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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 181 records · Page 10
All sourcesNASA NTRSDOE OSTI
NASA NTRS1971

Laminar or turbulent boundary-layer flows of perfect gases or reacting gas mixtures in chemical equilibrium

Turbulent boundary layer flows of non-reacting gases are predicted for both interal (nozzle) and external flows. Effects of favorable pressure gradients on two eddy viscosity models were studied in rocket and hypervelocity wind tunnel flows. Nozzle flows of equilibrium air with stagnation temperatures up to 10,000 K were computed. Predictions of equilibrium nitrogen flows through hypervelocity nozzles were compared with experimental data. A slender spherically blunted cone was studied at 70,000 ft altitude and 19,000 ft/sec. in the earth's atmosphere. Comparisons with available experimental data showed good agreement. A computer program was developed and fully documented during this investigation for use by interested individuals.

Anderson, E. C.↗
NASA NTRS1972

Thermodynamic and transport properties of frozen and reacting pH2-oH2 mixtures

Application of experimental state data and spectroscopic term values shows that the thermodynamic and transport properties of reacting pH2-oH2 mixtures are considerably different than those of chemically frozen pH2 at temperatures below 300 R. Calculated H-S data also show that radiation-induced pH2-oH2 equilibration at constant enthalpy produces a temperature drop of at least 28 R, corresponding to an ideal shaft work loss of 15% or more for a turbine operating downstream from the point of conversion. Aside from differences in thermodynamic and transport properties, frozen pH2-oH2 mixtures may differ from pure pH2 on a purely hydrodynamical basis.

Carter, H. G.↗
NASA NTRS1972

Transfer phenomena in reacting gas mixtures

In considering transfer phenomena in reacting gas mixtures, the following topics are discussed: (1) dynamics of paired collisions; (2) Enskog method for solving the Boltzmann equation, taking into account inelastic collisions; (3) use of the variation principle for approximate solutions; (4) computations of inelastic bracketed expressions; (5) calculation of collision integrals; and (6) formulas for transfer coefficients.

Alekseyev, B. V.↗
NASA NTRS1972

Perturbation of the Maxwellian distribution in chemically reacting gas mixtures

Chemically reacting gas mixtures are considered for the case in which inelastic collisions occur significantly less frequently than elastic ones. The first approximation of the general solution of the Boltzmann equation is developed and is shown to contain an additional scaler term. The concentration, the mean mass velocity, and the temperature of the mixture are determined and the rate of reaction in the first approximation is formulated. Tables are presented which give reaction rate values obtained by both the first and second approximation for different activation energies. The tables show that the first approximation is sufficient for practical purposes for calculating the reaction rate.

Alekseyev, B. V.↗
NASA NTRS1973

The analysis of nonequilibrium, chemically reacting, supersonic flow in three dimensions using a bicharacteristics method.

A second-order numerical method of characteristics based on a bicharacteristics scheme was developed for the evaluation of steady, supersonic, nonequilibrium, chemically reacting flows. The absolute accuracy and order of accuracy of the method was shown by comparisons with spherical source flow and axisymmetric, nonequilibrium flows. Numerical results were obtained for elliptical and super-elliptical nozzles. These results illustrate the complex nature of three-dimensional flows and the inadequacy of quasi-three-dimensional methods which neglect cross flows.

Cline, M. C.↗
NASA NTRS1974

A study of stratospheric gases catalytically reacting on alumina

A vacuum system developed to study stratospheric gases reacting on Al2O3. Special attention was given to the reactions of HCl, SO2, and O3. Efforts were made to detect atoms and/or molecules produced by catalytic action of Al2O3 with mass spectrometer.

Cox, J. L., Jr.↗
NASA NTRS1973

H theorem and kinetic equations for a reacting gas

A previously developed set of kinetic model equations for a chemically-reacting gas is modified. By examining closely the H theorem, a new set of constraints is obtained. These conditions are then used to determine the inelastic collision parameters proposed in the model. The kinetic equations so obtained are able to produce exactly the same rate equations as prescribed by the actual chemical reactions.

Fang, T.-M.↗
NASA NTRS1975

A study of reacting free and ducted hydrogen/air jets

The mixing and reaction of a supersonic jet of hydrogen in coaxial free and ducted high temperature test gases were investigated. The importance of chemical kinetics on computed results, and the utilization of free-jet theoretical approaches to compute enclosed flow fields were studied. Measured pitot pressure profiles were correlated by use of a parabolic mixing analysis employing an eddy viscosity model. All computations, including free, ducted, reacting, and nonreacting cases, use the same value of the empirical constant in the viscosity model. Equilibrium and finite rate chemistry models were utilized. The finite rate assumption allowed prediction of observed ignition delay, but the equilibrium model gave the best correlations downstream from the ignition location. Ducted calculations were made with finite rate chemistry; correlations were, in general, as good as the free-jet results until problems with the boundary conditions were encountered.

Beach, H. L., Jr.↗
NASA NTRS1975

Turbulent Chemically Reacting Flows According to a Kinetic Theory

A review of various methods of calculating turbulent chemically reacting flow such as the Green Function, Navier-Stokes equation, and others is presented. Nonequilibrium degrees of freedom were employed to study the mixing behavior of a multiscale turbulence field. Classical and modern theories are discussed.

Hong, Z. C.↗
NASA NTRS1975

A generalized hyperbolic marching method for chemically reacting 3-D supersonic flow using a splitting technique

A generalized hyperbolic marching method employing a nonorthogonal coordinate system and using a split differencing scheme for calculating steady supersonic flow over aerodynamic shapes is presented. It is a second-order-accurate mixed explicit-implicit procedure that solves the inviscid adiabatic and nondiffusive equations for chemically reacting flow in integral conservation-law form. The relationship between the integral and differential forms of the equations are examined and the relative merits of each discussed. The method admits initial Cauchy data situated on any arbitrary surface and integrates them forward along a general curvilinear coordinate, distorting and deforming the surface as it advances. The chemical kinetics term is split from the convective terms which are themselves dimensionally split, thereby freeing the fluid operators from the restricted step-size imposed by the chemical reactions and increasing the computational efficiency. The accuracy of this splitting technique is analyzed, a sufficient stability criterion is established, and comparisons are made with another method.

Rizzi, A. W.↗
NASA NTRS1975

Calculation of three-dimensional compressible laminar and turbulent boundary flows. Three-dimensional compressible boundary layers of reacting gases over realistic configurations

A three-dimensional boundary-layer code was developed for particular application to realistic hypersonic aircraft. It is very general and can be applied to a wide variety of boundary-layer flows. Laminar, transitional, and fully turbulent flows of compressible, reacting gases are efficiently calculated by use of the code. A body-oriented orthogonal coordinate system is used for the calculation and the user has complete freedom in specifying the coordinate system within the restrictions that one coordinate must be normal to the surface and the three coordinates must be mutually orthogonal.

Kendall, R. M.↗
NASA NTRS1976

Equilibrium properties of chemically reacting gases

The equilibrium energy, enthalpy, entropy, specific heat at constant volume and constant pressure, and the equation of state of the gas are all derived for chemically reacting gas mixtures in terms of the compressibility, the mol fractions, the thermodynamic properties of the pure gas components, and the change in zero point energy due to reaction. Results are illustrated for a simple diatomic dissociation reaction and nitrogen is used as an example. Next, a gas mixture resulting from combined diatomic dissociation and atomic ionization reactions is treated and, again, nitrogen is used as an example. A short discussion is given of the additional complexities involved when precise solutions for high-temperature air are desired, including effects caused by NO produced in shuffle reactions and by other trace species formed from CO2, H2O and Ar found in normal air.

Source record↗
NASA NTRS1976

Non-equilibrium radiation from viscous chemically reacting two-phase exhaust plumes

A knowledge of the structure of the rocket exhaust plumes is necessary to solve problems involving plume signatures, base heating, plume/surface interactions, etc. An algorithm is presented which treats the viscous flow of multiphase chemically reacting fluids in a two-dimensional or axisymmetric supersonic flow field. The gas-particle flow solution is fully coupled with the chemical kinetics calculated using an implicit scheme to calculate chemical production rates. Viscous effects include chemical species diffusion with the viscosity coefficient calculated using a two-equation turbulent kinetic energy model.

Penny, M. M.↗
NASA NTRS1976

Remarks on the construction of a second-order closure description of turbulent reacting flows

In this paper an attempt is made to illustrate how second-order closure techniques might be used to make detailed calculations of turbulent diffusion flames. Two of the problems of closure that are peculiar to turbulent chemically reacting flows are discussed in some detail. These are the problem of computing in a consistent way all the correlations of fluctuations in scalar quantities needed for closure and the problem of the generation of turbulence by chemical reactions. Tentative closure models are put forward for both of these problems. Although the closure model for fluctuations in scalar quantities can, to a certain extent, be checked against idealized numerical examples for which exact solutions are known, the validity of both the closure models proposed here must, in the end, be determined by detailed comparison of computed results with experimental data.

DONALDSON C. DUP.↗
NASA NTRS1975

On the modeling of the scalar correlations necessary to construct a second-order closure description of turbulent reacting flows

A tentative scheme is proposed for constructing second-order closure models of turbulent reacting flows, with particular reference to mixing processes in turbulent diffusion flows. The model is based on the concepts of typical structure and typical eddy, and treats various hypothetical turbulent flame situations, including the time dependence of species mass fractions passing a point in the flame, the most typical occurrence of species mass fractions, and the case of a rather bizarre typical eddy which shows the effects of nonmixedness.

Donaldson, C. DUP.↗
NASA NTRS1977

Gravitational effects on chemically reacting laminar boundary layer flows over a horizontal flat plate

A theoretical study of the chemically reacting laminar boundary layer flow over a horizontal flat plate with gravitationally induced buoyant force is presented. A diffusion flame sheet model was used to describe the combustion process. The effects of gravity on the purely force convection flow can be characterized by a dimensionless coordinate quantity, which is involved in the generation of the governing equations. A numerical solution of the zero and first order governing equations subject to the appropriate physical boundary conditions was obtained. It is shown that the cross stream buoyancy induced body force acts effectively to produce a streamwise pressure gradient in the fluid adjacent to the plate surface. It is concluded that buoyancy plays an important role in boundary layer diffusion flames.

Lavid, M.↗
NASA NTRS1978

Application of a two-dimensional parabolic computer program to prediction of turbulent reacting flows

The capabilities of a computer program are explored, and computed results are compared with data. The comparisons are restricted to two-dimensional flows. Subsonic and supersonic flows, ducted and nonducted, reacting and nonreacting, are considered. An evaluation of models used for turbulence and chemical reaction was included. Constants in the dissipation rate of turbulent kinetic energy, turbulence model, which produces mixing in good agreement with data, are the same for all calculations. Experimental data are reported for coaxial injection at matched pressure (1 atm or 101.3 kPa) of a cold, Mach 2, hydrogen jet into a hot, Mach 2, vitiated airstream. Profiles of pitot pressure and gas composition obtained from water cooled probes are reported and compared with theoretical results.

Evans, J. S.↗
NASA NTRS1977

Parallel computation of unsteady, three-dimensional, chemically reacting, nonequilibrium flow using a time-split finite-volume method on the Illiac IV

A description is presented of the split finite-volume method which is a viable numerical procedure for performing with the aid of a modern special purpose vector computer numerical simulation studies of complicated flow fields, including chemical reactions, about geometrically complex bodies. Such numerical studies are needed for the development of atmospheric entry vehicles such as the space shuttle. The equations which are approximated are quite general and can be used in studies of combustion, pollution, and other chemically reacting flow phenomena, where convective transport effects dominate the influence of radiative, viscous, and other transport mechanisms. The shock perturbed flow about a shuttle orbiter flying at a large angle of attack during atmospheric entry is illustrated. The method uses a time splitting of the convection differencing operator to achieve efficient data management.

Reinhardt, W. A.↗