enabling higher waste loadings, reducing operational risks, and expanding the processing envelope.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1972

Space shuttle orbit maneuvering engine reusable thrust chamber

A data dump is presented containing space shuttle orbiter maneuvering engine performance, weight, envelope, and interface pressure requirements for candidate propellant combinations (NTO/MMH, NTO50-50, LOX/MMH, LOX/50-50, LOX/N2H4, LOX/C3H8, and LOX/RP-1) and cooling concepts (regenerative and dump/film). These data are presented parametrically for the thrust, chamber pressure, nozzle expansion ratio, and engine mixture ratio ranges of interest. Also included is information describing sensitivity to system changes; reliability, maintainability and safety; development programs and associated critical technology areas; engine cost comparisons during development and operation; and ecological effects.

Source record↗
NASA NTRS1973

Stellar winds driven by Alfven waves

Models of stellar winds were considered in which the dynamic expansion of a corona is driven by Alfven waves propagating outward along radial magnetic field lines. In the presence of Alfven waves, a coronal expansion can exist for a broad range of reference conditions which would, in the absence of waves, lead to static configurations. Wind models in which the acceleration mechanism is due to Alfven waves alone and exhibit lower mass fluxes and higher energies per particle are compared to wind models in which the acceleration is due to thermal processes. For example, winds driven by Alfven waves exhibit streaming velocities at infinity which may vary between the escape velocity at the coronal base and the geometrical mean of the escape velocity and the speed of light. Upper and lower limits were derived for the allowed energy fluxes and mass fluxes associated with these winds.

Belcher, J. W.↗
NASA NTRS1982

On perturbations of magnetic field configurations

The behavior of stationary equilibrium solutions to the MHD equations possessing a well-defined symmetry to perturbations lacking that symmetry is explored. Two distinct situations of astrophysical interest are considered: solutions of the magnetostatic equations and of the magnetoconvection equations. The results show that in these cases changes in solution topology are not accessible to small-parameter (epsilon) expansions, so that such expansions do not describe the full range of behavior. In particular, finite-amplitude perturbations can lead to new stationary solutions possessing different symmetries from the initial solution.

Rosner, R.↗
NASA NTRS1983

NASA technology transfer in the southwest states - Arizona, Colorado, Nevada and Utah

Features of the NASA Regional Application Program for providing state and local land management agencies an opportunity to assess the usefulness of emerging remote sensing technology are described. The Program guidelines necessitated configuring software for local facilities, assuring that the aggncy involved furnished manpower, and applying the technology to local needs. The study focused on the southwestern U.S., particularly for purposes of water management, federal/state ownership/policy, energy development, environmental impact issues, timber and range inventory, fire control, and urban expansion. Demonstration projects were conducted in various topics, according to the state surveyed, with the success of the projects determined by the willingness of the agencies to continue with the technology, which happened in several cases.

Norman, S. D.↗
NASA NTRS1985

Probing the local interstellar medium

A sophisticated model of solar wind expansion is applied to deduce a range of parameters for the local interstellar medium that predicts a location for the heliospheric shock of about 30 AU. It is found that either the interstellar magnetic field is more than double the presently accepted value of 0.3 nT, or the pressure due to galactic cosmic rays with energies near 0.1 MeV is that obtained by simple extrapolation of the observed flux at higher energies inside the heliosphere. Alternatively, some combination of these two external effects yields an effective interstellar pressure approximately quadruple present estimates.

Suess, S. T.↗
NASA NTRS1989

A mandate for space education

Issues related to public education in preparation for a manned Mars program are discussed. Consideration is given to the near- and long-term goals of the space program, the benefits of human expansion in space, and long-range planning for fundamental problem areas in space education. Important concerns for space educators are outlined.

Von Puttkamer, Jesco↗
NASA NTRS1993

Advanced engine study program

A design and analysis study was conducted to provide advanced engine descriptions and parametric data for space transfer vehicles. The study was based on an advanced oxygen/hydrogen engine in the 7,500 to 50,000 lbf thrust range. Emphasis was placed on defining requirements for high-performance engines capable of achieving reliable and versatile operation in a space environment. Four variations on the expander cycle were compared, and the advantages and disadvantages of each were assessed. Parametric weight, envelope, and performance data were generated over a range of 7,500 to 50,000 lb thrust and a wide range of chamber pressure and nozzle expansion ratio.

Masters, A. I.↗
NASA NTRS1995

A hybrid neurocomputing/numerical strategy for nonlinear structural analysis

A hybrid neurocomputing/numerical strategy is presented for geometrically nonlinear analysis of structures. The strategy combines model-free data processing capabilities of computational neural networks with a Pade approximants-based perturbation technique to predict partial information about the nonlinear response of structures. In the hybrid strategy, multilayer feedforward neural networks are used to extend the validity of solutions by using training samples produced by Pade approximations to the Taylor series expansion of the response function. The range of validity of the training samples is taken to be the radius of convergence of Pade approximants and is estimated by setting a tolerance on the diverging approximants. The norm of residual vector of unbalanced forces in a given element is used as a measure to assess the quality of network predictions. To further increase the accuracy and the range of network predictions, additional training data are generated by either applying linear regression to weight matrices or expanding the training data by using predicted coefficients in a Taylor series. The effectiveness of the hybrid strategy is assessed by performing large-deflection analysis of a doubly-curved composite panel with a circular cutout, and postbuckling analyses of stiffened composite panels subjected to an in-plane edge shear load. In all the problems considered, the hybrid strategy is used to predict selective information about the structural response, namely the total strain energy and the maximum displacement components only.

Szewczyk, Z. Peter↗
NASA NTRS1999

Frequency-Dependent Viscosity of Xenon Near the Critical Point

We used a novel, overdamped oscillator aboard the Space Shuttle to measure the viscosity eta of xenon near its critical density rho(sub c), and temperature T(sub c). In microgravity, useful data were obtained within 0.1 mK of T(sub c), corresponding to a reduced temperature t = (T -T(sub c))/T(sub c) = 3 x 10(exp -7). The data extend two decades closer to T(sub c) than the best ground measurements, and they directly reveal the expected power-law behavior eta proportional to t(sup -(nu)z(sub eta)). Here nu is the correlation length exponent, and our result for the small viscosity exponent is z(sub eta) = 0.0690 +/- 0.0006. (All uncertainties are one standard uncertainty.) Our value for z(sub eta) depends only weakly on the form of the viscosity crossover function, and it agrees with the value 0.067 +/- 0.002 obtained from a recent two-loop perturbation expansion. The measurements spanned the frequency range 2 Hz less than or equal to f less than or equal to 12 Hz and revealed viscoelasticity when t less than or equal to 10(exp -1), further from T(sub c) than predicted. The viscoelasticity scales as Af(tau), where tau is the fluctuation-decay time. The fitted value of the viscoelastic time-scale parameter A is 2.0 +/- 0.3 times the result of a one-loop perturbation calculation. Near T(sub c), the xenon's calculated time constant for thermal diffusion exceeded days. Nevertheless, the viscosity results were independent of the xenon's temperature history, indicating that the density was kept near rho(sub c), by judicious choices of the temperature vs. time program. Deliberately bad choices led to large density inhomogeneities. At t greater than 10(exp -5), the xenon approached equilibrium much faster than expected, suggesting that convection driven by microgravity and by electric fields slowly stirred the sample.

Berg, Robert F.↗
NASA NTRS2012

Uncertainty Quantification for Polynomial Systems via Bernstein Expansions

This paper presents a unifying framework to uncertainty quantification for systems having polynomial response metrics that depend on both aleatory and epistemic uncertainties. The approach proposed, which is based on the Bernstein expansions of polynomials, enables bounding the range of moments and failure probabilities of response metrics as well as finding supersets of the extreme epistemic realizations where the limits of such ranges occur. These bounds and supersets, whose analytical structure renders them free of approximation error, can be made arbitrarily tight with additional computational effort. Furthermore, this framework enables determining the importance of particular uncertain parameters according to the extent to which they affect the first two moments of response metrics and failure probabilities. This analysis enables determining the parameters that should be considered uncertain as well as those that can be assumed to be constants without incurring significant error. The analytical nature of the approach eliminates the numerical error that characterizes the sampling-based techniques commonly used to propagate aleatory uncertainties as well as the possibility of under predicting the range of the statistic of interest that may result from searching for the best- and worstcase epistemic values via nonlinear optimization or sampling.

Crespo, Luis G.↗
NASA NTRS2016

Hall Thruster Thermal Modeling and Test Data Correlation

HERMeS - Hall Effect Rocket with Magnetic Shielding. Developed through a joint effort by NASA/GRC and the Jet Propulsion Laboratory (JPL). Design goals: High power (12.5 kW) high Isp (3000 sec), high efficiency (> 60%), high throughput (10,000 kg), reduced plasma erosion and increased life (5 yrs) to support Asteroid Redirect Robotic Mission (ARRM). Further details see "Performance, Facility Pressure Effects and Stability Characterization Tests of NASAs HERMeS Thruster" by H. Kamhawi and team. Hall Thrusters (HT) inherently operate at elevated temperatures approx. 600 C (or more). Due to electric magnetic (E x B) fields used to ionize and accelerate propellant gas particles (i.e., plasma). Cooling is largely limited to radiation in vacuum environment.Thus the hardware components must withstand large start-up delta-T's. HT's are constructed of multiple materials; assorted metals, non-metals and ceramics for their required electrical and magnetic properties. To mitigate thermal stresses HT design must accommodate the differential thermal growth from a wide range of material Coef. of Thermal Expansion (CTEs). Prohibiting the use of some bolted/torqued interfaces.Commonly use spring loaded interfaces, particularly at the metal-to-ceramic interfaces to allow for slippage.However most component interfaces must also effectively conduct heat to the external surfaces for dissipation by radiation.Thus contact pressure and area are important.

Model↗
DOE OSTI2023

Lens alignment system and method

A lens alignment system and method is disclosed. The disclosed system/method integrates one or more lens retaining members/tubes (LRM/LRT) and focal length spacers (FLS) each comprising a metallic material product (MMP) specifically manufactured to have a thermal expansion coefficient (TEC) in a predetermined range via selection of the individual MMP materials and an associated MMP manufacturing process providing for controlled TEC. This controlled LRM/LRT TEC enables a plurality of optical lenses (POL) fixed along a common optical axis (COA) by the LRM/LRT to maintain precise interspatial alignment characteristics that ensure consistent and/or controlled series focal length (SFL) within the POL to generate a thermally neutral optical system (TNOS). Integration of the POL using this LRM/LRT/FLS lens alignment system reduces the overall TNOS implementation cost, reduces the overall TNOS mass, reduces TNOS parts component count, and increases the reliability of the overall optical system.

Monroe, James Alan↗